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The vast amount of computational studies on electrical conduction in solid-state electrolytes is not mirrored by comparable efforts addressing thermal conduction, which has been scarcely investigated despite its relevance to thermal…

Materials Science · Physics 2024-06-18 Davide Tisi , Federico Grasselli , Lorenzo Gigli , Michele Ceriotti

The dependence of the electrical conductivity on the oxygen partial pressure is calculated for the prototypical perovskite $\Ba\Ti\O_3$ based on data obtained from first-principles calculations within density functional theory. The…

Materials Science · Physics 2012-01-19 Paul Erhart , Karsten Albe

We report on the temperature dependence of thermal conductivity of single crystalline and polycrystalline organometallic perovskite CH3NH3PbI3. The comparable absolute values and temperature dependence of the two sample's morphologies…

Management of heat during charging and discharging of Li-ion batteries is critical for their safety, reliability, and performance. Understanding the thermal conductivity of the materials comprising batteries is crucial for controlling the…

Materials Science · Physics 2021-03-17 Zhe Cheng , Beniamin Zahiri , Xiaoyang Ji , Chen Chen , Darshan Chalise , Paul V. Braun , David G. Cahill

The glassy thermal conductivities observed in crystalline inorganic perovskites such as Cs$_3$Bi$_2$I$_6$Cl$_3$ is perplexing and lacking theoretical explanations. Here, we first experimentally measure such its thermal transport behavior…

Materials Science · Physics 2024-12-23 Zezhu Zeng , Zheyong Fan , Michele Simoncelli , Chen Chen , Ting Liang , Yue Chen , Geoff Thornton , Bingqing Cheng

Great success has been achieved in improving the photovoltaic energy conversion efficiency of the organic-inorganic perovskite-based solar cells, but with very limited knowledge on the thermal transport in hybrid perovskites, which would…

Materials Science · Physics 2016-03-02 Xin Qian , Xiaokun Gu , Ronggui Yang

Perovskite-based optoelectronic devices have shown great promise for solar conversion and other optoelectronic applications, but their long-term performance instability is regarded as a major obstacle to their widespread deployment.…

Crystals and glasses differ by the amplitude and the temperature dependence of their thermal conductivity. However, there are crystals known to display glass-like thermal conductivity. Here, we show that EuTiO$_3$, a quantum paraelectric…

The thermopower and thermal conductivity of superconducting perovskite $MgCNi_3$ ($T_c \approx$ 8 K) have been studied. The thermopower is negative from room temperature to 10 K. Combining with the negative Hall coefficient reported…

Superconductivity · Physics 2009-11-07 S. Y. Li , W. Q. Mo , M. Yu , W. H. Zheng , C. H. Wang , Y. M. Xiong , R. Fan , H. S. Yang , B. M. Wu , L. Z. Cao , X. H. Chen

In a neutral system such as liquid helium-3, transport of mass, heat, and spin provide information analogous to electrical counterparts in metals, superconductors and topological materials. Of particular interest is transport in strongly…

Other Condensed Matter · Physics 2020-10-28 D. Lotnyk , A. Eyal , N. Zhelev , T. S. Abhilash , E. N. Smith , M. Terilli , J. Wilson , E. Mueller , D. Einzel , J. Saunders , J. M. Parpia

We study the thermal diffusion coefficient DT of a charged colloid in a temperature gradient, and find that it is to a large extent determined by the thermoelectric response of the electrolyte solution. The thermally induced salinity…

Soft Condensed Matter · Physics 2014-01-30 Alois Würger

Layered perovskite lithium yttrium titanate ($\rm LiYTiO_4$) has recently emerged as a promising low-potential, ultrahigh-rate intercalation-type anode material for lithium-ion batteries; however, its lattice dynamics and thermal transport…

Materials Science · Physics 2025-12-09 Lin Zhang , Wen Liu , Mingquan He , Jun Huang

Using finite-temperature phonon calculations and machine-learning methods, we calculate the mechanical stability of about 400 semiconducting oxides and fluorides with cubic perovskite structures at 0 K, 300 K and 1000 K. We find 92…

Materials Science · Physics 2017-02-10 Ambroise van Roekeghem , Jesús Carrete , Corey Oses , Stefano Curtarolo , Natalio Mingo

We have performed optical microscopy, micro-photoelectron spectroscopy, and micro-Raman scattering measurements on Y$_{0.63}$Ca$_{0.37}$TiO$_3$ single crystals in order to clarify the interplay between the microstructure and the temperature…

Strongly Correlated Electrons · Physics 2018-12-04 R. German , B. Zimmer , T. C. Koethe , A. Barinov , A. C. Komarek , M. Braden , F. Parmigiani , P. H. M. van Loosdrecht

We performed large-scale molecular dynamics simulations based on a machine-learning force field (MLFF) to investigate the Li-ion transport mechanism in cation-disordered Li$_3$TiCl$_6$ cathode at six different temperatures, ranging from…

Materials Science · Physics 2024-06-19 Selva Chandrasekaran Selvaraj , Volodymyr Koverga , Anh T. Ngo

Lithium chloride LiCl is widely used as a prototype system to study the strongly dissociated 1-1 electrolyte solution. Here, we combined experimental measurements and classical molecular dynamics simulations to study the ion conduction in…

Soft Condensed Matter · Physics 2019-05-14 Are Yllö , Chao Zhang

The investigation of the structural phase transition in the vicinity of the Curie temperature $T_c$ of LiNb$_{1-x}$Ta$_x$O$_3$ crystals is motivated by the expected combination of advantageous high-temperature properties of LiNbO$_3$ and…

We report a detailed analytic and numerical study of electronic thermal conductivity in d-wave superconductors. We compare theory of the cross over at low temperatures from T-dependence to T^3-dependence for increasing temperature with…

Superconductivity · Physics 2009-11-11 Tomas Lofwander , Mikael Fogelstrom

Li$_2$ZrCl$_6$ (LZC) is a promising solid-state electrolyte due to its affordability, moisture stability, and high ionic conductivity. We computationally investigate the role of cation disorder in LZC and its effect on Li-ion transport by…

Materials Science · Physics 2025-03-11 Peichen Zhong , Sunny Gupta , Bowen Deng , KyuJung Jun , Gerbrand Ceder

We study the thermoelectric transport properties in the three-dimensional Anderson model of localization near the metal-insulator transition [MIT]. In particular, we investigate the dependence of the thermoelectric power S, the thermal…

Disordered Systems and Neural Networks · Physics 2009-10-31 C. Villagonzalo , R. A. Roemer , M. Schreiber
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