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X-ray diffraction studies of the bond-orientational order in the hexatic-B phase of 75OBC and 3(10)OBC compounds are presented. The temperature evolution of an angular profile of a single diffraction peak is analyzed. Close to the…

Soft Condensed Matter · Physics 2016-10-07 I. A. Zaluzhnyy , R. P. Kurta , A. P. Menushenkov , B. I. Ostrovskii , I. A. Vartanyants

We present an x-ray study of freely suspended hexatic films of the liquid crystal 3(10)OBC. Our results reveal spatial inhomogeneities of the bond-orientational (BO) order in the vicinity of the hexatic-smectic phase transition and the…

We report on X-ray studies of freely suspended hexatic films of three different liquid crystal compounds. By applying angular X-ray cross-correlation analysis (XCCA) to the measured diffraction patterns the parameters of the…

We present an x-ray study of liquid crystal membranes in the vicinity of hexatic-smectic phase transition by means of angular x-ray cross-correlation analysis (XCCA). By applying two-point angular intensity cross-correlation functions to…

An x-ray scattering approach to determine the two-dimensional (2D) pair distribution function (PDF) in partially ordered 2D systems is proposed. We derive relations between the structure factor and PDF that enable quantitative studies of…

Soft Condensed Matter · Physics 2016-09-21 I. A. Zaluzhnyy , R. P. Kurta , A. P. Menushenkov , B. I. Ostrovskii , I. A. Vartanyants

We present detailed systematic studies of structural transformations in thin liquid crystal films with the smectic-C to hexatic phase transition. For the first time all possible structures reported in the literature are observed for one…

Soft Condensed Matter · Physics 2009-11-11 P. V. Dolganov , K. I. Belov , V. K. Dolganov , E. I. Demikhov , B. M. Bolotin , E. I. Kats

Using molecular dynamics simulation, we study structural and dynamical heterogeneities at melting in two-dimensional one-component systems with 36000 particles. Between crystal and liquid we find intermediate hexatic states, where the…

Statistical Mechanics · Physics 2010-04-07 Hayato Shiba , Akira Onuki , Takeaki Araki

Molecular arrangement in the chiral smectic phases of the glassforming (S)-4'-(1-methylheptylcarbonyl)biphenyl-4-yl 4-[7-(2,2,3,3,4,4,4-heptafluorobutoxy) heptyl-1-oxy]benzoate is investigated by X-ray diffraction. An increased correlation…

Soft Condensed Matter · Physics 2025-01-15 Aleksandra Deptuch , Natalia Górska , Stanisław Baran , Magdalena Urbańska

Comprehensive x-ray scattering studies have characterized the smectic ordering of octylcyanobiphenyl (8CB) confined in the hydrogen-bonded silica gels formed by aerosil dispersions. For all densities of aerosil and all measurement…

Soft Condensed Matter · Physics 2009-11-07 R. L. Leheny , S. Park , R. J. Birgeneau , J. -L. Gallani , C. W. Garland , G. S. Iannacchione

We report on a computer simulation study of a Lennard-Jones liquid confined in a narrow slit pore with tunable attractive walls. In order to investigate how freezing in this system occurs, we perform an analysis using different order…

Soft Condensed Matter · Physics 2015-05-27 N. Gribova , A. Arnold , T. Schilling , C. Holm

The present work is essentially focused on the study of optical and structural properties of hydrogenated amorphous silicon thin films (a-Si:H) prepared by radio-frequency cathodic sputtering. We examine separately the influence of hydrogen…

Materials Science · Physics 2007-05-23 A. Barhdadi , M. Chafik El Idrissi

The liquid crystalline compound, forming the glass of the smectic C$_A$* phase, is investigated by the X-ray diffraction in the 18-298 K range. The characteristic distances within the smectic C$_A$* phase are determined. The electron…

The structure of graphite-like BCx phases (x = 1, 1.5, 3, 4, 32) has been studied using conventional X-ray diffraction. The results have been obtained, which unambiguously point to turbostratic (one- dimensionally disordered) structure of…

Materials Science · Physics 2011-01-19 O. O. Kurakevych , T. Chauveau , V. L. Solozhenko

We report the structure of transient fluctuations in the liquid phase of a two-dimensional system that exhibits several ordered phases with different symmetries. The density-temperature phase diagram of the system studied, composed of…

Soft Condensed Matter · Physics 2018-07-04 Ari B. Roitman , Linsey M. Nowack , Chris Liepold , Binhua Lin , Stuart A. Rice

Resonant x-ray scattering shows that the bulk structure of the twist-bend liquid crystal phase, recently discovered in bent molecular dimers, has spatial periodicity without electron density modulation, indicating a lattice-free heliconical…

We report a molecular dynamics simulation demonstrating that the Smectic B crystalline phase (Cr-B), commonly observed in mesogenic systems of anisotropic molecules, can be formed by a system of identical particles interacting via a…

Soft Condensed Matter · Physics 2013-12-16 A. Metere , T. Oppelstrup , S. Sarman , A. Laaksonen , M. Dzugutov

We study a two-dimensional fluid of particles interacting through a spherically-symmetric and marginally soft two-body repulsion. This model can exist in three different crystal phases, one of them with square symmetry and the other two…

Soft Condensed Matter · Physics 2012-09-13 Santi Prestipino , Franz Saija , Paolo V. Giaquinta

Using video-microscopy data of a two-dimensional colloidal system the bond-order correlation function G6 is calculated and used to determine the temperature-dependence of both the orientational correlation length xi6 in the isotropic liquid…

Soft Condensed Matter · Physics 2012-10-26 P. Keim , G. Maret , H. H. von Gruenberg

We report on a comprehensive computer simulation study of the liquid-crystal phase behaviour of purely repulsive, semi-flexible rod-like particles. For the four aspect ratios we consider, the particles form five distinct phases depending on…

Soft Condensed Matter · Physics 2018-01-17 Bart de Braaf , Mariana Oshima Menegon , Stefan Paquay , Paul van der Schoot

Micrometer sized alkane-in-water emulsion drops, stabilized by appropriate long-chain surfactants, spontaneously break symmetry upon cooling and transform consecutively into series of regular shapes (Denkov et al., Nature 2015, 528, 392).…

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