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Rotating-wave approximation and its validity in multi-state quantum systems are studied through analytic approach. Their applicability is also verified from the viewpoint of generic states by the use of direct numerical integrations of the…

Chaotic Dynamics · Physics 2009-04-23 Toshiya Takami , Hiroshi Fujisaki

The similarity transformed equation of motion coupled cluster (STEOM-CC) method is benchmarked against CC3 and EOM-CCSDT-3 for a large test set of valence excited states of organic molecules studied by Schreiber et al. [M. Schreiber, M.R.…

Chemical Physics · Physics 2018-01-09 J. Sous , P. Goel , M. Nooijen

In order to study the structure of excited states we perform a variational calculation after spin parity projection (VAP) within the framework of Antisymmetrized Molecular Dynamics (AMD). The framework is proven to be a new powerful…

Nuclear Theory · Physics 2009-11-07 Y. Kanada-En'yo

Strongly coupled quantum field theories in $(1+1)$ dimensions are notoriously hard to solve non-perturbatively. Variational methods, despite their success for quantum many-body physics on the lattice, have long lacked a natural ansatz…

High Energy Physics - Theory · Physics 2026-04-14 Antoine Tilloy

We study the ground state and the first three radially excited states of a self-gravitating Bose-Einstein- Condensate with respect to the influence of two external parameters, the total mass and the strength of interactions between…

General Relativity and Quantum Cosmology · Physics 2015-12-09 Kris Schroven , Meike List , Claus Lämmerzahl

We establish a large deviation principle for the empirical measure process associated with a general class of finite-state mean field interacting particle systems with Lipschitz continuous transition rates that satisfy a certain ergodicity…

Probability · Mathematics 2016-01-26 Paul Dupuis , Kavita Ramanan , Wei Wu

We present a reduced-cost equation-of-motion coupled-cluster method for excited states, built on a new state-specific frozen natural orbital (SS-FNO) framework. This approach enables systematic and controllable truncation of the virtual…

Chemical Physics · Physics 2025-07-24 Amrita Manna , Achintya Kumar Dutta

Variational excited-state density functional theory (DFT) enables the calculation of excited states at a cost comparable to ground-state calculations, but single-configuration approaches often suffer from spin contamination. We implement…

Chemical Physics · Physics 2026-05-28 Michael J. Sahre , Marco Romanelli , Martijn Marsman , Leticia González , Georg Kresse

This paper presents a nonperturbative treatment of strong-coupling induced effects in atom-field systems which cannot be seen in traditional perturbative treatments invoking compromising assumptions such as the Born-Markov, rotating wave or…

Quantum Physics · Physics 2020-02-25 Jen-Tsung Hsiang , Bei-Lok Hu

We develop a variational formalism in order to study the structure of low energy spectra of frustrated quantum spin systems. It is first applied to trial wavefunctions of ladders with one spin-1/2 on each site. We determine energy minima of…

Strongly Correlated Electrons · Physics 2007-05-23 Jean Richert

Based on the work of Gorling and that of Levy and Nagy, density-functional formalism for many Fermionic excited-states is explored through a careful and rigorous analysis of the excited-state density to external potential mapping. It is…

Materials Science · Physics 2009-11-11 Prasanjit Samal , Manoj K. Harbola

We introduce a combination of coherent states as variational test functions for the atomic and radiation sectors to describe a system of Na three- level atoms interacting with a one-mode quantised electromagnetic field, with and without the…

Quantum Physics · Physics 2015-10-22 R. López-Peña , S. Cordero , E. Nahmad-Achar , O. Castaños

Artificial neural networks have been recently introduced as a general ansatz to compactly represent many- body wave functions. In conjunction with Variational Monte Carlo, this ansatz has been applied to find Hamil- tonian ground states and…

Strongly Correlated Electrons · Physics 2018-10-24 Kenny Choo , Giuseppe Carleo , Nicolas Regnault , Titus Neupert

We provide a detailed formulation of the recently proposed variational approach [Y. Ashida et al., Phys. Rev. Lett. 121, 026805 (2018)] to study ground-state properties and out-of-equilibrium dynamics for generic quantum spin-impurity…

Strongly Correlated Electrons · Physics 2018-07-13 Yuto Ashida , Tao Shi , Mari Carmen Bañuls , J. Ignacio Cirac , Eugene Demler

We describe a variational method to solve the Holstein model for an electron coupled to dynamical, quantum phonons on an infinite lattice. The variational space can be systematically expanded to achieve high accuracy with modest…

Strongly Correlated Electrons · Physics 2009-10-31 J. Bonca , S. A. Trugman , I. Batistic

Determining the steady state of an open quantum system is crucial for characterizing quantum devices and studying various physical phenomena. Often, computing a single steady state is insufficient, and it is necessary to explore its…

Quantum Physics · Physics 2026-04-09 André Melo , Gaspard Beugnot , Fabrizio Minganti

The calculation of excited state energies of electronic structure Hamiltonians has many important applications, such as the calculation of optical spectra and reaction rates. While low-depth quantum algorithms, such as the variational…

Quantum Physics · Physics 2019-07-03 Oscar Higgott , Daochen Wang , Stephen Brierley

The study of ground-state properties of the Fermi-Hubbard model is a long-lasting task in the research of strongly correlated systems. Owing to the exponentially growing complexity of the system, a quantitative analysis usually demands high…

Strongly Correlated Electrons · Physics 2023-08-15 Yue-Ran Shi , Yuan-Yao He , Ruijin Liu , Wei Zhang

It is shown that when the well-known minimal complementary energy variational principle in linear elastostatics is written in a different form with the strain tensor as an independent variable and the constitutive relation as one of the…

Classical Physics · Physics 2024-09-12 Jiashi Yang

Variational wave function ansatze are an invaluable tool to study the properties of strongly correlated systems. We propose such a wave function, based on the theory of auxiliary fields and combining aspects of auxiliary-field quantum Monte…

Strongly Correlated Electrons · Physics 2024-03-13 Ryan Levy , Miguel A. Morales , Shiwei Zhang