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Capacity and coulombic efficiency are often used to assess the performance of Li-ion batteries, under the assumption that these quantities can provide direct insights about the rate of electron consumption due to growth of the solid…

Chemical Physics · Physics 2022-11-11 Marco-Tulio Fonseca Rodrigues

Inactive lithium (Li) formation is the immediate cause of capacity loss and catastrophic failure of Li metal batteries. However, the chemical component and the atomic level structure of inactive Li have rarely been studied due to the lack…

The path toward Li-ion batteries with higher energy-densities will likely involve use of thin lithium metal (Li) anode (<50 $\mu$m in thickness), whose cyclability today remains limited by dendrite formation and low Coulombic efficiency.…

The existence of passivating layers at the interfaces is a major factor enabling modern lithium-ion (Li-ion) batteries. Their properties determine the cycle life, performance, and safety of batteries. A special case is the solid electrolyte…

Chemical Physics · Physics 2021-06-07 Zeeshan Ahmad , Victor Venturi , Hasnain Hafiz , Venkatasubramanian Viswanathan

Continuous solid electrolyte interface (SEI) formation remains the limiting factor of the lifetime of silicon nanoparticles (SiNPs) based negative electrodes. Methods that could provide clear diagnosis of the electrode degradation are of…

The reliability and safety of Lithium-ion batteries (LiBs) are of great concern in the energy storage industry. Nevertheless, the real-time monitoring of their degradation remains challenging due to limited quantitative metrics available…

High-energy-density lithium metal batteries require electrolytes that enable fast ion transport and form a stable solid-electrolyte interphase (SEI) to sustain high-rate cycling, a process that remains challenging to capture experimentally.…

Materials Science · Physics 2026-02-06 Syed Mustafa Shah , Mohammed Lemaalem , Anh T. Ngo

Understanding the mechanical interplay between silicon anodes and their surrounding solid-electrolyte interphase (SEI) is essential to improve the next generation of lithium-ion batteries. We model and simulate a 2D elliptical silicon…

Applied Physics · Physics 2024-09-13 Raphael Schoof , Lukas Köbbing , Arnulf Latz , Birger Horstmann , Willy Dörfler

Battery interfaces help govern rate capability, safety/stability, cycle life, and self-discharge, but significant gaps remain in our understanding at atomic length scales that can be exploited to improve interfacial properties. In…

Materials Science · Physics 2022-05-25 Kevin Leung , Laura C. Merrill , Katharine L. Harrison

With the rapid surge in the number of on-road Electric Vehicles (EVs), the amount of spent lithium-ion (Li-ion) batteries is also expected to explosively grow. The spent battery packs contain valuable metal and materials that should be…

Robotics · Computer Science 2023-03-15 Huanqing Wang , Kaixiang Zhang , Keyi Zhu , Ziyou Song , Zhaojian Li

Recently, Low Earth Orbit (LEO) satellites experience rapid development and satellite edge computing emerges to address the limitation of bent-pipe architecture in existing satellite systems. Introducing energy-consuming computing…

Systems and Control · Electrical Eng. & Systems 2022-03-14 Qing Li , Shangguang Wang , Xiao Ma , Ao Zhou , Fangchun Yang

The increased deployment of intermittent renewable energy generators opens up opportunities for grid-connected energy storage. Batteries offer significant flexibility but are relatively expensive at present. Battery lifetime is a key factor…

Systems and Control · Computer Science 2018-02-21 Jorn M. Reniers , Grietus Mulder , Sina Ober-Blobaum , David A. Howey

Real-life batteries tend to experience a range of operating conditions, and undergo degradation due to a combination of both calendar and cycling aging. Onboard health estimation models typically use cycling aging data only, and account for…

Machine Learning · Computer Science 2024-10-22 Muhammad Aadil Khan , Sai Thatipamula , Simona Onori

This paper presents a novel battery modeling framework based on the enhanced single particle model (ESPM) to account for degradation mechanisms of second-life batteries. While accounting for the transport and electrochemical phenomena in…

Systems and Control · Electrical Eng. & Systems 2021-08-19 Gabriele Pozzato , Seong Beom Lee , Simona Onori

As the core determinant of lithium-ion battery performance, electrode materials play a crucial role in defining the battery's capacity, cycling stability, and durability. During charging and discharging, electrode materials undergo complex…

Materials Science · Physics 2025-08-15 Liqi Wang , Ruijuan Xiao , Hong Li

The formation of passivating films is a common aging phenomenon, for example in weathering of rocks, silicon, and metals. In many cases, a dual-layer structure with a dense inner and a porous outer layer emerges. However, the origin of this…

Computational Physics · Physics 2022-12-01 Lars von Kolzenberg , Martin Werres , Jonas Tetzloff , Birger Horstmann

All-solid-state batteries are seen as promising candidates to replace conventional batteries with liquid electrolytes in many applications. However, they are not yet feasible for many relevant applications. One particular question of…

Chemical Physics · Physics 2023-07-06 Stephan Sinzig , Thomas Hollweck , Christoph P. Schmidt , Wolfgang A. Wall

Parameterisation of coupled degradation mechanisms in lithium-ion batteries is a major challenge. Interactions between the mechanisms depend on usage conditions: C-rate, rest state-of-charge (SoC), depth-of-discharge (DoD) and temperature.…

Materials Science · Physics 2026-04-13 Ganesh Madabattula

Lithium-ion batteries are recognised as a key technology to power electric vehicles and integrate grid-connected renewable energy resources. The economic viability of these applications is affected by the battery degradation during its…

Applied Physics · Physics 2020-07-07 Ahmed Gailani , Rehab Mokidm , Moaath El-Dalahmeh , Maad El-Dalahmeh , Maher Al-Greer

The penetration of the lithium-ion battery energy storage system (BESS) into the power system environment occurs at a colossal rate worldwide. This is mainly because it is considered as one of the major tools to decarbonize, digitalize, and…

Systems and Control · Electrical Eng. & Systems 2022-07-06 Anton V. Vykhodtsev , Darren Jang , Qianpu Wang , Hamidreza Zareipour , William D. Rosehart