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Most methods for estimating configurational entropy from molecular simulation data yield upper limits except for harmonic systems where they are exact. Problems arise at diffusive systems and the presence of conformational transitions.…

Chemical Physics · Physics 2019-10-22 Jürgen Schlitter , Matthias Massarczyk

An attempt is made to bypass spectral analysis and fit internal coordinates of radicals directly to experimental liquid- and solid-state electron spin resonance (ESR) spectra. We take advantage of the recently introduced large-scale spin…

Chemical Physics · Physics 2014-07-16 G. T. P. Charnock , M. Krzystyniak , Ilya Kuprov

Molecular self-assembly, the function of biomembranes, and the performance of organic solar cells rely on molecular interactions on the nanoscale. The understanding and design of such intrinsic or engineered heterogeneous functional soft…

Chemical Physics · Physics 2013-12-30 Benjamin Pollard , Eric A. Muller , Karsten Hinrichs , Markus B. Raschke

Spectral computed tomography (CT) has attracted much attention in radiation dose reduction, metal artifacts removal, tissue quantification and material discrimination. The x-ray energy spectrum is divided into several bins, each…

Image and Video Processing · Electrical Eng. & Systems 2021-08-26 Weiwen Wu , Dianlin Hu , Chuang Niu , Lieza Vanden Broeke , Anthony P. H. Butler , Peng Cao , James Atlas , Alexander Chernoglazov , Varut Vardhanabhuti , Ge Wang

Speckle metrology exploits the high sensitivity of scattered fields to parameters of interest, yet this also leaves measurements vulnerable to unintended perturbations. Here we employ transmission matrix formalism to engineer light fields…

Optics · Physics 2026-04-08 Hal Gee , Morgan Facchin , Graham D. Bruce

Spectroscopy has played the key role in revealing, and thereby understanding, the structure of atoms and molecules. A central drive in this field is the pursuit of higher precision and accuracy so that ever more subtle effects might be…

Spectroscopic techniques are essential tools for determining the structure of molecules. Different spectroscopic techniques, such as Nuclear magnetic resonance (NMR), Infrared spectroscopy, and Mass Spectrometry, provide insight into the…

Chemical Physics · Physics 2024-10-30 Marvin Alberts , Oliver Schilter , Federico Zipoli , Nina Hartrampf , Teodoro Laino

Multi-index models provide a popular framework to investigate the learnability of functions with low-dimensional structure and, also due to their connections with neural networks, they have been object of recent intensive study. In this…

Machine Learning · Statistics 2025-06-11 Filip Kovačević , Yihan Zhang , Marco Mondelli

We introduce a scheme based on machine learning and deep neural networks to model the environmental dependence of the electronic polarizability in insulating materials. Application to liquid water shows that training the network with a…

Chemical Physics · Physics 2020-06-24 Grace M. Sommers , Marcos F. Calegari Andrade , Linfeng Zhang , Han Wang , Roberto Car

In this paper, we investigate how the spectrogram of multicomponent signals can be decomposed into a mode part and an interference part. We explore two approaches: (i) a variational method inspired by texture-geometry decomposition in image…

Computer Vision and Pattern Recognition · Computer Science 2025-03-20 Kévin Polisano , Sylvain Meignen , Nils Laurent , Hubert Leterme

Many tools and techniques measure local structure in materials in contexts ranging from biology to geology. We provide a survey of those tools and metrics that are especially useful for analyzing particulate soft matter. The metrics we…

Soft Condensed Matter · Physics 2026-01-13 Rachael S. Skye , Erin G. Teich

A conceptual scheme of a hybrid-emulsion spectrometer for investigating various channels of neutrino oscillations is proposed. The design emphasizes detection of $\tau$ leptons by detached vertices, reliable identification of electrons, and…

High Energy Physics - Experiment · Physics 2009-10-31 A. E. Asratyan , G. V. Davidenko , A. G. Dolgolenko , V. S. Kaftanov , M. A. Kubantsev , V. S. Verebryusov

Observations of molecular lines are a key tool to determine the main physical properties of prestellar cores. However, not all the information is retained in the observational process or easily interpretable, especially when a larger number…

Astrophysics of Galaxies · Physics 2025-10-08 T. Grassi , M. Padovani , D. Galli , N. Vaytet , S. S. Jensen , E. Redaelli , S. Spezzano , S. Bovino , P. Caselli

We consider the problem of recovering the three-dimensional atomic structure of a flexible macromolecule from a heterogeneous cryo-EM dataset. The dataset contains noisy tomographic projections of the electrostatic potential of the…

Image and Video Processing · Electrical Eng. & Systems 2023-02-08 Carlos Esteve-Yagüe , Willem Diepeveen , Ozan Öktem , Carola-Bibiane Schönlieb

Recently, spectral CT has been drawing a lot of attention in a variety of clinical applications primarily due to its capability of providing quantitative information about material properties. The quantitative integrity of the reconstructed…

Medical Physics · Physics 2018-01-12 Shiyu Xu , Peter Prinsen , Jens Wiegert , Ravindra Manjeshwar

The electron density of a molecule or material has recently received major attention as a target quantity of machine-learning models. A natural choice to construct a model that yields transferable and linear-scaling predictions is to…

Chemical Physics · Physics 2022-06-29 Andrea Grisafi , Alan M. Lewis , Mariana Rossi , Michele Ceriotti

We apply a recently developed technique utilizing machine learning for statistical analysis of computational nitrogen K-edge spectra of aqueous triglycine. This method, the emulator-based component analysis, identifies spectrally relevant…

Soft Condensed Matter · Physics 2024-02-14 Eemeli A. Eronen , Anton Vladyka , Florent Gerbon , Christoph. J. Sahle , Johannes Niskanen

Amphiphilic molecules spontaneously form self-assembled structures of various shapes depending on their molecular structures, the temperature, and other physical conditions. The functionalities of these structures are dictated by their…

Soft Condensed Matter · Physics 2024-04-18 Takeo Sudo , Satoki Ishiai , Yuuki Ishiwatari , Takahiro Yokoyama , Kenji Yasuoka , Noriyoshi Arai

The temperature-dependent behavior of defect densities within a crystalline structure is intricately linked to the phenomenon of vibrational entropy. Traditional methods for evaluating vibrational entropy are computationally intensive,…

Computational Physics · Physics 2024-03-20 Tina Torabi , Yangshuai Wang , Christoph Ortner

In this study, we explore the potential of machine learning for modeling molecular electronic spectral intensities as a continuous function in a given wavelength range. Since presently available chemical space datasets provide excitation…

Chemical Physics · Physics 2022-08-02 Prakriti Kayastha , Sabyasachi Chakraborty , Raghunathan Ramakrishnan