Related papers: The second law of thermodynamics as a deterministi…
We improve on our version of the second law of thermodynamics as a deterministic theorem for quantum spin systems in two basic aspects. The first concerns the general statement of the second law: spontaneous changes in an adiabatically…
In quantum statistical mechanics, equilibrium states have been shown to be the typical states for a system that is entangled with its environment, suggesting a possible identification between thermodynamic and von Neumann entropies. In this…
The second law of thermodynamics states that the entropy of an isolated system can only increase over time. This appears to conflict with the reversible evolution of isolated quantum systems under the Schr\"odinger equation, which preserves…
We treat a quantum mechanical system with certain general properties which are expected to be common in macroscopic quantum systems. Starting from a PURE initial state (which may not describe an equilibrium) in which energy is mildly…
The essence of the second law of classical thermodynamics is the `entropy principle' which asserts the existence of an additive and extensive entropy function, S, that is defined for all equilibrium states of thermodynamic systems and whose…
The 2nd law of thermodynamics yields an irreversible increase in entropy until thermal equilibrium is achieved. This irreversible increase is often assumed to require large and complex systems to emerge from the reversible microscopic laws…
It exists a large class of systems for which the traditional notion of extensivity breaks down. From experimental examples we induce two general hypothesis concerning such systems. In the first the existence of an internal coordinate system…
In a macroscopic (quantum or classical) Hamiltonian system, we prove the second law of thermodynamics in the forms of the minimum work principle and the law of entropy increase, under the assumption that the initial state is described by a…
A microscopic definition of the thermodynamic entropy in an isolated quantum system must satisfy (i) additivity, (ii) extensivity and (iii) the second law of thermodynamics. We show that the diagonal entropy, which is the Shannon entropy in…
We re-interprete the microcanonical conditions in the quantum domain as constraints for the interaction of the "gas-subsystem" under consideration and its environment ("container"). The time-average of a purity-measure is found to equal the…
Based on quantum statistical mechanics and microscopic quantum dynamics, we prove Planck's and Kelvin's principles for macroscopic systems in a general and realistic setting. We consider a hybrid quantum system that consists of the…
In the scientific and engineering literature, the second law of thermodynamics is expressed in terms of the behavior of entropy in reversible and irreversible processes. According to the prevailing statistical mechanics interpretation the…
The irreversible entropy increase described by the second law of thermodynamics is fundamentally tied to thermalization and the emergence of equilibrium. In the first part of our work (Ref: arXiv.2503.04152), we constructed an isolated gas…
This thesis investigates the connection between quantum theory, thermodynamics and information theory. Theories with structure similar to that of quantum theory are considered, mathematically described by the framework of "Generalized…
The second law of thermodynamics states that for a thermally isolated system entropy never decreases. Most physical processes we observe in nature involve variations of macroscopic quantities over spatial and temporal scales much larger…
We show that the conservation and the non-additivity of the information, together with the additivity of the entropy make the entropy increase in an isolated system. The collapse of the entangled quantum state offers an example of the…
A system composed of identical spins and described by a quantum mechanical pure state is analyzed within the statistical framework presented in Part I of this work. We explicitly derive the typical values of the entropy, of the energy, and…
The second law of thermodynamics is discussed and reformulated from a quantum information theoretic perspective for open quantum systems using relative entropy. Specifically, the relative entropy of a quantum state with respect to…
The second law of ordinary thermodynamics and the second law of steady state thermodynamics, as proposed by Oono and Paniconi, are investigated from the microscopic point of view for the open quantum system. Based on the H-theorem of…
The second law of thermodynamics states that the entropy of an isolated system is almost always increasing. We propose combinatorial formalizations of the second law and explore their conditions of possibilities.