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Water shows anomalous properties that are enhanced upon supercooling. The unusual behavior is observed in both H$_2$O and D$_2$O, however with different temperature dependences for the two isotopes. It is often noted that comparing the…

Chemical Physics · Physics 2024-03-14 Greg A. Kimmel

We report shear viscosity of heavy water supercooled $33\,\mathrm{K}$ below its melting point, revealing a 15-fold increase compared to room temperature. We also confirm our previous data for the viscosity of supercooled light water, and…

Chemical Physics · Physics 2023-09-19 Pierre Ragueneau , Frédéric Caupin , Bruno Issenmann

Among the numerous anomalies of water, the acceleration of dynamics under pressure is particularly puzzling. Whereas the diffusivity anomaly observed in experiments has been reproduced in several computer studies, the parallel viscosity…

We review the effect of water anomalies on the properties of low temperature water. When supercooled, liquids dynamical properties change drastically. Supercooled liquids undergo an at least exponential decrease of their diffusion…

Soft Condensed Matter · Physics 2020-01-14 V. Teboul , A. P. Kerasidou

The model Tip4p/{\epsilon} for water is tested for the presence of thermodynamic and dy- namic anomalies. Molecular dynamic simulations for this model were performed and we show that for this system the density versus temperature at…

Soft Condensed Matter · Physics 2015-08-12 Raul Fuentes-Azcatl , Marcia C. Barbosa

We report measurements of the shear viscosity $\eta$ in water up to $150\,\mathrm{MPa}$ and down to $229.5\,\mathrm{K}$. This corresponds to more than $30\,\mathrm{K}$ supercooling below the melting line. The temperature dependence is…

Soft Condensed Matter · Physics 2023-09-19 Alexandre Mussa , Romain Berthelard , Frédéric Caupin , Bruno Issenmann

By confining water in nanopores, so narrow that the liquid cannot freeze, it is possible to explore its properties well below its homogeneous nucleation temperature TH ~ 235 K. In particular, the dynamical parameters of water can be…

Soft Condensed Matter · Physics 2007-05-23 Sow-Hsin Chen , Francesco Mallamace , Chung-Yuan Mou , Matteo Broccio , Carmelo Corsaro , Antonio Faraone , Li Liu

H2O is a unique substance with exceptional thermal properties arising from the subtle interplay between its electronic, phononic, and structural degrees of freedom. Of particular interest in H2O are the negative thermal expansion (NTE)…

Chemical Physics · Physics 2025-12-30 B. I. Min , J. -S. Kang

The anomalous properties of water in the supercooled state are numerous and well-known. Particularly striking are the strong changes in dynamic properties that appear to display divergences at temperatures close to -- but beyond -- the…

Statistical Mechanics · Physics 2007-05-23 Francis W. Starr , Srikanth Sastry , Francesco Sciortino , H. E. Stanley

Nuclear quantum effects lead to an anomalous shift of the volume of hexagonal ice; heavy ice has a larger volume than light ice. This anomaly in ice increases with temperature and persists in liquid water up to the boiling point. We study…

Materials Science · Physics 2018-01-10 Betül Pamuk , P. B. Allen , M-V Fernández-Serra

Liquid water exhibits anomalous behavior in the supercooled region. A popular hypothesis to explain supercooled water's anomalies is the existence of a metastable liquid-liquid transition terminating at a critical point. The hypothesized…

Chemical Physics · Physics 2020-01-08 V. P. Voronov , V. E. Podnek , M. A. Anisimov

This paper is the fourth in a series devoted to identifying and explaining the properties of strongly correlating liquids, i.e., liquids where virial and potential energy correlate better than 90% in their thermal equilibrium fluctuations…

Soft Condensed Matter · Physics 2013-01-29 Nicoletta Gnan , Thomas B. Schrøder , Ulf R. Pedersen , Nicholas P. Bailey , Jeppe C. Dyre

Some experiments have witnessed increasing decoupling of viscosity from the translational self-diffusion of supercooled water with decreasing temperature. While theory and computer simulation studies indicated the jump translation of the…

Chemical Physics · Physics 2018-10-10 Shivam Dueby , Vikas Dubey , Snehasis Daschakraborty

In supercooled liquids, at a temperature between the glass transition temperature Tg and the melting point Tm, thermodynamic properties remain continuous, while dynamic behavior exhibits anomalies. The origin of such thermodynamics-dynamic…

Soft Condensed Matter · Physics 2025-06-17 X. R. Tian , D. M. Zhang , B. Zhang , D. Y. Sun , X. G. Gong

The viscosity of supercooled water has been a subject of intense study, in particular with respect to its temperature dependence. Much less is known, however, about the influence of dynamical effects on the viscosity in its supercooled…

Soft Condensed Matter · Physics 2020-04-15 Ingrid de Almeida Ribeiro , Maurice de Koning

Water keeps puzzling scientists because of its numerous properties which behave oppositely to usual liquids: for instance, water expands upon cooling, and liquid water is denser than ice. To explain this anomalous behaviour, several…

We investigate the temperature dependence of thermodynamic (density, isobaric heat capacity), dynamical (self-diffusion coefficient, shear viscosity), and dielectric properties of several water models, the commonly employed TIP3P water…

Soft Condensed Matter · Physics 2022-04-13 Tatiana I. Morozova , Nicolas A. Garcia , Jean-Louis Barrat

The viscosity of glass-forming liquids increases by many orders of magnitude if their temperature is lowered by a mere factor of 2-3 [1,2]. Recent studies suggest that this widespread phenomenon is accompanied by spatially heterogeneous…

Disordered Systems and Neural Networks · Physics 2015-05-28 Walter Kob , Sandalo Roldan-Vargas , Ludovic Berthier

The striking behavior of water has deserved it to be referred to as an "anomalous" liquid. The water anomalies are greatly amplified in metastable (supercooled/stretched) regions. This makes difficult a complete experimental description…

Statistical Mechanics · Physics 2016-08-24 Miguel A. Gonzalez , Chantal Valeriani , Frederic Caupin , Jose L. F. Abascal

We study causal viscous hydrodynamics in the context of central relativistic heavy-ion collisions and provide details of a straightforward numerical algorithm to solve the hydrodynamic equations. It is shown that correlation functions of…

Nuclear Theory · Physics 2008-11-26 Rudolf Baier , Paul Romatschke
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