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Real-time propagation methods for chemistry and physics are invariably formulated using variational techniques. The time-dependent bivariational principle (TD-BIVP) is known to be the proper framework for coupled-cluster type methods, and…

We present an approach based upon binary tree tensor network (BTTN) states for computing steady-state current statistics for a many-particle 1D ratchet subject to volume exclusion interactions. The ratcheted particles, which move on a…

Statistical Mechanics · Physics 2023-01-02 Nils E. Strand , Hadrien Vroylandt , Todd R. Gingrich

We show that the time-dependent variational principle provides a unifying framework for time-evolution methods and optimisation methods in the context of matrix product states. In particular, we introduce a new integration scheme for…

Quantum Physics · Physics 2016-10-19 Jutho Haegeman , Christian Lubich , Ivan Oseledets , Bart Vandereycken , Frank Verstraete

We propose two complimentary numerical methods for rigorous computation of dynamic structure factor at zero temperature. One solution is to solve Schrodinger equation using time dependent variational principle (TDVP) with matrix product…

Strongly Correlated Electrons · Physics 2019-01-24 Ling Wang , Hai-Qing Lin

We investigate the critical behavior and real-time scattering dynamics of the interacting $\phi^4$ quantum field theory in (1+1)-dimensions using uniform matrix product states (uMPS) and the time-dependent variational principle (TDVP). A…

High Energy Physics - Theory · Physics 2026-04-21 Bahaa Al Sayegh , Wissam Chemissany

We propose a systematic approach to the basis set extension for nonadiabatic dynamics of entangled combination of nuclear coherent states (CSs) evolving according to the time-dependent variational principle (TDVP). TDVP provides a rigorous…

Chemical Physics · Physics 2017-03-14 Artur F. Izmaylov , Loïc Joubert-Doriol

We show that the time-dependent Schr\"odinger equation (TDSE) is the phenomenological dynamical law of evolution unraveled in the classical limit from a timeless formulation in terms of probability amplitudes conditioned by the values of…

Quantum Physics · Physics 2015-06-04 Julio César Arce

We develop a new algorithm based on the time-dependent variational principle applied to matrix product states to efficiently simulate the real- and imaginary time dynamics for infinite one-dimensional quantum lattice systems. This…

Strongly Correlated Electrons · Physics 2012-03-13 Jutho Haegeman , J. Ignacio Cirac , Tobias J. Osborne , Iztok Pizorn , Henri Verschelde , Frank Verstraete

Tensor network methods, particularly those based on Matrix Product States (MPS), provide a powerful framework for simulating quantum many-body systems. A persistent computational challenge in these methods is the selection of the bond…

Emerging Technologies · Computer Science 2026-04-07 Harshni Kumaresan , Gayathri Muruganantham , Lakshmi Rajendran , Santhosh Sivasubramani

Understanding transition pathways between two meta-stable states of a molecular system is crucial to advance drug discovery and material design. However, unbiased molecular dynamics (MD) simulations are computationally infeasible because of…

Machine Learning · Computer Science 2025-01-28 Kiyoung Seong , Seonghyun Park , Seonghwan Kim , Woo Youn Kim , Sungsoo Ahn

Within the Projected Entangled Pair State (PEPS) tensor network formalism, a simple update (SU) method has been used to investigate the time evolution of a two-dimensional U(1) critical spin-1/2 spin liquid under Hamiltonian quench [Phys.…

Strongly Correlated Electrons · Physics 2023-10-11 Ravi Teja Ponnaganti , Matthieu Mambrini , Didier Poilblanc

Predicting the dynamical properties of topological matter is a challenging task, not only in theoretical and experimental settings, but also numerically. This work proposes a variational approach based on a time-dependent correlated Ansatz,…

Quantum Physics · Physics 2025-08-05 Linda Mauron , Zakari Denis , Jannes Nys , Giuseppe Carleo

We have examined the validity of the time-dependent variational approximation (TDVA) to the Gaussian wavepacket method (GWM) for quantum double-well (DW) systems, by using the quasi-exact spectral method (SM). Comparisons between results of…

Quantum Physics · Physics 2015-06-12 Hideo Hasegawa

This paper proposes a novel low-rank approximation to the multivariate State-Space Model. The Stochastic Partial Differential Equation (SPDE) approach is applied component-wise to the independent-in-time Mat\'ern Gaussian innovation term in…

Engineering simulations are usually based on complex, grid-based, or mesh-free methods for solving partial differential equations. The results of these methods cover large fields of physical quantities at very many discrete spatial…

Fluid Dynamics · Physics 2025-08-08 Eduardo Di Costanzo , Niklas Kühl , Jean-Christophe Marongiu , Thomas Rung

The rapid growth of entanglement under unitary time evolution is the primary bottleneck for modern tensor-network techniques--such as Matrix Product States (MPS)--when computing time-dependent expectation values. This {entanglement barrier}…

Quantum Physics · Physics 2025-06-10 Stefano Carignano , Guglielmo Lami , Jacopo De Nardis , Luca Tagliacozzo

Tensor-network simulations of quantum many-body dynamics are fundamentally limited by entanglement build-up, which leads to exponentially growing computational costs. Furthermore, these classical simulation algorithms are inherently…

Quantum Physics · Physics 2026-04-16 Fredrik Hasselgren , Bálint Koczor

We propose a general-purpose, self-adaptive approach to construct variational wavefunction ans\"atze for highly accurate quantum dynamics simulations based on McLachlan's variational principle. The key idea is to dynamically expand the…

The time-dependent restricted-active-space self-consistent-field (TD-RASSCF) method is formulated based on the TD variational principle. In analogy with the configuration-interaction singles (CIS), singles-and-doubles (CISD),…

Quantum Physics · Physics 2014-06-26 Haruhide Miyagi , Lars Bojer Madsen

The computation of the nuclear quantum dynamics of molecules is challenging, requiring both accuracy and efficiency to be applicable to systems of interest. Recently, theories have been developed for employing time-dependent basis functions…