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Stability and electronic properties of atomic layers of GaN are investigated in the framework of the van der Waals-density functional theory. We find that the ground state of the layered GaN is a planar graphene-like configuration rather…

Mesoscale and Nanoscale Physics · Physics 2013-02-22 Dongwei Xu , Haiying He , Ravindra Pandey , Shashi P. Karna

$\alpha$-graphyne is a two-dimensional sheet of $sp$-$sp^2$ hybridized carbon atoms in a honeycomb lattice. While the geometrical structure is similar to that of graphene, the hybridized triple bonds give rise to electronic structure that…

Materials Science · Physics 2017-08-04 Hyeondeok Shin , Jeongnim Kim , Hoonkyung Lee , Olle Heinonen , Anouar Benali , Yongkyung Kwon

When two-dimensional atomic layers of different materials are brought into close proximity to form van der Waals (vdW) heterostructures, interactions between adjacent layers significantly influence their physicochemical properties. These…

In this work, for the first time, a density functional theory (DFT) based comprehensive theoretical study is performed on the surface electronic properties of Bi2Se3 nanosheet in the presence of a surface capping layer as well as mechanical…

Materials Science · Physics 2024-12-10 Naresh Bahadursha , Banasree Sadhukhan , Tanay Nag , Swastik Bhattacharya , Sayan Kanungo

When two identical two-dimensional (2D) periodic lattices are stacked in parallel after rotating one layer by a certain angle relative to the other layer, the resulting bilayer system can lose lattice periodicity completely and become a 2D…

Mesoscale and Nanoscale Physics · Physics 2021-10-13 Hyunsoo Ha , Bohm-Jung Yang

Following the recent demonstration that van der Waals forces control the ferroelectric ordering of layers within nanoflakes and bulk samples of CuBiP2Se6 and CuInP2S6, it is demonstrated that they also control the internal geometrical…

Materials Science · Physics 2018-05-30 Sherif Abdulkader Tawfik , Jeffrey R. Reimers , Catherine Stampfl , Michael J. Ford

We employ first-principles density functional theory (DFT) calculations to investigate the structural, electronic, and catalytic properties of biphenylene supported on various metal substrates. The substrates considered are the (111)…

Searching for novel two-dimensional (2D) materials is highly desired in the field of nanoelectronics. We here propose a new 2D crystal barium tri-arsenide ($\mathrm{BaAs_3}$) with a series of encouraging functionalities. Being kinetically…

Materials Science · Physics 2024-09-17 Ping Tang , Jun-Hui Yuan , Ya-Qian Song , Ming Xu , Kan-Hao Xue , Xiang-Shui Miao

Controlling the size and shape of nanopores in two-dimensional materials is a key challenge in applications such as DNA sequencing, sieving, and quantum emission in artificial atoms. We here investigate experimentally and theoretically…

The structural stability, electronic properties and NH$_3$ adsorption properties of pristine, Ti, Zr and F substituted $\alpha$-MoO$_3$ nanostructures are successfully studied using density functional theory with B3LYP/LanL2DZ basis set.…

Mesoscale and Nanoscale Physics · Physics 2017-06-23 V. Nagarajan , R. Chandiramouli

In this contribution we present the results of Density-Functional Theory (DFT) calculations of platelets as modelled by infinite planar arrangements of hydrogen atoms and vacancies in (100) planes of silicon. From the observation of the…

Materials Science · Physics 2011-11-29 Liviu Bîlteanu , Jean-Paul Crocombette

Stable and metastable metallic nanoparticles exhibit unique properties compared to the bulk, with potentially important applications for catalysis. This is in particular the case for the AgPt alloy that can exhibit the ordered L1$_1$…

Materials Science · Physics 2023-07-11 F. Ait Hellal , J. Puibasset , C. Andreazza-Vignolle , P. Andreazza

Density-functional-theory (DFT) calculations have been performed on the Li-Si and Li-Ge systems. Lithiated Si and Ge, including their metastable phases, play an important technological r\^ole as Li-ion battery (LIB) anodes. The calculations…

Materials Science · Physics 2015-06-18 Andrew J. Morris , C. P. Grey , C. J Pickard

Atomic nanolines are one dimensional systems realized by assembling many atoms on a substrate into long arrays. The electronic properties of the nanolines depend on those of the substrate. Here, we demonstrate that to fully understand the…

Materials Science · Physics 2017-12-20 M. Longobardi , C. J. Kirkham , R. Villarreal , S. A. Koster , D. R. Bowler , Ch. Renner

The possibility to control the commensurability and distance between graphene layers separated by a dielectric spacer is considered by the example of a heterostructure consisting of double-layer graphene separated by atomic layers of argon.…

Mesoscale and Nanoscale Physics · Physics 2013-09-24 Andrey M. Popov , Irina V. Lebedeva , Andrey A. Knizhnik , Yurii E. Lozovik , Boris V. Potapkin

We examine the organization and dynamics of binary colloidal monolayers composed of micron-scale silica particles interspersed with smaller-diameter silica particles that serve as minority component impurities. These binary monolayers are…

Soft Condensed Matter · Physics 2023-05-22 Jonathan G. Raybin , Rebecca B. Wai , Naomi S. Ginsberg

Few-layer graphene systems come in various stacking orders. Considering tight-binding models for electrons on stacked honeycomb layers, this gives rise to a variety of low-energy band structures near the charge neutrality point. Depending…

Strongly Correlated Electrons · Physics 2012-11-07 Michael M. Scherer , Stefan Uebelacker , Daniel D. Scherer , Carsten Honerkamp

By using ab inito calculations within Density Functional Theory, we have explored the possible structures and various properties of porous AlN monolayer materials. Two kinds of porous AlN monolayer are identified, and the phonon dispersion…

Materials Science · Physics 2020-04-22 Yanwei Luo , Jiahui Hu , Yu Jia

Silicon (Si) anodes attract a lot of research attention for their potential to enable high energy density lithium-ion batteries (LIBs). Many studies focus on nanostructured Si anodes to counteract deterioration. In this work, we model LIBs…

Chemical Physics · Physics 2024-04-23 Franziska Kilchert , Max Schammer , Arnulf Latz , Birger Horstmann

Two-dimensional materials with ferroelectric properties break the size effect of conventional ferroelectric materials and unlock unprecedented potentials of ferroelectric-related application at small length scales. In this work, using…

Materials Science · Physics 2022-03-25 Bo Xu , Junkai Deng , Xiangdong Ding , Jun Sun , Jefferson Zhe Liu