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We have investigated energies, magnetic dipole hyperfine structure constants ($A_{hyf}$) and electric dipole (E1) matrix elements of a number of low-lying states of the triply ionized tin (Sn$^{3+}$) by employing relativistic…

Atomic Physics · Physics 2020-04-22 Mandeep Kaur , Rishabh Nakra , Bindiya Arora , Cheng-Bin Li , B. K. Sahoo

Study and comparison of over 30 examples of electron doped BaFe2As2 for transition metal (TM) = Co, Ni, Cu, and (Co/Cu mixtures) have lead to an understanding that the suppression of the structural/antiferromagnetic phase transition to low…

Superconductivity · Physics 2009-08-04 P. C. Canfield , S. L. Bud'ko , N. Ni , J. Q. Yan , A. Kracher

We present accurate nonrelativistic ground-state energies of the transition metal atoms of the 3d series calculated with Fixed-Node Diffusion Monte Carlo (FN-DMC). Selected multi-determinantal expansions obtained with the CIPSI method…

Chemical Physics · Physics 2016-07-25 A. Scemama , T. Applencourt , E. Giner , M. Caffarel

In this work, we report results from our extensive spectroscopic study on AlF and AlCl molecules, keeping in mind potential laboratory as well as astrophysical applications. We carry out detailed electronic structure calculations in both…

Atomic Physics · Physics 2023-03-16 R. Bala , V. S. Prasannaa , D. Chakravarti , D. Mukherjee , B. P. Das

We report systematic first-principles calculations for ordered zinc-blende compounds of the transition metal elements V, Cr, Mn with the sp elements N, P, As, Sb, S, Se, Te, motivated by recent fabrication of zinc-blende CrAs, CrSb, and…

Materials Science · Physics 2009-11-07 Iosif Galanakis , Phivos Mavropoulos

We calculate binding energies of four molecular solids using the Hartree-Fock (HF) and second-order M{\o}ller-Plesset perturbation theory (MP2). We obtain the energies within many-body expansion (MBE) as well as using periodic boundary…

Chemical Physics · Physics 2022-08-15 J. Hofierka , J. Klimes

A precise theoretical study of the electronic structure of heavy atom diatomic molecules is of key importance to interpret the experiments in the search for violation of time-reversal (T) and spatial-parity (P) symmetries of fundamental…

Atomic Physics · Physics 2016-12-02 L. V. Skripnikov

The coupling of light to electrical charge carriers in semiconductors is the foundation of many technological applications. Attosecond transient absorption spectroscopy measures simultaneously how excited electrons and the vacancies they…

Materials Science · Physics 2023-05-03 Z. Schumacher , S. A. Sato , S. Neb , A. Niedermayr , L. Gallmann , A. Rubio , U. Keller

A systematic calculation for the transition form factors of heavy to light mesons ($B,B_s,D,D_s \to \pi, K, \eta, \rho, K^*, \omega, \phi$) is carried out by using light-cone sum rules in the framework of heavy quark effective field theory.…

High Energy Physics - Phenomenology · Physics 2008-11-26 Yue-Liang Wu , Ming Zhong , Ya-Bing Zuo

The transition metal nitride BaHfN$_2$, which consists of weakly bonded neutral slabs of closed shell ions, has structural and chemical similarities to other layered nitrides which have impressive superconducting T$_c$ when electron doped:…

Materials Science · Physics 2010-10-20 Amandeep Kaur , Erik R. Ylvisaker , Yan Li , Giulia Galli , Warren E. Pickett

Highly accurate theoretical predictions of transition energies in the radium monofluoride molecule, $^{226}$RaF and radium cation, $^{226}$Ra$^+$, are reported. The considered transition $X~^2\Sigma_{1/2} \to A~^2\Pi_{1/2}$ in RaF is one of…

Atomic Physics · Physics 2021-05-26 Leonid V. Skripnikov

Laser irradiation of materials is most commonly modeled with the two-temperature model (TTM), or its combination with molecular dynamics, TTM-MD. For such modeling, the electronic transport coefficients are required. Here, we calculate the…

Materials Science · Physics 2024-05-14 Nikita Medvedev , Fedor Akhmetov , Igor Milov

A direct measurement of the ground-state-to-ground-state electron-capture decay $Q$ ($Q_{\rm EC}$) value of $^{97}$Tc has been conducted employing the high resolving power phase-imaging ion-cyclotron-resonance technique with the double…

A robust potential wherein is embedded the crucial core polarization interaction is used in the Regge Pole methodology to calculate low energy electron elastic scattering total cross section (TCS) for the C60 fullerene in the electron…

Atomic and Molecular Clusters · Physics 2017-03-02 Z. Felfli , A. Z. Msezane

The band calculation scheme for $f$ electron compounds is developed on the basis of the dynamical mean field theory (DMFT) and the LMTO method. The auxiliary impurity problem is solved by a method named as NCA$f^{2}$v', which includes the…

Strongly Correlated Electrons · Physics 2009-11-11 O. Sakai , Y. Shimizu , Y. Kaneta

Previous first-principles calculations of the melting properties of Si, based on the local-density approximation (LDA) for electronic exchange-correlation energy, under-predict the melting temperature by ~ 20%. We present new…

Materials Science · Physics 2016-08-16 D. Alfè , M. J. Gillan

Charge self-consistent DFT+DMFT quantitatively captures dynamical electronic correlations in real materials, but its cost precludes the large-scale thermodynamic sampling required for phase boundaries and equations of state. Here, we…

Materials Science · Physics 2026-05-20 Rishi Rao , Li Zhu

The excitation energies and ionization potentials of the atoms in the first transition series are notoriously difficult to compute accurately. Errors in calculated excitation energies can range from 1--4 eV at the Hartree-Fock level, and…

chem-ph · Physics 2009-10-22 Thomas V. Russo , Richard L. Martin , P. Jeffrey Hay

We present a computational study of 2$p$ core-level X-ray photoemission spectra of transition metal monoxides MO (M=Ni, Co, Mn) and sesquioxides M$_2$O$_3$ (M=V, Cr, Fe) using a theoretical framework based on the local-density approximation…

Strongly Correlated Electrons · Physics 2017-07-19 Atsushi Hariki , Takayuki Uozumi , Jan Kuneš
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