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An efficient and expressive wavefunction ansatz is key to scalable solutions for complex many-body electronic structures. While Slater determinants are predominantly used for constructing antisymmetric electronic wavefunction ans\"{a}tze,…

Machine Learning · Computer Science 2024-11-12 Luca Thiede , Chong Sun , Alán Aspuru-Guzik

A fundamental problem in quantum physics is to encode functions that are completely anti-symmetric under permutations of identical particles. The Barron space consists of high-dimensional functions that can be parameterized by infinite…

Numerical Analysis · Mathematics 2023-03-24 Nilin Abrahamsen , Lin Lin

This paper concerns the long-standing question of representing (totally) anti-symmetric functions in high dimensions. We propose a new ansatz based on the composition of an odd function with a fixed set of anti-symmetric basis functions. We…

Classical Analysis and ODEs · Mathematics 2025-01-10 Ziang Chen , Jianfeng Lu

In quantum mechanics, the wave function of fermion systems such as many-body electron systems are anti-symmetric (AS) and continuous, and it is crucial yet challenging to find an ansatz to represent them. This paper addresses this challenge…

Quantum Physics · Physics 2024-03-01 Haotian Ye , Ruichen Li , Yuntian Gu , Yiping Lu , Di He , Liwei Wang

In this paper we analyze a recently proposed approach for the construction of antisymmetric functions for atomic and molecular systems. It is based on the assumption that the main problems with Hartree-Fock wavefunctions stem from their…

Quantum Physics · Physics 2019-06-18 Francisco M. Fernández

Representing fermionic wavefunctions efficiently is a central problem in quantum physics, chemistry and materials science. In this work, we introduce a universal and exact representation of continuous antisymmetric functions by lifting them…

Strongly Correlated Electrons · Physics 2025-10-14 Liang Fu

Direct approaches to the quantum many-body problem suffer from the so-called "curse of dimensionality": the number of parameters needed to fully specify the exact wavefunction grows exponentially with increasing system size. This motivates…

Quantum Physics · Physics 2023-04-21 Valerii Chuiko , Paul W. Ayers

In this work, dissipative quantum backflow is studied for a superposition of two stretched Gaussian wave packets and two identical spinless particles within the Caldirola-Kanai framework. Backflow is mainly an interference process and…

Quantum Physics · Physics 2020-09-30 S. V. Mousavi , S. Miret-Artés

Some notable systems, such as room-temperature superconductors and materials for controlled nuclear fusion, require an accurate description of finite-temperature quantum matter. Stochastic path integral methods are finite-temperature and…

Strongly Correlated Electrons · Physics 2026-04-06 Ingvars Vitenburgs , Jarvist Moore Frost

A way is presented to design quantum wave functions that exhibit backflow, namely negative probability current despite having a strictly positive spectrum of momentum. These wave functions are derived from rational complex functions which…

Quantum Physics · Physics 2023-08-21 Ioannis Chremmos

We present a formulation of quantum mechanics based on orthogonal polynomials. The wavefunction is expanded over a complete set of square integrable basis in configuration space where the expansion coefficients are orthogonal polynomials in…

Quantum Physics · Physics 2020-01-03 A. D. Alhaidari

We show that the use of the electromagnetic inverse source framework offers great flexibility in the design of metasurfaces. In particular, this approach is advantageous for antenna design applications where the goal is often to satisfy a…

Applied Physics · Physics 2019-10-17 Trevor Brown , Chaitanya Narendra , Yousef Vahabzadeh , Christophe Caloz , Puyan Mojabi

We provide an algorithm for the construction of orthonormal multivariate polynomials that are symmetric with respect to the interchange of any two coordinates on the unit hypercube and are constrained to the hyperplane where the sum of the…

High Energy Physics - Phenomenology · Physics 2014-12-24 S. S. Chabysheva , J. R. Hiller

Permutation-invariant, -equivariant, and -covariant functions and anti-symmetric functions are important in quantum physics, computer vision, and other disciplines. Applications often require most or all of the following properties: (a) a…

Neural and Evolutionary Computing · Computer Science 2020-07-31 Marcus Hutter

We derive for Bohmian mechanics topological factors for quantum systems with a multiply-connected configuration space Q. These include nonabelian factors corresponding to what we call holonomy-twisted representations of the fundamental…

Quantum Physics · Physics 2007-05-23 Detlef Duerr , Sheldon Goldstein , James Taylor , Roderich Tumulka , Nino Zanghi

The construction of fully (anti-)symmetric states with many particles, when the single particle state carries multiple quantum numbers, is a problem that seems to have not been systematically addressed in the literature. A quintessential…

High Energy Physics - Theory · Physics 2019-03-07 Chethan Krishnan , K. V. Pavan Kumar , P. N. Bala Subramanian

Quantum mechanics introduces the possibility for particles to move in a direction opposite to their momentum -- a counter-intuitive and classically impossible phenomenon known as quantum backflow. The magnitude of this effect is relatively…

Quantum Physics · Physics 2025-03-13 Maximilien Barbier , Arseni Goussev

Neural networks have shown to be a powerful tool to represent the ground state of quantum many-body systems, including fermionic systems. However, efficiently integrating lattice symmetries into neural representations remains a significant…

Strongly Correlated Electrons · Physics 2025-02-03 Imelda Romero , Jannes Nys , Giuseppe Carleo

The need to enforce fermionic antisymmetry in the nuclear many-body problem commonly requires use of single-particle coordinates, defined relative to some fixed origin. To obtain physical operators which nonetheless act on the nuclear…

Nuclear Theory · Physics 2020-12-02 M. A. Caprio , A. E. McCoy , P. J. Fasano

We suggest that low-lying eigenvalues of realistic quantum many-body hamiltonians, given, as in the nuclear shell model, by large matrices, can be calculated, instead of the full diagonalization, by the diagonalization of small truncated…

Nuclear Theory · Physics 2009-10-31 Mihai Horoi , Alexander Volya , Vladimir Zelevinsky
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