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A central difficulty of state-specific Multi-Reference Coupled Cluster (MR-CC) formalisms concerns the definition of the amplitudes of the single and double excitation operators appearing in the exponential wave operator. If the reference…

Chemical Physics · Physics 2017-04-20 Yann Garniron , Emmanuel Giner , Jean-Paul Malrieu , Anthony Scemama

Estimating quantum amplitude, or the overlap between two quantum states, is a fundamental task in quantum computing and underpins numerous quantum algorithms. In this work, we introduce a novel algorithmic framework for quantum amplitude…

Quantum Physics · Physics 2025-02-27 Zhong-Xia Shang , Qi Zhao

The iteration dynamics of the coupled cluster equations exhibits a synergistic relationship among the cluster amplitudes. The iteration scheme may be viewed as a multivariate discrete-time propagation of nonlinearly coupled equations, which…

Computational Physics · Physics 2021-09-16 Valay Agarawal , Samrendra Roy , Kapil K. Shrawankar , Mayank Ghogale , S Bharathi , Anchal Yadav , Rahul Maitra

The cluster perturbation theory (CPT) is one of the simplest but systematic quantum cluster approaches to lattice models of strongly correlated electrons with local interactions. By treating the inter-cluster potential, in addition to the…

Strongly Correlated Electrons · Physics 2011-05-27 Matthias Balzer , Michael Potthoff

In this work, we investigate the possibility of improving multireference-driven coupled cluster (CC) approaches with an algorithm that iteratively combines complete active space (CAS) calculations with tailored CC and externally corrected…

Chemical Physics · Physics 2025-03-06 Robin Feldmann , Max Mörchen , Jakub Lang , Michał Lesiuk , Markus Reiher

The Principle of Maximum Conformality (PMC) provides scale-fixed perturbative QCD predictions which are independent of the choice of the renormalization scheme, as well as the choice of the initial renormalization scale. In this article, we…

High Energy Physics - Phenomenology · Physics 2017-08-22 Alexandre Deur , Jian-Ming Shen , Xing-Gang Wu , Stanley J. Brodsky , Guy F. de Teramond

Quantum embedding methods have recently developed significantly to model large molecular structures. This work proposes a novel wave function theory in density functional theory (WTF-in-DFT) embedding scheme based on pair-coupled cluster…

Chemical Physics · Physics 2024-01-10 Rahul Chakraborty , Katharina Boguslawski , Paweł Tecmer

Introducing an active space approximation is inevitable for the quantum computations of chemical systems. However, this approximation ignores the electron correlations related to non-active orbitals. Here, we propose a computational method…

Quantum Physics · Physics 2024-06-06 Luca Erhart , Yuichiro Yoshida , Viktor Khinevich , Wataru Mizukami

Applying a variational multiparticle-multihole configuration mixing method whose purpose is to include correlations beyond the mean field in a unified way without particle number and Pauli principle violations, we investigate pairing-like…

Nuclear Theory · Physics 2008-11-26 N. Pillet , J. -F. Berger , E. Caurier

One of the commonly used chemical-inspired approaches in variational quantum computing is the unitary coupled-cluster (UCC) ansatze. Despite being a systematic way of approaching the exact limit, the number of parameters in the standard UCC…

Quantum Physics · Physics 2023-06-06 Shashank G Mehendale , Bo Peng , Niranjan Govind , Yuri Alexeev

By using the coupled cluster method (CCM) and the numerical exact diagonalization (ED) method, we investigated the properties of the one quasi-one-dimensional coupled spin triangles. The results of ED disclose that the system is in the…

Strongly Correlated Electrons · Physics 2015-03-25 Jian-Jun Jiang , Yong-Jun Liu , Fei Tang , Cui-Hong Yang

In high-dynamic range (HDR) analog-to-digital converters (ADCs), having many quantization bits minimizes quantization errors but results in high bit rates, limiting their application scope. A strategy combining modulo-folding with a low-DR…

Signal Processing · Electrical Eng. & Systems 2023-11-23 Satish Mulleti , Resham Yashwanth Kumar , Laxmeesha Somappa

This paper studies computationally efficient methods and their minimax optimality for high-dimensional clustering and signal recovery under block signal structures. We propose two sets of methods, cross-block feature aggregation PCA…

Methodology · Statistics 2025-04-14 Wu Su , Yumou Qiu

Density functional theory (DFT) provides convenient electronic structure methods for the study of molecular systems and materials. Regular Kohn-Sham DFT calculations rely on unitary transformations to determine the ground-state electronic…

Chemical Physics · Physics 2022-10-10 Greta Jacobson , Juan M. Marmolejo-Tejada , Martín A. Mosquera

The accurate and efficient description of strongly correlated systems remains an important challenge for computational methods. Doubly occupied configuration interaction (DOCI), in which all electrons are paired and no correlations which…

Chemical Physics · Physics 2016-02-25 Thomas M. Henderson , Ireneusz W. Bulik , Gustavo E. Scuseria

Correlation Clustering is a classic clustering objective arising in numerous machine learning and data mining applications. Given a graph $G=(V,E)$, the goal is to partition the vertex set into clusters so as to minimize the number of edges…

Data Structures and Algorithms · Computer Science 2024-07-17 Vincent Cohen-Addad , David Rasmussen Lolck , Marcin Pilipczuk , Mikkel Thorup , Shuyi Yan , Hanwen Zhang

In the present work, the cluster radioactivity preformation probability Pc in the scheme of NpNn for the effective number of the valence particles (holes) in trans-lead nuclei has been systematically investigated. This quantity has been…

Nuclear Theory · Physics 2024-03-08 Lin-Jing Qi , Dong-Meng Zhang , Song Luo , Gui-Qing Zhang , Peng-Cheng Chu , Xi-Jun Wu , Xiao-Hua Li

Unitary coupled cluster (UCC) theory offers a promising Hermitian alternative to conventional coupled cluster (CC) theory, but its practical implementation is hindered by the non-truncating nature of the Baker-Campbell-Hausdorff (BCH)…

Chemical Physics · Physics 2025-05-05 Justin T. Phillips , Lauren N. Koulias , Stephen H. Yuwono , A. Eugene DePrince

The ionization potential (IP) is an important parameter providing essential insights into the reactivity of chemical systems. IPs are also crucial for designing, optimizing, and understanding the functionality of modern technological…

Chemical Physics · Physics 2024-02-12 Marta Gałyńska , Katharina Boguslawski

The Pairwise Markov Chain (PMC) is a probabilistic graphical model extending the well-known Hidden Markov Model. This model, although highly effective for many tasks, has been scarcely utilized for continuous value prediction. This is…

Machine Learning · Statistics 2025-08-12 Elie Azeraf
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