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We use computer simulations to study the glass transition of dense fluids made of polydisperse, repulsive spheres. For hard particles, we vary the volume fraction, phi, and use compressible particles to explore finite temperatures, T>0. In…

Statistical Mechanics · Physics 2009-08-25 Ludovic Berthier , Thomas A. Witten

Although much is known about the metastable liquid branch of hard spheres--from low dimension $d$ up to ${d\to\infty}$--its crystal counterpart remains largely unexplored for $d>3$. In particular, it is unclear whether the crystal phase is…

Statistical Mechanics · Physics 2022-05-03 Patrick Charbonneau , Caitlin M. Gish , Robert S. Hoy , Peter K. Morse

Finite-dimensional signatures of spinodal criticality are notoriously difficult to come by. The dynamical transition of glass-forming liquids, first described by mode-coupling theory, is a spinodal instability preempted by thermally…

Statistical Mechanics · Physics 2020-09-09 Ludovic Berthier , Patrick Charbonneau , Joyjit Kundu

We study the statistical mechanics of supercooled liquids when the system evolves at a temperature $T$ with a field $\epsilon$ linearly coupled to its overlap with a reference configuration of the same liquid sampled at a temperature $T_0$.…

Statistical Mechanics · Physics 2022-04-05 Benjamin Guiselin , Ludovic Berthier , Gilles Tarjus

We introduce fractal liquids by generalizing classical liquids of integer dimensions $d = 1, 2, 3$ to a fractal dimension $d_f$. The particles composing the liquid are fractal objects and their configuration space is also fractal, with the…

Statistical Mechanics · Physics 2015-08-31 Marco Heinen , Simon K. Schnyder , John F. Brady , Hartmut Löwen

We explore the nature of glass-formation in variable spatial dimensionality ($d$) based on the generalized entropy theory, a synthesis of the Adam-Gibbs model with direct computation of the configurational entropy of polymer fluids using an…

Soft Condensed Matter · Physics 2016-11-09 Wen-Sheng Xu , Jack F. Douglas , Karl F. Freed

Critical single-particle fluctuations associated with particle displacements are inherent to simple glass-forming liquids in the limit of large dimensions and leave a pseudo-critical trace across all finite dimensions. This characteristic…

Disordered Systems and Neural Networks · Physics 2024-08-14 Corentin C. L. Laudicina , Patrick Charbonneau , Yi Hu , Liesbeth M. C. Janssen , Peter K. Morse , Ilian Pihlajamaa , Grzegorz Szamel

Understanding glass formation is a challenge because the existence of a true glass state, distinct from liquid and solid, remains elusive: Glasses are liquids that have become too viscous to flow. An old idea, as yet unproven…

When a liquid freezes, a change in the local atomic structure marks the transition to the crystal. When a liquid is cooled to form a glass, however, no noticeable structural change marks the glass transition. Indeed, characteristic features…

Soft Condensed Matter · Physics 2015-11-24 Samuel S. Schoenholz , Ekin D. Cubuk , Daniel M. Sussman , Efthimios Kaxiras , Andrea J Liu

The nature of the glass transition is theoretically understood in the mean-field limit of infinite spatial dimensions, but the problem remains totally open in physical dimensions. Nontrivial finite-dimensional fluctuations are hard to…

Statistical Mechanics · Physics 2019-04-05 Ludovic Berthier , Patrick Charbonneau , Andrea Ninarello , Misaki Ozawa , Sho Yaida

The nature of glassy states in realistic finite dimensions is still under fierce debate. Lattice models can offer valuable insights and facilitate deeper theoretical understanding. Recently, a disordered-interacting lattice model with…

Soft Condensed Matter · Physics 2024-02-01 Bo Li , Chun-Shing Lee , Xin-Yuan Gao , Hai-Yao Deng , Chi-Hang Lam

An analysis of the dynamics is performed, of exactly solvable models for fragile and strong glasses, exploiting the partitioning of the free energy landscape in inherent structures. The results are compared with the exact solution of the…

Statistical Mechanics · Physics 2009-11-07 Luca Leuzzi , Theo M. Nieuwenhuizen

I briefly review a recent series of papers putting forward a coarse-grained theoretical approach to the physics of supercooled liquids approaching their glass transition. After a suitable coarse-graining, the dynamics of the liquid is…

Statistical Mechanics · Physics 2009-11-10 Ludovic Berthier

The structure, thermodynamics and slow activated dynamics of the equilibrated metastable regime of glass-forming fluids remains a poorly understood problem of high theoretical and experimental interest. We apply a highly accurate…

Soft Condensed Matter · Physics 2024-08-21 Subhashish Chaki , Baicheng Mei , Kenneth S. Schweizer

We propose a simple theory for the dynamics of model glass-forming fluids, which should be solvable using a mean-field-like approach. The theory is based on transparent physical assumptions, which can be tested in computer simulations. The…

Disordered Systems and Neural Networks · Physics 2017-10-18 Grzegorz Szamel

In this paper we propose a simple mean-field "toy" model for the liquid-glass phase transition. This is the system of $N$ point-like particles confined in a finite volume of a $D$-dimensional space interacting via infinite-range oscillating…

Disordered Systems and Neural Networks · Physics 2007-05-23 Victor Dotsenko

The systematic method to explore how the dynamics of strong liquids (S) is different from that of fragile liquids (F) near the glass transition is proposed from a unified point of view based on the mean-field theory discussed recently by…

Statistical Mechanics · Physics 2014-09-23 Michio Tokuyama , Shohei Enda , Junichi Kawamura

We present a mean field model for spin glasses with a natural notion of distance built in, namely, the Edwards-Anderson model on the diluted D-dimensional unit hypercube in the limit of large D. We show that finite D effects are strongly…

Disordered Systems and Neural Networks · Physics 2010-05-12 L. A. Fernandez , V. Martin-Mayor , G. Parisi , B. Seoane

The response of amorphous solids to an applied shear deformation is an important problem, both in fundamental and applied research. To tackle this problem, we focus on a system of hard spheres in infinite dimensions as a solvable model for…

Statistical Mechanics · Physics 2019-10-11 Ada Altieri , Francesco Zamponi

By means of a systematic expansion around the infinite-dimensional solution, we obtain an approximation scheme to compute properties of glasses in low dimensions. The resulting equations take as input the thermodynamic and structural…

Disordered Systems and Neural Networks · Physics 2016-01-25 Matthieu Mangeat , Francesco Zamponi