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A complex quantum system can be constructed by coupling simple quantum elements to one another. For example, trapped-ion or superconducting quantum bits may be coupled by Coulomb interactions, mediated by the exchange of virtual photons.…

Experimental studies indicate that optical cavities can affect chemical reactions, through either vibrational or electronic strong coupling and the quantized cavity modes. However, the current understanding of the interplay between…

We studied the interaction of a two-level atom with a frequency modulated cavity mode in an ideal optical cavity. The system, described by a Jaynes-Cumming Hamiltonian, gave rise to a set of stiff nonlinear first order equations solved…

Quantum Physics · Physics 2013-01-22 U. Pishipati , I. Almakremi , Amitabh Joshi , Juan D. Serna

In this work, we present a field-theoretic model of strongly coupled photonic molecules composed of interacting dielectric cavities in a closed, perfect-electric-conductor domain. Within this setting, we treat the resulting inter-mode…

Optics · Physics 2025-12-17 Kevin C. Smith , Austin G. Nixon , David J. Masiello

Molecular polaritons arise when molecules interact so strongly with light that they become entangled with each other. This light-matter hybridization alters the chemical and physical properties of the molecular system and allows chemical…

Chemical Physics · Physics 2023-07-28 Tor S. Haugland , John P. Philbin , Tushar K. Ghosh , Ming Chen , Henrik Koch , Prineha Narang

The prospect of controlling chemical reactivity using frequency-tunable optical microcavities has materialized over the past decade, evolving into a fascinating yet challenging new field of polaritonic chemistry, a multidisciplinary domain…

Chemical Physics · Physics 2025-10-07 Yaling Ke , Jakob Assan

We introduce a simple scheme to efficiently compute photon exchange-correlation contributions due to the coupling to transversal photons as formulated in the newly developed quantum-electrodynamical density functional theory (QEDFT). Our…

Quantum Physics · Physics 2018-04-16 Johannes Flick , Christian Schäfer , Michael Ruggenthaler , Heiko Appel , Angel Rubio

The manipulation of low-energy matter properties such as superconductivity, ferromagnetism and ferroelectricity via cavity quantum electrodynamics engineering has been suggested as a way to enhance these many-body collective phenomena. In…

An open question in experimental physics is the characterization of gravitational effects in quantum regimes. We propose an experimental set-up that uses well-tested techniques in cavity optomechanics to observe the effects of the…

Quantum Physics · Physics 2018-10-10 Abdulrahim Al Balushi , Wan Cong , Robert B. Mann

In this paper we develop quantum dynamical methods capable of treating the dynamics of chemically reacting systems in an optical cavity in the vibrationally strong-coupling (VSC) limit at finite temperatures and in the presence of a…

Quantum Physics · Physics 2025-02-11 Lachlan P. Lindoy , Arkajit Mandal , David R. Reichman

Since the photon box gedanken experiments of several of the founding fathers of modern physics, considerable progress has been made in differentiating the quantum and classical worlds. In this pursuit, the cavity as an open quantum system…

Quantum Physics · Physics 2014-12-02 Nathan D. Poulin

We demonstrate the effects of cavity quantum electrodynamics for a quantum dot coupled to a photonic molecule, consisting of a pair of coupled photonic crystal cavities. We show anti-crossing between the quantum dot and the two super-modes…

Mesoscale and Nanoscale Physics · Physics 2012-07-30 Arka Majumdar , Armand Rundquist , Michal Bajcsy , Jelena Vučković

Cavity quantum electrodynamics (QED) studies the interaction between a quantum emitter and a single radiation-field mode. When an atom is in strong coupling with a cavity mode1,2, it is possible to realize key quantum information processing…

Quantum Physics · Physics 2009-11-13 K. Hennessy , A. Badolato , M. Winger , D. Gerace , M. Atature , S. Gulde , S. Falt , E. L. Hu , A. Imamoglu

The development of reliable ab initio methods for light-matter strong coupling is necessary for a deeper understanding of molecular polaritons. The recently developed strong coupling quantum electrodynamics Hartree-Fock model (SC-QED-HF)…

Chemical Physics · Physics 2025-02-21 Matteo Castagnola , Rosario R. Riso , Yassir El Moutaoukal , Enrico Ronca , Henrik Koch

The search for experimental demonstrations of the quantum behavior of macroscopic mechanical resonators is a fastly growing field of investigation and recent results suggest that the generation of quantum states of resonators with a mass at…

Quantum Physics · Physics 2009-09-24 C. Genes , A. Mari , D. Vitali , P. Tombesi

Molecular polaritons have become an emerging platform for remotely controlling molecular properties through strong light-matter interactions. Herein, a semiclassical approach is developed for describing molecular polaritons by…

Chemical Physics · Physics 2022-04-19 Tao E. Li , Zhen Tao , Sharon Hammes-Schiffer

Through a non-perturbative quantum theory, we investigate how the quasi-electron excitations of a two-dimensional electron gas are modified by strong coupling to the vacuum field of a microcavity. We show that the electronic dressed states…

Quantum Physics · Physics 2009-11-13 Simone De Liberato , Cristiano Ciuti

In this thesis, we use classical, semi-classical and quantum-mechanical methods to simulate chemical reaction dynamics inside of an optical cavity. Within such a cavity, by selectively coupling vibrational modes of the reactants to the…

Chemical Physics · Physics 2024-02-08 Andrew C. Hunt

The ability to directly follow and time resolve the rearrangement of the nuclei within molecules is a frontier of science that requires atomic spatial and few-femtosecond temporal resolutions. While laser induced electron diffraction can…

Cavity quantum electrodynamics systems using atoms in resonant optical cavities are central elements of many applications such as quantum networks and quantum-enhanced sensing. We present a novel experimental setup that achieves strong…

Atomic Physics · Physics 2025-03-25 T. Olney , V. Naniyil , V. Boyer , J. Goldwin , A. B. Deb
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