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The essential postulates of classical thermodynamics are formulated, from which the second law is deduced as the principle of increase of entropy in irreversible adiabatic processes that take one equilibrium state to another. The entropy…

Soft Condensed Matter · Physics 2009-10-30 Elliott H. Lieb , Jakob Yngvason

It exists a large class of systems for which the traditional notion of extensivity breaks down. From experimental examples we induce two general hypothesis concerning such systems. In the first the existence of an internal coordinate system…

Statistical Mechanics · Physics 2015-03-09 J-P. Badiali , A. El Kaabouchi

In textbooks on statistical mechanics, one finds often arguments based on classical mechanics, phase space and ergodicity in order to justify the second law of thermodynamics. However, the basic equations of motion of classical mechanics…

Statistical Mechanics · Physics 2014-08-28 Barbara Drossel

This article is a short version of a longer article to appear in Physics Reports (cond-mat/9708200). The essential postulates of classical thermodynamics are formulated, from which the second law is deduced as the principle of increase of…

Mathematical Physics · Physics 2007-05-23 Elliott H. Lieb , Jakob Yngvason

We provide a characterization of energy in the form of exchanged heat and work between two interacting constituents of a closed, bipartite, correlated quantum system. By defining a binding energy we derive a consistent quantum formulation…

Quantum Physics · Physics 2016-10-25 S. Alipour , F. Benatti , F. Bakhshinezhad , M. Afsary , S. Marcantoni , A. T. Rezakhani

Quantum correlation, or entanglement, is now believed to be an indispensable physical resource for certain tasks in quantum information processing, for which classically correlated states cannot be useful. Besides information processing,…

Quantum Physics · Physics 2009-11-10 K. Maruyama , F. Morikoshi , V. Vedral

We consider a generalisation of thermodynamics that deals with multiple conserved quantities at the level of individual quantum systems. Each conserved quantity, which, importantly, need not commute with the rest, can be extracted and…

Quantum Physics · Physics 2016-07-14 Yelena Guryanova , Sandu Popescu , Anthony J. Short , Ralph Silva , Paul Skrzypczyk

We have presented a set of laws of entanglement thermodynamics for $T\bar{T}$-deformed CFTs and in general for $T^2$-deformed field theories. In particular, the first law of this set, states that although we are dealing with a non-trivial…

High Energy Physics - Theory · Physics 2023-02-21 Kuroush Allameh , Amin Faraji Astaneh

The second law of thermodynamics states that entropy increases (or does not change) by time in an isolated system. As microscopic physical laws are reversible, the origin of irreversibility is not straightforward. Although the outcome of a…

Statistical Mechanics · Physics 2013-02-19 Balint Szabo

In the classical regime, thermodynamic state transformations are governed by the free energy. This is also called as the second law of thermodynamics. Previous works showed that, access to a catalytic system allows us to restore the second…

Quantum Physics · Physics 2025-03-20 Tulja Varun Kondra , Ray Ganardi , Alexander Streltsov

Reciprocal relations correlate fairly accurately a great variety of experimental results. Nevertheless, the concepts of statistical fluctuations, and microscopic reversibility - the bases of the accepted proof of the relations by Onsager -…

Chemical Physics · Physics 2007-05-23 Elias P. Gyftopoulos

Entanglement and entropy are key concepts standing at the foundations of quantum and statistical mechanics, respectively. In the last decade the study of quantum quenches revealed that these two concepts are intricately intertwined.…

Strongly Correlated Electrons · Physics 2017-08-21 Vincenzo Alba , Pasquale Calabrese

The first law of thermodynamics imposes not just a constraint on the energy-content of systems in extreme quantum regimes, but also symmetry-constraints related to the thermodynamic processing of quantum coherence. We show that this…

Quantum Physics · Physics 2015-04-15 Matteo Lostaglio , Kamil Korzekwa , David Jennings , Terry Rudolph

Entanglement entropy is often speculated as a strong candidate for the origin of the black-hole entropy. To judge whether this speculation is true or not, it is effective to investigate the whole structure of thermodynamics obtained from…

General Relativity and Quantum Cosmology · Physics 2009-10-30 Shinji Mukohyama , Masafumi Seriu , Hideo Kodama

The first law of thermodynamics restates the law of conservation of energy. It partitions the change in energy of a system into two pieces, heat and work. While there is no ambiguity to define heat and work in classical thermodynamics,…

Quantum Physics · Physics 2023-01-19 Xue-Qun Yan , Yan-Jiao Du , Wen-Tao Hou , Xiao-Ming Liu

The role of quantum entanglement in thermodynamical systems remains elusive. Does entanglement result in thermodynamic advantages or does it impose fundamental limitations? Here, we unambiguously quantify the amount of heat and work in a…

Quantum Physics · Physics 2026-03-23 Joan Alba , Laura Ares , Jan Sperling , Julien Pinske

The essence of the second law of classical thermodynamics is the `entropy principle' which asserts the existence of an additive and extensive entropy function, S, that is defined for all equilibrium states of thermodynamic systems and whose…

Mathematical Physics · Physics 2007-05-23 Elliott H. Lieb , Jakob Yngvason

Quantum theory makes the most accurate empirical predictions and yet it lacks simple, comprehensible physical principles from which the theory can be uniquely derived. A broad class of probabilistic theories exist which all share some…

Quantum Physics · Physics 2012-04-17 Borivoje Dakic , Caslav Brukner

We show that the conservation and the non-additivity of the information, together with the additivity of the entropy make the entropy increase in an isolated system. The collapse of the entangled quantum state offers an example of the…

Quantum Physics · Physics 2009-11-13 Qi-Ren Zhang

Thermodynamics at the nanoscale is known to differ significantly from its familiar macroscopic counterpart: the possibility of state transitions is not determined by free energy alone, but by an infinite family of free-energy-like…

Quantum Physics · Physics 2018-12-21 Markus P. Mueller