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We have investigated the atomic and electronic structure of the ($\sqrt{3}\times \sqrt{3}$)$R30^{\circ}$ SnAu$_2$/Au(111) surface alloy. Low energy electron diffraction and scanning tunneling microscopy measurements show that the native…

Using a tight-binding model along with the mean-field Hubbard method, we investigate the effect of twisting angle on the magnetic properties of twisted bilayer graphene (tBLG) quantum dots (QDs) with triangular shape and zigzag edges. We…

Mesoscale and Nanoscale Physics · Physics 2023-04-14 M. Mirzakhani , H. C. Park , F. M. Peeters , D. R. da Costa

Diamondoids are a unique form of carbon nanostructure best described as hydrogen-terminated diamond molecules. Their diamond-cage structures and tetrahedral sp3 hybrid bonding create new possibilities for tuning electronic band gaps,…

The electronic properties of the two-dimensional (2D) $\alpha$ phase of antimonene are unique, featuring unpinned Dirac cones that can be moved with strain. Here we investigate the structural and electronic properties of an epitaxial 2D…

Accurate nanoscale detection of hydrogen is essential for understanding hydrogen-related phenomena in materials, yet conventional deuterium tracing is often complicated by residual background hydrogen. This study evaluates tritium as an…

We report on total-energy electronic structure calculations in the density-functional theory performed for the ultra-thin atomic layers of Si on Ag(111) surfaces. We find several distinct stable silicene structures:…

Mesoscale and Nanoscale Physics · Physics 2015-05-05 Zhi-Xin Guo , Atsushi Oshiyama

We present linear ensembles of dangling bond chains on a hydrogen terminated Si(100) surface, patterned in the closest spaced arrangement allowed by the surface lattice. Local density of states maps over a range of voltages extending…

Mesoscale and Nanoscale Physics · Physics 2016-07-21 John A. Wood , Mohammad Rashidi , Mohammad Koleini , Jason L. Pitters , Robert A. Wolkow

We investigate the electron transfer from a dissociatively adsorbed H2 molecule to a Au(111) surface using the first-principles methods. A fractional electron transfers from a molecule to a substrate, and potential energy increases during…

Materials Science · Physics 2009-11-13 Shigeyuki Takagi , Jun-ichi Hoshino , Hidekazu Tomono , Kazuo Tsumuraya

Phenalenyl is a radical nanographene with triangular shape that hosts an unpaired electron with spin S = 1/2. The open-shell nature of phenalenyl is expected to be retained in covalently bonded networks. Here, we study a first step in that…

Mesoscale and Nanoscale Physics · Physics 2023-07-20 N. Krane , E. Turco , A. Bernhardt , D. Jacob , G. Gandus , D. Passerone , M. Luisier , M. Juríček , R. Fasel , J. Fernández-Rossier , P. Ruffieux

Using Density functional theory (DFT) in conjunction with a solvation model we have investigated the phenomenon of eletrode-electrolyte interaction at the electrode surface and its consequences on the electrochemical properties like the…

Materials Science · Physics 2022-04-20 Mandira Das , Subhradip Ghosh

We have theoretically investigated the electronic and magnetic properties of graphene whose zigzag edges are oxidized. The alteration of these properties by adsorption of $\mathrm{H_{2}O}$ and $\mathrm{NH_3}$ molecules have been considered.…

Chemical Physics · Physics 2015-05-14 Julia Berashevich , Tapash Chakraborty

Graphene and its heterostructures exhibit interesting electronic properties and are explored for quantum spin Hall effect(QSHE) and magnetism based device applications. In present work, we propose a heterostructure of graphene encapsulated…

Materials Science · Physics 2019-10-07 Mohammed Ghadiyali , Sajeev Chacko

While the growth of germanene has been claimed on many substrates, the exact crystal structures remain controversial. Here, we systematically explore the possible structures formed by Ge deposition onto Al(111) surface by combining…

Materials Science · Physics 2022-08-17 Feini Yan , Shaogang Xu , Chao He , Changchun He , Changming Zhao , Hu Xu

We have studied the surface of pure and oxidized Pt$_3$Zr(0001) by scanning tunneling microscopy (STM), Auger electron microscopy, and density functional theory (DFT). The well-annealed alloy surface shows perfect long-range chemical order.…

The discrete and charge-separated nature of matter - electrons and nuclei - results in local electrostatic fields that are ubiquitous in nanoscale structures and are determined by their shape, material, and environment. Such fields are…

We have used scanning tunneling microscopy to study the structure of graphene islands on Au(111) grown by deposition of elemental carbon at 950{\deg}C. Consistent with low-energy electron microscopic observations, we find that the graphene…

Epitaxial silicene, which is one single layer of silicon atoms packed in a honeycomb structure, demonstrates a strong interaction with the substrate that dramatically affects its electronic structure. The role of electronic coupling in the…

Mesoscale and Nanoscale Physics · Physics 2014-12-08 Xun Xu , Jincheng Zhuang , Yi Du , Haifeng Feng , Nian Zhang , Chen Liu , Tao Lei , Jiaou Wang , Michelle Spencer , Tetsuya Morishita , Xiaolin Wang , Shi Xue Dou

The recent synthesis of nitrogen-doped monolayer amorphous carbon (MAC @N) opens new possibilities for multifunctional materials. In this study, we have investigated the nitrogen doping limits and their effects on MAC@N's structural and…

A conversion of AA- to AB-stacking bilayer graphene (BLG) due to interlayer interaction is demonstrated. Two types of interlayer interactions, an attractive and a repulsive, between the Boron and Nitrogen dopant atoms in BLG are found. In…

Mesoscale and Nanoscale Physics · Physics 2022-04-05 Nzar Rauf Abdullah , Hunar Omar Rashid , Chi-Shung Tang , Andrei Manolescu , Vidar Gudmundsson

Relative to conventional wet-chemical synthesis techniques, on-surface synthesis of organic networks in ultrahigh vacuum has few control parameters. The molecular deposition rate and substrate temperature are typically the only synthesis…

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