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NaNiO$_2$ is a layered material consisting of alternating layers of NaO$_6$ and Jahn-Teller-active NiO$_6$ edge-sharing octahedra. At ambient pressure it undergoes a broad phase transition from a monoclinic to rhombohedral structure between…

Materials Science · Physics 2022-02-21 Liam A V Nagle-Cocco , Craig L Bull , Sian E Dutton , Christopher J Ridley

In transition metal oxides, quantum confinement arising from a large surface to volume ratio often gives rise to novel physico-chemical properties at nanoscale. Their size dependent properties have potential applications in diverse areas,…

Chemically _ driven isothermal close space vapour transport was used to prepare pure MoO2 films which were eventually converted to MoO3 by annealing in air. According to temperature_dependent Raman measurements, the MoO2/MoO3 phase…

Materials Science · Physics 2021-04-22 O. de Melo , Y. Gonzalez , A. Climent-Font , P. Galan , A. Ruediger , M. Sanchez , C. Calvo , G. Santana , V. Torres-Costa

Ferroelectric domain wall devices offer a promising route to low-voltage, reconfigurable nanoelectronics by confining currents to nanoscale conducting interfaces within an insulating bulk. However, the potential for resistive heating and…

The structure and the dielectric properties of Pb(Zn1/3Nb2/3)O3 (PZN) crystal have been investigated by means of high-resolution synchrotron x-ray diffraction (with an x-ray energy of 32 keV) and dielectric spectroscopy (in the frequency…

Materials Science · Physics 2009-11-10 Y. -H. Bing , A. A. Bokov , Z. -G. Ye , B. Noheda , G. Shirane

We have performed a temperature-dependent photoemission study of a NaxCoO2 (x~0.8) epitaxial thin film prepared by the reactive solid-phase epitaxy method. The chemical potential shift as a function of temperature was derived from the Co 3d…

Strongly Correlated Electrons · Physics 2007-10-11 Y. Ishida , H. Ohta , A. Fujimori , H. Hosono

Transmission electron microscopy study of tetragonal-like BiFeO3 films reveals a hitherto unreported hierarchical nanodomain structure. The 30-50 nm wide stripe domains with {110} domain walls consist of a substructure of lamellar…

Materials Science · Physics 2015-06-03 Yajun Qi , Zuhuang Chen , Lihua Wang , Xiaodong Han , Junling Wang , Thirumany Sritharan , Lang Chen

The ferroelectric to paraelectric phase transition in LiTaO$_3$ and in pure as well as Mg doped LiNbO$_3$ is investigated theoretically by atomistic calculations in the framework of the density functional theory, as well as experimentally…

The resistance of the electron gas at the interface between the two band insulators LaAlO3 (LAO) and SrTiO3 (STO) typically drops monotonically with temperature and R/T curves during cooling and warm-up look identical for large area…

Mesoscale and Nanoscale Physics · Physics 2017-03-21 M. Z. Minhas , A. Müller , F. Heyroth , H. H. Blaschek , G. Schmidt

Sol-gel deposited (010) textured polycrystalline thin films of gallium ferrite (GaFeO3 or GFO) on n-Si(100) and Pt/Si(111) substrates are characterized for room temperature multiferroism. Structural characterization using X-ray diffraction…

Materials Science · Physics 2016-11-04 Monali Mishra , Amritendu Roy , Ashish Garg , Rajeev Gupta , Somdutta Mukherjee

Knowledge of the electronic band structure of multiferroic oxides, crucial for the understanding and tuning of photo-induced effects, remains very limited even in the model and thoroughly studied BiFeO3. Here, we investigate the electronic…

It was experimentally found that the evolution of dielectric loss with processing temperature displays a common trend in ferroelectric and dielectric thin oxide films: firstly an increase and then a decrease in dielectric loss when the…

Materials Science · Physics 2009-11-13 X. H. Zhu , B. Guigues , E. Defay , M. Aid

A magneto-structural phase transition is investigated in single crystal CrN thin films grown by rf plasma molecular beam epitaxy on MgO(001) substrates. While still within the vacuum environment following MBE growth, $\it in-situ$…

Multiferroic materials open up the possibility to design novel functionality in electronic devices, with low energy consumption. However, there are very few materials that show multiferroicity at room temperature, which is essential to be…

The authors report on the interplay between magnetically ordered phases with temperature and magnetic field across compressively strained interfaces of thin La0.67Sr0.33MnO3 films on LaAlO3 substrates. From the temperature dependence of the…

Applied Physics · Physics 2019-03-04 Arjan A. Burema , Job J. L. van Rijn , Tamalika Banerjee

The current controversies about the existence of an intermediate 'beta' phase of BiFeO_3 and the high temperature paraelectric 'gamma' phase are resolved by studying the sequence of ferroic transitions in 0.8BiFeO_3-0.2Pb(Fe_1/2Nb_1/2)O_3…

Materials Science · Physics 2009-06-08 Jay Prakash Patel , Anar Singh , Dhananjai Pandey

Variable temperature scanning tunneling microscopy/spectroscopy studies on (110) oriented epitaxial thin films of La$_{0.350}$Pr$_{0.275}$Ca$_{0.375}$MnO$_3$ are reported in the temperature range of 77 to 340 K. The films, grown on lattice…

Strongly Correlated Electrons · Physics 2009-11-13 Udai Raj Singh , S. Chaudhuri , Shyam K. Choudhary , R. C. Budhani , Anjan K. Gupta

In this paper we study the size effects of the ferroelectric nanotube phase diagrams and polar properties allowing for effective surface tension and depolarization field influence. The approximate analytical expression for the…

Materials Science · Physics 2007-05-23 A. N. Morozovska , M. D. Glinchuk , E. A. Eliseev

We present a coordinated study of the paramagnetic-to-antiferromagnetic, rhombohedral-to-monoclinic, and metal-to-insulator transitions in thin-film specimens of the classic Mott insulator V$_2$O$_3$ using low-energy muon spin relaxation,…

In this work structural refinement, complex impedance spectroscopy, and Raman spectroscopy have been investigated on Na$_{0.5}$(Bi$_{1-x}$Dy$_x$)$_{0.5}$TiO$_3$ (xDyNBT) ceramic systems. The pure NBT, 2DyNBT and 5DyNBT compounds crystallize…