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We present a theoretical method for calculating optical absorption spectra based on maximally localized Wannier functions, which is suitable for large periodic systems. For this purpose, we calculate the exciton Hamiltonian, which…

Mesoscale and Nanoscale Physics · Physics 2023-09-14 Konrad Merkel , Frank Ortmann

The paper presents the group theory of best localized and symmetry-adapted Wannier functions in a crystal of any given space group G or magnetic group M. Provided that the calculated band structure of the considered material is given and…

Strongly Correlated Electrons · Physics 2015-05-22 Ekkehard Krüger , Horst P. Strunk

A procedure to construct symmetry-adapted Wannier functions in the framework of the maximally-localized Wannier function approach[Marzari and Vanderbilt, Phys. Rev. B \textbf{56}, 12847 (1997); Souza, Marzari, and Vanderbilt, \textit{ibid.}…

Strongly Correlated Electrons · Physics 2015-06-16 R. Sakuma

From the order-N electronic-structure formulation, a Hamiltonian is derived, of which lowest eigen state is the generalized or composite-band Wannier state. This Hamiltonian maps the locality of the Wannier state to that of a virtual…

Materials Science · Physics 2009-10-31 Takeo Hoshi , Takeo Fujiwara

We present a spin-dependent extension of the non-orthogonal generalized Wannier function (NGWF) formalism within the framework of linear-scaling density functional theory (LS-DFT) as implemented in the ONETEP code. In traditional LS-DFT…

The problem of construction of the Wannier functions (WFs) in a restricted Hilbert space of eigenstates of the one-electron Hamiltonian $\hat{H}$ (forming the so-called low-energy part of the spectrum) can be formulated in several different…

Strongly Correlated Electrons · Physics 2007-05-23 I. V. Solovyev , Z. V. Pchelkina , V. I. Anisimov

A new scheme for the computation of dispersive interactions from first principles is presented. This cost-effective approach relies on a Wannier function representation compatible with density function theory descriptions. This is an…

Materials Science · Physics 2025-02-04 Diem Thi-Xuan Dang , Dai-Nam Le , Lilia M. Woods

We define Wannier functions for interacting systems, and show that the results on the localization of the Wannier functions for non-interacting systems carry over to the Wannier functions for interacting systems. In addition we demonstrate…

Strongly Correlated Electrons · Physics 2009-11-07 Erik Koch , Stefan Goedecker

The construction of Wannier functions from Bloch orbitals offers a unitary freedom that can be exploited to yield Wannier functions with advantageous properties. Minimizing the spatial variance is a well-known choice; another, previously…

Materials Science · Physics 2026-04-29 Aaron Mahler , Jacob Z. Williams , Neil Qiang Su , Weitao Yang

We present Wannier90, a program for calculating maximally-localised Wannier functions (MLWF) from a set of Bloch energy bands that may or may not be attached to or mixed with other bands. The formalism works by minimising the total spread…

Materials Science · Physics 2011-05-18 A. A. Mostofi , J. R. Yates , Y. -S. Lee , I. Souza , D. Vanderbilt , N. Marzari

We present a code-independent compact representation of one-electron wavefunctions and other volumetric data (electron density, electrostatic potential, etc.) produced by electronic-structure calculations. The compactness of the…

Materials Science · Physics 2019-02-08 Sergey V. Levchenko , Matthias Scheffler

The maximally localized Wannier functions play a very important role in the study of chemical bonding, ballistic transport and strongly-correlated system, etc. A significant development in this branch was made in 1997 and conjectured that…

Materials Science · Physics 2014-07-28 Sangryol Ri , Suil Ri

Density functional perturbation theory is a well-established method to study responses of molecules and solids, especially responses to atomic displacements or to different perturbing fields (electric, magnetic). Like for density functional…

Materials Science · Physics 2024-02-16 Xavier Gonze , Samare Rostami , Christian Tantardini

The electronic ground state of a periodic crystalline solid is usually described in terms of extended Bloch orbitals; localized Wannier functions can alternatively be used. These two representations are connected by families of unitary…

Materials Science · Physics 2009-10-31 Nicola Marzari , David Vanderbilt

We present a scheme for calculating coherent electron transport in atomic-scale contacts. The method combines a formally exact Green's function formalism with a mean-field description of the electronic structure based on the Kohn-Sham…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 K. S. Thygesen , K. W. Jacobsen

Predicting the fate of an interacting system in the limit where the electronic bandwidth is quenched is often highly non-trivial. The complex interplay between interactions and quantum fluctuations driven by the band geometry can drive…

Strongly Correlated Electrons · Physics 2023-06-02 Johannes S. Hofmann , Erez Berg , Debanjan Chowdhury

The insulating state of matter is characterized by the excitation spectrum, but also by qualitative features of the electronic ground state. The insulating ground wavefunction in fact: (i) sustains macroscopic polarization, and (ii) is…

Materials Science · Physics 2009-10-31 R. Resta , S. Sorella

A first-principles study of the adsorption of a single water molecule on a layer of graphitic carbon nitride employing an embedding approach is presented. The embedding approach involves an algorithm to obtain localized Wannier orbitals of…

Chemical Physics · Physics 2022-01-11 Tobias Schäfer , Alejandro Gallo , Andreas Irmler , Felix Hummel , Andreas Grüneis

We present a novel family of continuous, linear time-frequency transforms adaptable to a multitude of (nonlinear) frequency scales. Similar to classical time-frequency or time-scale representations, the representation coefficients are…

Functional Analysis · Mathematics 2024-03-20 Nicki Holighaus , Christoph Wiesmeyr , Peter Balazs

We derive a theory for transmission through disordered finite superlattices in which the interface roughness scattering is treated by disorder averaging. This procedure permits efficient calculation of the transmission thr ough samples with…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 Andreas Wacker , Ben Yu-Kuang Hu