Related papers: Dissipation and spontaneous emission in quantum el…
Ensemble density functional theory (EDFT) is a promising alternative to time-dependent density functional theory for computing electronic excitation energies. Using coordinate scaling, we prove several fundamental exact conditions in EDFT…
We investigate spontaneous photon emission and absorption processes of two two-level atoms trapped close to the focal points of an ellipsoidal cavity, thereby taking into account the full multimode scenario. In particular, we calculate the…
One of the paradigms of a small quantum system in a dissipative environment is the decay of an excited atom undergoing spontaneous photon emission into the fluctuating quantum electrodynamic vacuum. Recent experiments have demonstrated that…
The quantum dynamics of a simplest dissipative system, a particle moving in a constant external field , is exactly studied by taking into account its interaction with a bath of Ohmic spectral density. We apply the main idea and methods…
We experimentally perform the simulation of open quantum dynamics in single-qudit systems. Using a spatial light modulator as a dissipative optical device, we implement dissipative-dynamical maps onto qudits encoded in the transverse…
Partition Density Functional Theory (P-DFT) is a density embedding method that partitions a molecule into fragments by minimizing the sum of fragment energies subject to a local density constraint and a global electron-number constraint. To…
Density functional theory (DFT) embedding provides a formally exact framework for interfacing correlated wave-function theory (WFT) methods with lower-level descriptions of electronic structure. Here, we report techniques to improve the…
The exact exchange potential in time-dependent density-functional theory is defined as an orbital functional through the time-dependent optimized effective potential (TDOEP) method. We numerically solve the TDOEP integral equation for the…
Recent developments in generalized symmetries have provided new insights into quantum field theories. Within this framework, photons can be understood as Nambu-Goldstone modes associated with a spontaneously broken higher-form symmetry. In…
We derive analytical formulas for the forward emission and side emission spectra of cavity-modified single-photon sources, as well as the corresponding normal-mode oscillations in the cavity quantum electrodynamics (QED) strong-coupling…
The optimized effective potential (OEP) is the exact Kohn-Sham potential for explicitly orbital-dependent energy functionals, e.g., the exact exchange energy. We give a proof for the OEP equation which does not depend on the chain rule for…
Light-harvesting via the transport and trapping of optically-induced electronic excitations is of fundamental interest to the design of new energy efficient quantum technologies. Using a paradigmatic quantum optical model, we study the…
We introduce 'single-particle-exact density functional theory' (1pEx-DFT), a novel density functional approach that represents all single-particle contributions to the energy with exact functionals. Here, we parameterize interaction energy…
We present a rigorous formulation of the time-dependent density functional theory for interacting lattice electrons strongly coupled to cavity photons. We start with an example of one particle on a Hubbard dimer coupled to a single photonic…
Controlling atom-photon interactions in engineered environments is central to quantum optics and emerging quantum technologies. Non-Hermitian (NH) photonic baths, where dissipation fundamentally reshapes spectral and dynamical properties,…
Ground-state electronic structure calculations using Kohn-Sham density functional theory (KS-DFT) offer an unprecedented balance between efficiency and accuracy, now paradigmatic to the fields of quantum chemistry and condensed matter…
Various ways to analyze the dynamical response of clusters and molecules to electromagnetic perturbations exist. Particularly rich information can be obtained from measuring the properties of electrons emitted in the course of the…
Due to efficient scaling with electron number N, density functional theory (DFT) is widely used for studies of large molecules and solids. Restriction of an exact mean-field theory to local potential functions has recently been questioned.…
Several semilocal exchange potentials usually employed in the framework of density-functional theory (DFT) are tested and compared with their exact counterpart, the exchange Optimized Effective Potential (OEP), as applied to the…
The real-time electronic dynamics on material surfaces is critically important to a variety of applications. However, their simulations have remained challenging for conventional methods such as the time-dependent density-functional theory…