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Transition-metal oxides offer an opportunity to explore unconventional superconductors, where the superconductivity (SC) is often interrelated with novel phenomena such as spin/charge order, fluctuations, and Fermi surface instability…

LiTi2O4 is a unique material in that it is the only known oxide spinel superconductor. Although bulk studies have demonstrated that superconductivity can be generally described by the Bardeen-Cooper-Schreiffer theory, the microscopic…

Superconductivity · Physics 2010-05-27 Rajesh V. Chopdekar , Elke Arenholz , Yuri Suzuki

Among hundreds of spinel oxides, LiTi2O4 (LTO) is the only one that exhibits superconductivity (Tc ~13 K). Although the general electron-phonon coupling is still the main mechanism for electron pairing in LTO, unconventional behaviors such…

High-field electrical transport and point-contact tunneling spectroscopy were used to investigate superconducting properties of the unique spinel oxide, LiTi$_2$O$_{4-\delta}$ films with various oxygen content. We find that the upper…

Spinel compounds have demonstrated rich functionalities but rarely shown superconductivity. Here, we report the emergence of superconductivity in the spinel $\mathrm{MgTi}_2\mathrm{O}_4$, known to be an insulator with a complicated order.…

Spinel oxides are well-known functional materials but rarely show superconductivity. Recently, emergent superconductivity was discovered in MgTi$_2$O$_4$, which is attributed to the increase of electron doping and the suppression of orbital…

Superconductivity · Physics 2023-03-23 Qizhi Li , Abhishek Nag , Xiquan Zheng , Fucong Chen , Jie Yuan , Kui Jin , Yi Lu , Ke-Jin Zhou , Yingying Peng

This review discusses the multifaceted electronic properties of spinel oxides with a particular focus on Lithium Vanadate (LiV2O4), Lithium Titanate (LiTi2O4), and Magnesium Titanate (MgTi2O4). We selected LiTi2O4, LiV2O4, and MgTi2O4…

Materials Science · Physics 2025-12-03 Jagadis Prasad Nayak , Raju Saini , Sourav Dash , Gopi Nath Daptary

A systematic study is performed on the spinel oxide, i.e. LiTi2O4 thin films oriented along [111]-, [110]-, and [001]-directions, to reveal the crystallographic dependence of transport properties. With decreasing temperature, the LiTi2O4…

Superconductivity · Physics 2016-08-25 Yanli Jia , Ge He , Heshan Yu , Wei Hu , Zhenzhong Yang , Jinan Shi , Zefeng Lin , Jie Yuan , Beiyi Zhu , Kai Liu , Lin Gu , Hong Li , Kui Jin

Superconductivity in the family of spinel oxides is very rare owing to their robust Mott-insulating nature. About half a century ago, LiTi$_2$O$_4$ became the first reported spinel compound to show superconductivity with a 12K transition…

Superconductivity · Physics 2023-05-16 Dibyendu Dey , T. Maitra , A. Taraphder

The associations between emergent physical phenomena (e.g., superconductivity) and orbital, charge, and spin degrees of freedom of $3d$ electrons are intriguing in transition metal compounds. Here, we successfully manipulate the…

Around fifty years ago, LiTi$_2$O$_4$ was reported to be first spinel oxide to exhibit a superconducting transition with highest T$_c$ $\approx$ 13.7 K. Recently, MgTi$_2$O$_4$ has been found to be the only other spinel oxide to reveal a…

Superconductivity · Physics 2023-06-27 A. Rahaman , T. Paramanik , B. Pal , R. Pal , P. Maji , K. Bera , S. Mallik , D. K. Goswami , A. N. Pal , D. Choudhury

Geometrically frustrated lattices can display a range of correlated phenomena, ranging from spin frustration and charge order to dispersionless flat bands due to quantum interference. One particularly compelling family of such materials is…

The spinel oxide superconductor LiTi2O4 (LTO) is an intriguing material platform where the electronic structure near the Fermi energy (EF) is derived from 3d elections on the geometrically frustrated Ti pyrochlore network. A recent…

Unique superconductivity at surfaces/interfaces, as exemplified by LaAlO3/SrTiO3 interfaces, and the high transition temperature in ultrathin FeSe films, have triggered intense debates on how superconductivity is affected in atomic and…

The evolution from superconducting LiTi2O4-delta to insulating Li4Ti5O12 thin films has been studied by precisely adjusting the oxygen pressure during the sample fabrication process. In the superconducting LiTi2O4-delta films, with the…

Superconductivity · Physics 2017-06-26 Yanli Jia , Ge He , Wei Hu , Hua Yang , Zhenzhong Yang , Heshan Yu , Qinghua Zhang , Jinan Shi , Zefeng Lin , Jie Yuan , Beiyi Zhu , Lin Gu , Hong Li , Kui Jin

Spin-orbit coupling in transition metal dichalcogenides (TMDCs) causes spin-valley locking giving rise to unconventional optical, transport, and superconducting properties. In this paper, we propose exotic superconductivity in bilayer…

Superconductivity · Physics 2017-09-13 Yasuharu Nakamura , Youichi Yanase

The superconducting state formed due to direct intra-orbital pairing in tetragonal multi-band superconductor Sr$_2$RuO$_4$ has different properties than the state formed due to intra-band pairing. In particular, the theory operating with…

Superconductivity · Physics 2016-11-26 V. P. Mineev

Noncentrosymmetric 2D superconductors with large spin-orbit coupling offer an opportunity to explore superconducting behaviors far beyond the Pauli limit. One such superconductor, few-layer T$_d$-MoTe$_2$, has large upper critical fields…

We report the synthesis, crystal structure, and superconductivity of Ti$_4$Ir$_2$O. The title compound crystallizes in an $\eta$-carbide type structure of the space group $Fd\overline{3}m$ (No. 227), with lattice parameters…

Superconductivity · Physics 2022-02-08 Bin-Bin Ruan , Meng-Hu Zhou , Qing-Song Yang , Ya-Dong Gu , Ming-Wei Ma , Gen-Fu Chen , Zhi-An Ren

A variety of experimental observations in monolayer transition metal dichalcogenide superconductors with Ising spin-orbit coupling suggest the presence of an unconventional superconducting pairing mechanism. Some of these experiments…

Superconductivity · Physics 2026-02-05 Subhojit Roy , Andreas Kreisel , Brian M. Andersen , Shantanu Mukherjee
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