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Transport of water through ion-exchange membranes is of importance both for electrodialysis (ED) and reverse electrodialysis (RED). In this work, we extend our previous theory [J. Membrane Sci., 510, (2016) 370-381] and include water…

Chemical Physics · Physics 2019-12-24 M. Tedesco , H. V. M. Hamelers , P. M. Biesheuvel

We present theory for ion and water transport through reverse osmosis membranes based on a Maxwell-Stefan framework combined with hydrodynamic theory for the reduced motion of particles in thin pores. We include all driving forces and…

Chemical Physics · Physics 2018-03-07 Y. S. Oren , P. M. Biesheuvel

Shock electrodialysis (shock ED), an emerging electrokinetic process for water purification, leverages the new physics of deionization shock waves in porous media. In previous work, a simple leaky membrane model with surface conduction can…

Fluid Dynamics · Physics 2021-03-16 Huanhuan Tian , Mohammad A. Alkhadra , Martin Z. Bazant

Reverse Osmosis(RO) membranes are widespread nowadays for separating the solvent from a solution. RO membranes are made of polymer matrix. Experiments show changes in relative interaction of solvent and solute with RO membrane matrix lead…

Soft Condensed Matter · Physics 2023-05-16 Rahul Karmakar , Jaydeb Chakrabarti

The reverse osmosis membrane module is an integral element of a desalination system as it determines the overall performance of the desalination plant. The fraction of clean water that can be recovered via this process is often limited by…

Numerical Analysis · Mathematics 2023-01-31 Nicodemo Di Pasquale , Mayo Akele , Federico Municchi , John King , Matteo Icardi

Polyamide membranes, such as nanofiltration (NF) and reverse osmosis (RO) membranes, are widely used for water desalination and purification. However, the mechanisms of solute transport and solute rejection due to charge interactions remain…

Soft Condensed Matter · Physics 2025-03-17 Suwei Liu , Zi Hao Foo , John H. Lienhard , Sinan Keten , Richard M. Lueptow

Osmotic transport in nanoconfined aqueous electrolytes provides new venues for water desalination and "blue energy" harvesting; the osmotic response of nanofluidic systems is controlled by the interfacial structure of water and electrolyte…

Chemical Physics · Physics 2022-08-16 Laurent Joly , Robert H. Meißner , Marcella Iannuzzi , Gabriele Tocci

Osmosis is a universal phenomenon occurring in a broad variety of processes and fields. It is the archetype of entropic forces, both trivial in its fundamental expression - the van 't Hoff perfect gas law - and highly subtle in its physical…

Soft Condensed Matter · Physics 2020-03-03 Sophie Marbach , Lyderic Bocquet

In this paper, we explore osmotic transport by means of molecular dynamics (MD) simulations. We first consider osmosis through a membrane, and investigate the reflection coefficient of an imperfectly semi-permeable membrane, in the dilute…

Mesoscale and Nanoscale Physics · Physics 2017-05-18 Hiroaki Yoshida , Sophie Marbach , Lydéric Bocquet

Shock electrodialysis is a recently developed electrochemical water treatment method which shows promise for water deionization and ionic separations. Although simple models and scaling laws have been proposed, a predictive theory has not…

Fluid Dynamics · Physics 2021-04-21 Sven Schlumpberger , Raymond B. Smith , Huanhuan Tian , Ali Mani , Martin Z. Bazant

The shift in water security demands improvements in alternative solutions such as saltwater desalination. One of the most efficient technologies in this scope is the reverse osmosis systems, a technology based on a membrane separation…

Soft Condensed Matter · Physics 2024-06-19 João P. K. Abal , Marcia C. Barbosa

Reverse osmosis and nanofiltration are membrane-based methods that remove solutes from solvent, for instance they remove salts from water (desalination). In these methods, an applied pressure is the driving force for solvent to pass the…

Chemical Physics · Physics 2024-01-23 P. M. Biesheuvel , S. Porada , B. Blankert , I. Ryzhkov , M. Elimelech

Possible mechanisms of overlimiting current in unsupported electrolytes, exceeding diffusion limitation, have been intensely studied for their fundamental significance and applications to desalination, separations, sensing, and energy…

Fluid Dynamics · Physics 2015-06-22 Sungmin Nam , Inhee Cho , Joonseong Heo , Geunbae Lim , Martin Z. Bazant , Gunyong Sung , Sung Jae Kim

A filtration procedure was developed to measure the reversibility of fouling during cross-flow filtration based on the square wave of applied pressure. The principle of this method, the apparatus required, and the associated mathematical…

Soft Condensed Matter · Physics 2008-01-18 Benjamin Espinasse , Patrice Bacchin , Pierre Aimar

Most electrochemical processes, such as electrodialysis, are limited by diffusion, but in porous media, surface conduction and electro-osmotic flow also contribute to ionic fluxes. In this paper, we report experimental evidence for…

The development of energy and infrastructure efficient water purification systems are among the most critical engineering challenges facing our society. Water purification is often a multi-step process involving filtration, desalination,…

Reverse osmosis (RO) is a method to desalinate water with membranes and an applied pressure. Very important in the theory of mass transport in RO is the concentration polarization (CP) layer, which develops on the upstream side of the…

Chemical Physics · Physics 2023-10-03 P. M. Biesheuvel , S. Porada , I. Ryzhkov , M. Elimelech

In the present study, two schemes named face discernment and flux correction are proposed to achieve single-phase transportation of free charge in multiphase electrohydrodynamic(EHD) problems. Many EHD phenomena occur between air and…

Fluid Dynamics · Physics 2022-07-19 Qiang Liu , Jie Zhang , Jian Wu

Electro-osmosis (EO) is a powerful tool to manipulate liquids in micro and nanofluidic systems. While EO has been studied extensively at liquid-solid interfaces, the case of liquid-vapor interfaces, found e.g. in foam films and bubbles,…

Soft Condensed Matter · Physics 2021-11-23 Alexia Barbosa de Lima , Laurent Joly

Electro-sorption (ES) is a research frontier in electrochemical separation, with proven potential applications in desalination, wastewater treatment, and selective resource extraction. However, due to the limited adsorption capacity of film…

Chemical Physics · Physics 2024-03-19 Weifan Liu , Longqian Xu , Zezhou Yang , Xudong Zhang , Shihong Lin
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