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We present a new wavefunction ansatz that combines the strengths of spin projection with the language of matrix product states (MPS) and matrix product operators (MPO) as used in the density matrix renormalization group (DMRG).…

Chemical Physics · Physics 2017-05-05 Zhendong Li , Garnet Kin-Lic Chan

We show that an optimized projection functions method can automatically construct maximally localized Wannier functions even for bands with nontrivial topology. We demonstrate this method on a tight-binding model of a two-dimensional…

Materials Science · Physics 2016-10-05 Jamal I. Mustafa , Sinisa Coh , Marvin L. Cohen , Steven G. Louie

We present a joint implementation of dynamical-mean-field theory (DMFT) with the pseudopotential plane-wave approach, via Wannier functions, for the determination of the electronic properties of strongly correlated materials. The scheme…

Strongly Correlated Electrons · Physics 2018-08-08 G. Trimarchi , I. Leonov , N. Binggeli , Dm. Korotin , V. I. Anisimov

The approximation properties of the finite element method can often be substantially improved by choosing smooth high-order basis functions. It is extremely difficult to devise such basis functions for partitions consisting of arbitrarily…

Numerical Analysis · Mathematics 2021-01-18 Eky Febrianto , Michael Ortiz , Fehmi Cirak

In this work we present a new basis set for electronic structures (Density Functional Theory (DFT)) calculations. This basis set extends Soler Williams Linearized Augmented Plane Wave (SLAPW) basis sets by allowing variable Muffin Tin (MT)…

Other Condensed Matter · Physics 2024-04-15 Garry Goldstein

We present a new code to evaluate thermoelectric and electronic transport properties of extended systems with a maximally-localized Wannier function basis set. The semiclassical Boltzmann transport equations for the homogeneous infinite…

Materials Science · Physics 2013-11-22 Giovanni Pizzi , Dmitri Volja , Boris Kozinsky , Marco Fornari , Nicola Marzari

We consider the applicability of phase space Wannier functions" to electronic structure calculations. These generalized Wannier functions are analogous to localized plane waves and constitute a complete, orthonormal set which is…

Other Condensed Matter · Physics 2010-07-22 D. J. Sullivan , J. J. Rehr , J. W. Wilkins , K. G. Wilson

A sequential quadratic programming (SQP) algorithm is designed for nonsmooth optimization problems with upper-C^2 objective functions. Upper-C^2 functions are locally equivalent to difference-of-convex (DC) functions with smooth convex…

Optimization and Control · Mathematics 2023-10-31 Jingyi Wang , Cosmin G. Petra

As a projection-free algorithm, Frank-Wolfe (FW) method, also known as conditional gradient, has recently received considerable attention in the machine learning community. In this dissertation, we study several topics on the FW variants…

Optimization and Control · Mathematics 2021-05-11 Mingrui Zhang

The popularity of local meshless methods in the field of numerical simulations has increased greatly in recent years. This is mainly due to the fact that they can operate on scattered nodes and that they allow a direct control over the…

Numerical Analysis · Mathematics 2022-06-29 Mitja Jančič , Gregor Kosec

We construct a Wannier basis for twisted bilayer graphene that is projected only from the Bloch functions of the twisted bilayer flat bands. The $C_3$ and $C_{2} \mathcal{T}$ symmetries act locally on the Wannier functions while the Wannier…

Mesoscale and Nanoscale Physics · Physics 2022-10-25 Jiawei Zang , Jie Wang , Antoine Georges , Jennifer Cano , Andrew J. Millis

We present a spin-dependent extension of the non-orthogonal generalized Wannier function (NGWF) formalism within the framework of linear-scaling density functional theory (LS-DFT) as implemented in the ONETEP code. In traditional LS-DFT…

We consider symmetry-projected Hartree--Fock trial wave functions in constrained-path Monte Carlo (CPMC) calculations. Previous CPMC calculations have mostly employed Hartree--Fock (HF) trial wave functions, restricted or unrestricted. The…

Strongly Correlated Electrons · Physics 2015-03-19 Hao Shi , Carlos A. Jiménez-Hoyos , R. Rodríguez-Guzmán , Gustavo E. Scuseria , Shiwei Zhang

When using Wannier functions to study the electronic structure of multi-parameter Hamiltonians $H^{(\boldsymbol k,\bf \lambda)}$ carrying a dependence on crystal momentum $\boldsymbol k$ and an additional periodic parameter $\bf\lambda$,…

Materials Science · Physics 2015-06-11 Jan-Philipp Hanke , Frank Freimuth , Stefan Blügel , Yuriy Mokrousov

We investigate the electronic structure of over-coordinated defects in amorphous silicon via density-functional total-energy calculations, with the aim of understanding the relationship between topological and electronic properties on a…

Materials Science · Physics 2007-05-23 M. Fornari , N. Marzari , M. Peressi , A. Baldereschi

Wannier interpolation is a powerful tool for performing Brillouin zone integrals over dense grids of $\mathbf{k}$ points, which are essential to evaluate such quantities as the intrinsic anomalous Hall conductivity or Boltzmann transport…

Materials Science · Physics 2021-02-22 Stepan S. Tsirkin

The localized nature of a flat band is understood by the existence of a compact localized eigenstate. However, the localization properties of a partially flat band, ubiquitous in surface modes of topological semimetals, have been unknown.…

Strongly Correlated Electrons · Physics 2023-12-25 Jin-Hong Park , Jun-Won Rhim

Accurate prediction of fundamental band gaps of crystalline solid state systems entirely within density functional theory is a long standing challenge. Here, we present a simple and inexpensive method that achieves this by means of…

We extend the Intrinsic Atomic Orbital (IAO) method for localisation of molecular orbitals to calculate well-localised generalised Wannier functions in crystals using the Pipek--Mezey locality metric. We furthermore present a one-shot…

Materials Science · Physics 2024-07-02 Andrew Zhu , David P. Tew

The problem of construction of the Wannier functions (WFs) in a restricted Hilbert space of eigenstates of the one-electron Hamiltonian $\hat{H}$ (forming the so-called low-energy part of the spectrum) can be formulated in several different…

Strongly Correlated Electrons · Physics 2007-05-23 I. V. Solovyev , Z. V. Pchelkina , V. I. Anisimov
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