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The Coulomb exchange and correlation energy density functionals for electron systems are applied to nuclear systems. It is found that the exchange functionals in the generalized gradient approximation provide agreements with the exact-Fock…

Nuclear Theory · Physics 2019-12-09 Tomoya Naito , Ryosuke Akashi , Gianluca Colò , Haozhao Liang , Xavier Roca-Maza

Electronic structure methods for accurate calculation of molecular properties have a high cost that grows steeply with the problem size, therefore, it is helpful to have the underlying atomic basis functions that are less in number but of…

Chemical Physics · Physics 2019-03-15 Dimitri N. Laikov

Transition to a nonrelativistic Pauli equation in Riemann space of constant positive curvature for a Dirac particle in presence of the Coulomb field is performed in the system of radial equations, exact solutions are constructed in terms of…

Mathematical Physics · Physics 2011-09-29 E. M. Ovsiyuk

With the aid of a modified similarity transformation we obtained exact energy eigenvalues of the generalized Dirac-Coulomb equation. This equation consists of the time component of the Lorentz 4-vector potential V_v(r)=-A_1/r, and a Lorentz…

Mathematical Physics · Physics 2007-05-23 Omar Mustafa , Thabit Barakat

Describing the Coulomb interactions between electrons in atomic or molecular systems is an important step to help us obtain accurate results for the different observables in the system. One convenient approach is to separate the dynamic…

Chemical Physics · Physics 2025-01-22 Claude Le Sech , Antonio Sarsa

An electrodynamical coupled cluster (CC) methodology starting from a covariant formalism and an equal time approximation, and finally based on the Dirac-Fock picture of the electron and positron fields and Coulomb gauge, is given here. The…

Atomic Physics · Physics 2019-04-30 Sambhu N. Datta

The ambiguity involved in the definition of effective-mass Hamiltonians for nonrelativistic models is resolved using the Dirac equation. The multistep approximation is extended for relativistic cases allowing the treatment of arbitrary…

Condensed Matter · Physics 2009-10-31 R. Renan , M. H. Pacheco , C. A. S. Almeida

The traditional approach to accelerator optics, based mainly on classical mechanics, is working excellently from the practical point of view. However, from the point of view of curiosity, as well as with a view to explore quantitatively the…

Accelerator Physics · Physics 2007-05-23 R. Jagannathan

We consider a single particle which is bound by a central potential and obeys the Dirac equation in d dimensions. We first apply the asymptotic iteration method to recover the known exact solutions for the pure Coulomb case. For a…

Mathematical Physics · Physics 2009-11-11 Hakan Ciftci , Richard L. Hall , Nasser Saad

We present an analytic ansatz to find the effective electrostatic potential and Coulomb correlations in multicenter problems, specifically homogeneous and doped clusters of metal atoms. The approach is based on a quasi-classical…

Chemical Physics · Physics 2007-05-23 F. Despa , R. S. Berry

An explicitly orbital-dependent correlation energy functional is proposed, which is to be used in combination with the orbital-dependent exchange energy functional in energy-band calculations. It bears a close resemblance to the…

Strongly Correlated Electrons · Physics 2009-11-10 Masahiko Higuchi , Hiroshi Yasuhara

A computational method is proposed to calculate bound and resonant states by solving the Klein-Gordon and Dirac equations for real and complex energies, respectively. The method is an extension of a non-relativistic one, where the potential…

Quantum Physics · Physics 2023-12-06 D. Wingard , B. Kónya , Z. Papp

We consider a specific form of explicitly correlated Gaussians -- with tensor pre-factors -- which appear naturally when dealing with certain few-body systems in nuclear and particle physics. We derive analytic matrix elements with these…

Nuclear Theory · Physics 2024-09-12 D. V. Fedorov , A. F. Teilmann , M. C. Østerlund , T. L. Norrbohm

Exact solutions of the Dirac equation, a system of four partial differential equations, are rare. The vast majority of them are for highly symmetric stationary systems. Moreover, only a handful of solutions for time dependent dynamics…

Quantum Physics · Physics 2021-03-24 Andre G. Campos , Karen Z. Hatsagortsyan , Christoph H. Keitel

We present exact analytical solutions of the Dirac equation in $(1+1)$-dimensions for the generalized Kratzer potential by taking the pseudoscalar interaction term as an attractive Coulomb potential. We study the problem for a particular…

Quantum Physics · Physics 2019-01-18 Altug Arda , Ramazan Sever

Coulomb interactions that occur in electronic structure calculations are correlated by allowing basis function components of the interacting densities to polarize, thereby reducing the magnitude of the interaction. Exchange integrals of…

Chemical Physics · Physics 2022-05-16 Jerry L. Whitten

The Coulomb potential produced by an ultrarelativistic particle (such as a heavy ion) in uniform motion is shown in the appropriate gauge to factorize into a longitudinal Dirac delta function of (z - t) times the simple two dimensional…

Nuclear Theory · Physics 2009-10-28 A. J. Baltz

We develop a relativistic model to describe the bound states of positive energy and negative energy in finite nuclei at the same time. Instead of searching for the negative-energy solution of the nucleon's Dirac equation, we solve the Dirac…

Nuclear Theory · Physics 2016-08-15 G. Mao , H. Stöcker , W. Greiner

It is a well known fact that Dirac phenomenology of nuclear forces predicts the existence of large scalar and vector mean fields in matter. To analyse the relativistic self-energy in a model independent way, modern high precision…

Nuclear Theory · Physics 2008-11-26 O. Plohl , C. Fuchs

The Dirac equation with the Coulomb potential is studied. It is shown that there exists a new invariant in addition to the known Dirac and Johnson-Lippman ones. The solution of the Dirac equation, using the generalized invariant, and…

Quantum Physics · Physics 2020-09-22 A. A. Eremko , L. Brizhik , V. M. Loktev