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Electronic structure calculation of atoms and molecules, in the past few decades has largely been dominated by density functional methods. This is primarily due to the fact that this can account for electron correlation effects in a…

Chemical Physics · Physics 2013-07-12 Amlan K. Roy

We derive analytical solutions for the zero-energy states of degenerate shell obtained as a singular eigenevalue problem found in tight-binding (TB) Hamiltonian of triangular graphene quantum dots with zigzag edges. These analytical…

Materials Science · Physics 2013-05-29 P. Potasz , A. D. Güçlü , P. Hawrylak

A quantitative and predictive theory of quantum light-matter interactions in ultra thin materials involves several fundamental challenges. Any realistic model must simultaneously account for the ultra-confined plasmonic modes and their…

Subsystem Density-Functional Theory (DFT) is an emerging technique for calculating the electronic structure of complex molecular and condensed phase systems. In this topical review, we focus on some recent advances in this field related to…

Chemical Physics · Physics 2015-06-24 Alisa Krishtal , Debalina Sinha , Alessandro Genova , Michele Pavanello

A finite electronic band gap is a standard filter in high-throughput screening of materials using density functional theory (DFT). However, because of the systematic underestimation of band gaps in standard DFT approximations, a number of…

Materials Science · Physics 2021-09-15 Kristian Berland , Ole Martin Løvvik , Rasmus Tranås

We study the thermoelectric coefficients of a multi-level quantum dot (QD) weakly coupled to two electron reservoirs in the Coulomb blockade regime. Detailed calculations and analytical expressions of the power factor and the figure of…

Mesoscale and Nanoscale Physics · Physics 2015-05-20 M. Tsaousidou , G. P. Triberis

The structural, electronic and optical properties of nearly ferromagnetic compound HfZn2 have been studied using ab-initio technique. We have carried out the plane-wave pseudopotential approach within the framework of the first-principles…

Materials Science · Physics 2016-05-17 Md. Atikur Rahman , Md. Afjalur Rahman , Md. Zahidur Rahaman

Density functional theory (DFT) is a widespread and effective tool in electronic structure calculations for ground-state electron systems. Its success has prompted exploration into the use of DFT for non-collective excited states. The delta…

Chemical Physics · Physics 2025-08-12 Ethan Pollack , Rohan Maniar , John P. Perdew

Density functional theory (DFT), the most widely adopted method in modern computational chemistry, fails to describe accurately the electronic structure of strongly correlated systems. Here we show that DFT can be formally and practically…

Chemical Physics · Physics 2022-04-18 Daniel Gibney , Jan-Niklas Boyn , David A. Mazziotti

Ab-initio density functional perturbation theory (DFPT) has been employed to study thermodynamical properties of pure and doped graphene sheet and the results have been compared with available theoretical and experimental data. The…

Mesoscale and Nanoscale Physics · Physics 2020-05-22 Sarita Mann , Pooja Rani , Ranjan Kumar , Girija S. Dubey , V. K. Jindal

We consider a square lattice configuration of circular gate-defined quantum dots in an unbiased graphene sheet and calculate the electronic, particularly spectral properties of finite albeit actual sample sized systems by means of a…

Mesoscale and Nanoscale Physics · Physics 2015-06-19 A. Pieper , R. L. Heinisch , G. Wellein , H. Fehske

We propose a local real-space formulation for orbital-free DFT with density dependent kinetic energy functionals and a unified variational framework for computing the configurational forces associated with geometry optimization of both…

Materials Science · Physics 2015-06-15 Sambit Das , Mrinal Iyer , Vikram Gavini

The tight-binding method is employed to investigate the effects of three typical in-plane electric fields on the electronic structure of a triangular zigzag graphene quantum dot. The calculation shows that the single-electron eigenstates…

Mesoscale and Nanoscale Physics · Physics 2017-03-14 Qing-Rui Dong

The thermal properties of bulk copper are investigated by performing ab initio DFT and DFPT calculations and using the quasiharmonic approximation for the free energy. Using both the LDA and the GGA for the exchange-correlation potential,…

Materials Science · Physics 2009-11-07 Shobhana Narasimhan , Stefano de Gironcoli

The first part of this article centers on the fact that key features of the dynamical response of weakly-correlated materials (the alkalis, Al), have been found experimentally to differ qualitatively from simple-model behavior. In the…

Strongly Correlated Electrons · Physics 2007-05-23 Adolfo G. Eguiluz , Wei Ku

A specific structure of doped graphene with substituted silicon impurity is introduced and ab. initio density-functional approach is applied for energy band structure calculation of proposed structure. Using the band structure calculation…

Mesoscale and Nanoscale Physics · Physics 2011-03-01 Mohammad S. Sharif Azadeh , Alireza Kokabi , Mehdi Hosseini , Mehdi Fardmanesh

This chapter concerns with the recent development of a new DFT methodology for accurate, reliable prediction of many-electron systems. Background, need for such a scheme, major difficulties encountered, as well as their potential remedies…

Chemical Physics · Physics 2019-04-19 Amlan K. Roy

We report on the fabrication, transport measurements, and density functional theory (DFT) calculations of atomic size contacts made out of gadolinium (Gd). Gd is known to have local moments mainly associated with $f$ electrons. These…

Mesoscale and Nanoscale Physics · Physics 2017-02-15 B. Olivera , C. Salgado , J. L. Lado , A. Karimi , V. Henkel , E. Scheer , J. Fernández-Rossier , J. J. Palacios , C. Untiedt

By invoking a divide-and-conquer strategy, subsystem DFT dramatically reduces the computational cost of large-scale, \textit{ab-initio} electronic structure simulations of molecules and materials. The central ingredient setting subsystem…

Materials Science · Physics 2020-08-24 Wenhui Mi , Michele Pavanello

The biphenylene network (BPN) is a notable achievement in recent fabrication endeavors for conceiving new 2D materials. The stability of its boron nitride counterpart, BN-BPN, has been confirmed through numerical investigations. In this…

Materials Science · Physics 2023-10-12 Kleuton Antunes Lopes Lima , Luiz Antonio Ribeiro Junior
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