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Two-dimensional materials and their heterostructures have emerged as a new class of materials for not only fundamental physics but also for electronic and optoelectronic applications. Black phosphorus (BP) is a relatively new addition to…

Mesoscale and Nanoscale Physics · Physics 2015-11-23 Manabendra Kuiri , Chandan Kumar , Biswanath Chakraborty , Satyendra N Gupta , Mit H. Naik , Manish Jain , A. K. Sood , Anindya Das

High-performance infrared photodetection underpins various applications spanning surveillance, environmental monitoring, optical communications and biomedical imaging. However, conventional bulk detectors remain limited by poor spectral…

The electronic structure and functionality of 2D materials is highly sensitive to structural morphology, opening the possibility for manipulating material properties, but also making predictable and reproducible functionality challenging.…

Mesoscale and Nanoscale Physics · Physics 2022-10-26 Prakriti P. Joshi , Ruiyu Li , Joseph L. Spellberg , Liangbo Liang , Sarah B. King

Atomic layers of black phosphorus (P) isolated from its layered bulk make a new two-dimensional (2D) semiconducting crystal with sizable direct bandgap, high carrier mobility, and promises for 2D electronics and optoelectronics. However,…

Mesoscale and Nanoscale Physics · Physics 2023-05-03 Zenghui Wang , Arnob Islam , Rui Yang , Xu-Qian Zheng , Philip X. -L. Feng

Black phosphorus (BP), a layered van der Waals (vdW) crystal, has unique in-plane band anisotropy and many resulting anisotropy properties such as the effective mass, electron mobility, optical absorption, thermal conductivity and plasmonic…

Materials Science · Physics 2020-08-14 Zhimin Liu , Ye Yang , Yueshao Zheng , Qinjun Chen , Yexin Feng

The temperature dependence of the band gap is crucial to a semiconductor. Bulk black phosphorus (BP) is known to exhibit an anomalous behavior. Through optical spectroscopy, here we show that the temperature effect on BP band gap gradually…

Elemental substitution is a proven method of Fermi level tuning in topological insulators, which is needed for device applications. Through static and time resolved photoemission, we show that in MnBi$_2$Te$_4$, elemental substitution of Bi…

Materials Science · Physics 2022-06-30 Daniel Nevola , Kevin F. Garrity , Nader Zaki , Jiaqiang Yan , Hu Miao , Sugata Chowdhury , Peter D. Johnson

We study the effect of impurity scattering effect in black phosphorurene (BP) in this work. For single impurity, we calculate impurity induced local density of states (LDOS) in momentum space numerically based on tight-binding Hamiltonian.…

Mesoscale and Nanoscale Physics · Physics 2016-07-27 Y. L. Zou , J. T. Song , C. X. Bai , K. Chang

Anisotropy refers to the property of a material exhibiting directionally dependent features. In this paper, we introduce black phosphorous (BP), the most stable allotrope of phosphorus in layered orthorhombic structure with a bandgap of 0.3…

Mesoscale and Nanoscale Physics · Physics 2014-07-30 Fengnian Xia , Han Wang , Yichen Jia

Recently rediscovered black phosphorus is a layered semiconductor with promising electronic and photonic properties. Dynamic control of its bandgap can enable novel device applications and allow for the exploration of new physical…

Mesoscale and Nanoscale Physics · Physics 2017-04-21 Bingchen Deng , Vy Tran , Hao Jiang , Cheng Li , Yujun Xie , Qiushi Guo , Xiaomu Wang , He Tian , Han Wang , Judy J. Cha , Qiangfei Xia , Li Yang , Fengnian Xia

The complete subgap defect density of states (DoS) is measured using the ultrabroadband (0.15 to 3.5 eV) photoconduction response from p-type thin-film transistors (TFTs) of tin oxide, SnO, and copper oxide, Cu$_2$O. The TFT photoconduction…

Few-layer black phosphorus (BP), as the most alluring graphene analogue owing to its similar structure as graphene and thickness dependent direct band-gap, has now triggered a new wave of research on two-dimensional (2D) materials based…

The atomic and electronic structure of positively charged P vacancies on InP(110) surfaces is determined by combining scanning tunneling microscopy, photoelectron spectroscopy, and density-functional theory calculations. The vacancy…

Materials Science · Physics 2009-10-31 Ph. Ebert , K. Urban , L. Aballe , C. H. Chen , K. Horn , G. Schwarz , J. Neugebauer , M. Scheffler

Negative compressibility generated by many-body effects in 2D electronic systems can enhance gate capacitance. We observe capacitance enhancement in a newly emerged 2D layered material, atomically thin black phosphorus (BP). The…

Mesoscale and Nanoscale Physics · Physics 2016-04-05 Yingying Wu , Xiaolong Chen , Zefei Wu , Shuigang Xu , Tianyi Han , Jiangxiazi Lin , Yuan Cai , Yuheng He , Chun Cheng , Ning Wang

We present first-principles density-functional calculations for the structural, electronic, and magnetic properties of substitutional 3d transition metal (TM) impurities in two-dimensional black and blue phosphorenes. We find that the…

Materials Science · Physics 2016-03-17 Weiyang Yu , Zhili Zhu , Chun-Yao Niu , Chong Li , Jun-Hyung Cho , Yu Jia

Black phosphorene (BP) has emerged as a promising platform for tunable nonlinear photonics due to its layer-dependent bandgap, high carrier mobility, and remarkable in-plane anisotropy. This study investigates the second-harmonic generation…

Mesoscale and Nanoscale Physics · Physics 2025-10-14 Yan Meng , Kainan Chang , Yanyan Qian , Luxia Wang , Jin Luo Cheng

Black phosphorus (BP), a two-dimensional (2D) van der Waals layered material composed of phosphorus atoms, has been one of the most actively studied 2D materials in recent years due to its tunable energy band gap (tunable even to a negative…

Mesoscale and Nanoscale Physics · Physics 2019-04-08 Sanghyun Park , Seungchan Woo , Hongki Min

The electronic structure evolutions of few-layer black phosphorus (BP) under pressure shows a wealth of phenomena, such as the nonmonotonic change of direct gap at the {\Gamma} point, the layer-number dependence, and the distinct responses…

Black phosphorus (BP) has recently emerged as a promising narrow band gap layered semiconductor with optoelectronic properties that bridge the gap between semi-metallic graphene and wide band gap transition metal dichalcogenides such as…

Layered and two-dimensional (2D) materials such as graphene, boron nitride, transition metal dichalcogenides(TMDCs), and black phosphorus (BP) have intriguing fundamental physical properties and bear promise of numerous important…

Mesoscale and Nanoscale Physics · Physics 2018-10-04 Yohannes Abate , Sampath Gamage , Li Zhen , Stephen B. Cronin , Han Wang , Viktoriia Babicheva , Mohammad H. Javani , Mark I. Stockman