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We report on the first experimental demonstration of enantioselective rotational control of chiral molecules with a laser field. In our experiments, two enantiomers of propylene oxide are brought to accelerated unidirectional rotation by…

The quantum dynamics of Excited State Intramolecular Proton Transfer (ESIPT) is studied using a non-Markovian open quantum system perspective. Models of 2-(2-hydroxyphenyl) benzothiazole (HBT) and 10-hydroxybenzo[h]quinoline (HBQ) are…

Chemical Physics · Physics 2025-03-05 Brieuc Le Dé , Simon Huppert , Riccardo Spezia , Alex W. Chin

Pulse flip angles are calculated for three wave mixing, three state cycles of chiral molecules to produce optimized free induction decay amplitudes proportional to the enantiomeric excess of a sample, and to produced optimized degree of…

Chemical Physics · Physics 2018-11-02 Kevin K. Lehmann

Photo-induced excited-state energy transfer (EET) processes play an important role in the solar energy conversions. The phenylene ethynylene (PE) dendrimers display great potential in improving the efficiency of solar cells, because of…

Chemical Physics · Physics 2024-01-17 Sisi Liu , Jiawei Peng , Peng Bao , Qiang Shi , Zhenggang Lan

Superconducting qubits typically use a dispersive readout scheme, where a resonator is coupled to a qubit such that its frequency is qubit-state dependent. Measurement is performed by driving the resonator, where the transmitted resonator…

Chiroptical enantioselective sensing is gaining traction across various applications. However, intrinsic molecular chiroptical responses are weak, and existing amplification approaches add synthesis, manufacturing, or operational complexity…

A beam of polar molecules can be focused and transported through an ac electric quadrupole guide. At a given ac frequency, the transmission of the guide depends on the mass-to-dipole-moment (m/\textmu) ratio of the molecular quantum state.…

Atomic and Molecular Clusters · Physics 2017-09-13 Stephan Putzke , Frank Filsinger , Henrik Haak , Jochen Küpper , Gerard Meijer

Acquiring quantitative information on charge transfer (CT) dynamics at the nanoscale remains an important scientific challenge. In particular, CT processes in single molecules at surfaces needs to be investigated to be properly controlled…

Mesoscale and Nanoscale Physics · Physics 2017-06-20 Hatem Labidi , Henry Pinto , Jerzy Leszczynski , Damien Riedel

Exceptional points (EPs) are remarkable spectral degeneracies in a non-Hermitian system's parameter space, where both eigenvalues and eigenstates coalesce. Here, we show that in non-Hermitian molecular chiral systems the position of EPs in…

Quantum Physics · Physics 2025-12-02 Nicola Mayer , Alexander Löhr , Nimrod Moiseyev , Misha Ivanov , Olga Smirnova

Three-wave mixing spectroscopy of chiral molecules, which exist in left-handed and right-handed conformations, allows for enantio-selective population transfer despite random orientation of the molecules. This is based on constructive…

Quantum Physics · Physics 2019-07-09 Monika Leibscher , Thomas F. Giesen , Christiane P. Koch

We construct a quantum Ginsburg-Landau theory to study the quantum phases and transitions in electron hole bilayer system. We propose that in the dilute limit as distance is increased, there is a first order transition from the excitonic…

Strongly Correlated Electrons · Physics 2010-01-31 Jinwu Ye

In this work we investigate the theory for three different uni-directional population transfer schemes in trapped multilevel systems which can be utilized to cool molecular ions. The approach we use exploits the laser-induced coupling…

Quantum Physics · Physics 2010-01-27 C. Lazarou , M. Keller , B. M. Garraway

Enantiodetection is an important and challenging task across natural science. Nowadays, some chiroptical methods of enantiodetection based on decoherence-free cyclic three-level models of chiral molecules can reach the ultimate limit of the…

Quantum Physics · Physics 2022-11-29 Chong Ye , Xiaowei Mu , Yifan Sun , Libin Fu , Xiangdong Zhang

When a molecule contains more than a few atoms, its full-dimensional dynamics becomes untractable, especially when introducing temperature effects. In such a case, it can be interesting to focus only on a few degrees of freedom and to model…

Chemical Physics · Physics 2026-01-09 Loïse Attal , Cyril Falvo , Pascal Parneix

Controlling the internal degrees of freedom is a key challenge for applications of cold and ultracold molecules. Here, we demonstrate rotational-state cooling of trapped methyl fluoride molecules (CH3F) by optically pumping the population…

We combine experimental and theoretical approaches to explore excited rotational states of molecules embedded in helium nanodroplets using CS$_2$ and I$_2$ as examples. Laser-induced nonadiabatic molecular alignment is employed to measure…

We investigate the steady-state electronic transport through a suspended dimer molecule coupled to leads. When strongly coupled to a vibrational mode, the electron transport is enhanced at the phonon resonant frequency and higher-order…

Mesoscale and Nanoscale Physics · Physics 2013-02-18 D. H. Santamore , Neill Lambert , Franco Nori

The translational motion of molecular ions can be effectively cooled sympathetically to translational temperatures below 100 mK in ion traps through Coulomb interactions with laser-cooled atomic ions. The ro-vibrational degrees of freedom,…

Atomic Physics · Physics 2009-11-10 I. S. Vogelius , L. B. Madsen , M. Drewsen

Electromagnetically induced transparency, as a quantum interference effect to eliminate optical absorption in an opaque medium, has found extensive applications in slow light generation, optical storage, frequency conversion, optical…

We establish a testbed system for the development of high-sensitivity Electron Spin Resonance (ESR) techniques for small samples at cryogenic temperatures. Our system consists of a Niobium Nitride thin-film planar superconducting…