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Related papers: Origin of C$_{60}$ surface reconstruction resolved…

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Single crystals of C$_{60}$ saturated with molecular hydrogen and nitrogen were studied using the spectral-luminescent method of registration in the quantum counting mode at a low temperature of 20 K. Previously, it was found that the…

Chemical Physics · Physics 2026-02-12 Victor Zoryansky , Peter Zinoviev , Yuri Semerenko

In this paper, we evaluate of the adsorption/ desorption of ammonia molecules on a graphene surface by studying the Fermi level shift. Based on a physically plausible model, the adsorption and desorption rates of ammonia molecules on…

Mesoscale and Nanoscale Physics · Physics 2015-05-19 Shanshan Chen , Weiwei Cai , David Chen , Yujie Ren , Xuesong Li , Yanwu Zhu , Rodney S. Ruoff

The adsorption of metal atoms on nanostructures, such as graphene and nanotubes, plays an important role in catalysis, electronic doping, and tuning material properties. Quantum chemical calculations permit the investigation of this process…

Mesoscale and Nanoscale Physics · Physics 2020-02-18 Christoph Rohmann , Maicol A. Ochoa , Michael Zwolak

Copper is a good CO2 electroreduction catalyst as products beyond CO form, but efficiency and selectivity is low. Experiments have shown that admixture of other elements can help, and computational screening studies have pointed out various…

Enhanced optical absorption of molecules in the vicinity of metallic nanostructures is key to a number of surface-enhanced spectroscopies and of great general interest to the fields of plasmonics and nano-optics. Yet, experimental access to…

We have investigated the electronic properties of a C_60 molecule in between carbon nanotube leads. This problem has been tackled within a quantum chemical treatment utilizing a density functional theory-based LCAO approach combined with…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 G. Cuniberti , R. Gutierrez , G. Fagas , F. Grossmann , K. Richter , R. Schmidt

The observed anisotropies of surface vibrations for unreconstructed FCC metal (110) surfaces are often reversed from the "common sense" expectation. The source of these reversals is investigated by performing ab initio density functional…

Materials Science · Physics 2009-10-31 Shobhana Narasimhan

We report total-energy calculations based on the density-functional theory that clarify microscopic mechanisms of initial stage of graphene formation on the SiC(0001) surface. We explore favorable reactions for desorption of either Si or C…

Materials Science · Physics 2016-11-21 Fumihiro Imoto , Jun-Ichi Iwata , Mauro Boero , Atsushi Oshiyama

The behavior of a polyelectrolyte adsorbed on a charged substrate of high-dielectric constant is studied by both Monte-Carlo simulation and analytical methods. It is found that in a low enough ionic strength medium, the adsorption…

Soft Condensed Matter · Physics 2007-05-23 Chi-Ho Cheng , Pik-Yin Lai

We report on results of a theoretical study of the adsorption process of a single carbon oxide molecule on a Platinum (111) surface. A four-component relativistic density functional method was applied to account for a proper description of…

Atomic and Molecular Clusters · Physics 2009-11-07 D. Geschke , T. Bastug , T. Jacob , S. Fritzsche , W. -D. Sepp , B. Fricke

The electronic structure and absorption spectrum of hydrogenated silicon carbide nanocrystals (SiCNC) have been determined by first principles calculations. We show that the reconstructed surface can significantly change not just the onset…

Materials Science · Physics 2015-05-13 Márton Vörös , Péter Deák , Thomas Frauenheim , Adam Gali

The Cu nanowires were electrodeposited in polycarbonate track-etched (PCT) membrane. SEM, TEM and XPS techniques were used to characterize the morphology, structure and size of nanowires as well as chemical Composition. The absorption…

Mesoscale and Nanoscale Physics · Physics 2012-07-17 A. Azariana , F. Babaei

The thermal desorption of ammonia (NH$_3$) from single crystal forsterite (010) has been investigated using temperature-programmed desorption. The effect of defects on the desorption process has been probed by the use of a rough cut…

Solar and Stellar Astrophysics · Physics 2015-10-21 T. Suhasaria , J. D. Thrower , H. Zacharias

This work presents the experimental demonstration of total absorption by a metal-dielectric metasurface. Following the theoretical proposal [A. D\'iaz-Rubio et al. Phys. Rev. B 89, 245123 (2014)], we fabricated a metasurface consisting of a…

The interaction of metals with carbon materials, specifically with graphene, is of importance for various technological applications. In particular, intercalation of alkali metals is believed to provide a means for tuning the electronic…

Mesoscale and Nanoscale Physics · Physics 2023-01-26 Marianna Lorenzo , Conrad Escher , Tatiana Latychevskaia , Hans-Werner Fink

Recent I/V curve measurements suggest that C60 molecules deposited in gold nanojunctions change their adsorption configuration when a finite voltage in a 2-terminal setting is applied. This is of interest for molecular electronics because a…

Materials Science · Physics 2015-06-25 R. Stadler , S. Kubatkin , T. Bjornholm

The results are presented of a detailed combined experimental and theoretical investigation of the influence of coadsorbed electron-donating alkali atoms and the prototypical electron acceptor molecule TCNQ…

Graphene nanostructures that support surface plasmons have been utilized to create a variety of dynamically tunable light modulators, motivated by theoretical predictions of the potential for unity absorption in resonantly-excited monolayer…

The geometrical and electronic properties of the monolayer (ML) of tetracene (Tc) molecules on Ag(111) are systematically investigated by means of DFT calculations with the use of localized basis set. The bridge and hollow adsorption…

Mesoscale and Nanoscale Physics · Physics 2016-11-09 N. L. Zaitsev , I. A. Nechaev , U. Höfer , E. V. Chulkov

Using the highly localized current of electrons tunneling through a double barrier Scanning Tunneling Microscope (STM) junction, we excite luminescence from a selected C$_{60}$ molecule in the surface layer of fullerene nanocrystals grown…

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