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All current formulations of nonequilibrium thermodynamics of open chemical reaction networks rely on the assumption of non-interacting species. We develop a general theory which accounts for interactions between chemical species within a…

Statistical Mechanics · Physics 2021-03-09 Francesco Avanzini , Emanuele Penocchio , Gianmaria Falasco , Massimiliano Esposito

Liquid mixtures of many interacting components often exhibit numerous coexisting types of droplets. An exciting example is the cytosol of biological cells, where diverse droplets, called condensates, are essential for cellular function.…

Soft Condensed Matter · Physics 2025-05-28 Yicheng Qiang , Chengjie Luo , David Zwicker

The equilibrium behavior of binary mixtures can be understood through the competition of energy scales, which classifies their corresponding phase diagrams into distinct topological regimes (Types I-IV). However, in many soft-matter…

Understanding how interparticle interactions govern phase behavior is central to controlling self-organization in multicomponent soft-matter systems. In particular, the role of cross-interactions between unlike components remains…

Soft Condensed Matter · Physics 2026-03-03 Umesh Dhumal

We present a new multiphase-field theory for describing pattern formation in multi-domain and/or multi-component systems. The construction of the free energy functional and the dynamic equations is based on criteria that ensure mathematical…

Materials Science · Physics 2015-12-09 Gyula I. Toth , Tamas Pusztai , Laszlo Granasy

Multicomponent phase separation is a routine occurrence in both living and synthetic systems. Thermodynamics provides a straightforward path to determine the phase boundaries that characterize these transitions for systems at equilibrium.…

Statistical Mechanics · Physics 2025-12-08 Yu-Jen Chiu , Daniel Evans , Ahmad K. Omar

We consider a phase field crystal modeling approach for binary mixtures of interacting active and passive particles. The approach allows to describe generic properties for such systems within a continuum model. We validate the approach by…

Soft Condensed Matter · Physics 2018-09-19 Francesco Alaimo , Axel Voigt

The population dynamics and stability of ecosystems of interacting species is studied from the perspective of non-equilibrium thermodynamics by assuming that species, through their biotic and abiotic interactions, are units of entropy…

Biological Physics · Physics 2007-05-23 Karo Michaelian

The past two decades have seen a revolution in statistical physics, generalizing it to apply to systems of arbitrary size, evolving while arbitrarily far from equilibrium. Many of these new results are based on analyzing the dynamics of the…

Statistical Mechanics · Physics 2022-08-08 David H. Wolpert

Considering a broad class of steady-state nonequilibrium systems for which some additive quantities are conserved by the dynamics, we introduce from a statistical approach intensive thermodynamic parameters (ITPs) conjugated to the…

Statistical Mechanics · Physics 2007-05-23 Eric Bertin , Kirsten Martens , Olivier Dauchot , Michel Droz

We revisit the structure of the phase diagram of the two-component mean-field Bose mixture at finite temperatures, considering both the cases of attractive and repulsive interspecies interactions. In particular, we analyze the evolution of…

Statistical Mechanics · Physics 2026-03-18 Oskar Stachowiak , Pawel Jakubczyk

The fixed-point analysis refers to the study of fixed-points that arise in the context of complex systems with many interacting entities. In this expository paper, we describe four levels of fixed-points in mean-field interacting particle…

Networking and Internet Architecture · Computer Science 2021-06-08 Sarath Yasodharan , Rajesh Sundaresan

A diffuse-interface model for microstructure with an arbitrary number of components and phases was developed from basic thermodynamic and kinetic principles and formalized within a variational framework. The model includes a composition…

Materials Science · Physics 2011-07-28 Daniel A. Cogswell , W. Craig Carter

The influence of short-range interactions between a multi-phase, multi-component mixture and a solid wall in confined geometries is crucial in life sciences and engineering. In this work, we extend the Cahn-Hilliard model with dynamic…

Fluid Dynamics · Physics 2023-12-18 Shuang Liu , Yue Wu , Xueping Zhao

The liquid-gas phase transition for homogeneous symmetric nuclear matter is studied in the mean-field approximation. Critical properties are computed using a comprehensive group of Skyrme and Gogny forces in an effort to elucidate the…

Nuclear Theory · Physics 2010-07-23 A. Rios

We describe a finite inhomogeneous three dimensional system of classical particles which interact through short and (or) long range interactions by means of a simple analytic spin model. The thermodynamic properties of the system are worked…

Nuclear Theory · Physics 2009-10-31 J. Richert , P. Wagner , M. Henkel , J. M. Carmona

A statistical theory of the mean field is developed. It is based on the proposition that the mean field can be obtained as an energy average. Moreover, it is assumed that the matrix elements of the residual interaction, obtained after the…

Nuclear Theory · Physics 2009-10-30 R. Caracciolo , A. De Pace , H. Feshbach , A. Molinari

We show how the stability conditions for a system of interacting fermions that conventionally involve variations of thermodynamic potentials can be rewritten in terms of one- and two-particle correlators. We illustrate the applicability of…

Strongly Correlated Electrons · Physics 2024-08-09 A. Kowalski , M. Reitner , L. Del Re , M. Chatzieleftheriou , A. Amaricci , A. Toschi , L. de' Medici , G. Sangiovanni , T. Schäfer

We propose a method for describing a phase behavior of a system consisting of particles of two sorts. The interaction of each species is described by interaction potentials containing the repulsive and attractive components. Asymmetry is…

Statistical Mechanics · Physics 2020-06-19 M. P. Kozlovskii , O. A. Dobush

Active systems, which are driven out of equilibrium by local non-conservative forces, exhibit unique behaviors and structures with potential utility for the design of novel materials. An important and difficult challenge along the path…

Soft Condensed Matter · Physics 2022-08-09 Laura Tociu , Gregory Rassolov , Étienne Fodor , Suriyanarayanan Vaikuntanathan
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