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It is a commonly accepted creed that in typical situations the rate of entropy production is non-negative. We show that this assertion is not entirely correct if a time-dependent, external perturbation is not compensated by a rapid enough…

Statistical Mechanics · Physics 2021-01-20 Marcus V. S. Bonança , Pierre Nazé , Sebastian Deffner

We report on a numerical experiment performed to analyze fluctuations of the entropy production in turbulent thermal convection, a physical configuration that represents here a prototypical case of an out-of-equilibrium dissipative system.…

Statistical Mechanics · Physics 2016-07-12 Francesco Zonta , Sergio Chibbaro

The second law of thermodynamics posits that in closed macroscopic systems the rate of entropy production must be positive. However, small systems can exhibit negative entropy production over short timescales, seemingly in contradiction…

Quantum Gases · Physics 2023-08-08 Rama Sharma , Tapio P. Simula , Andrew J. Groszek

We demonstrate that the Gibbs-Shannon entropy is applicable to non-equilibrium systems of any size and boundary conditions. The change in microscopic entropy can be attributed to the stochastic nature of dynamic processes and to the…

Statistical Mechanics · Physics 2020-10-13 Jianzhong Wu

Fluctuation theorems establish that thermodynamic processes at the microscale can occasionally result in negative entropy production. At the microscale, another distinct possibility becomes more likely: processes in which no entropy is…

Statistical Mechanics · Physics 2026-03-11 Abhaya S. Hegde , André M. Timpanaro , Gabriel T. Landi

Asymptotic fluctuation theorems are statements of a Gallavotti-Cohen symmetry in the rate function of either the time-averaged entropy production or heat dissipation of a process. Such theorems have been proved for various general classes…

Mathematical Physics · Physics 2010-01-23 Benjamin Hertz Shargel , Tom Chou

The fluctuation theorem for entropy production is a remarkable symmetry of the distribution of produced entropy that holds universally in non-equilibrium steady states with Markovian dynamics. However, in systems with slow degrees of…

Statistical Mechanics · Physics 2018-02-21 Matthias Uhl , Patrick Pietzonka , Udo Seifert

The irreversibility of trajectories in stochastic dynamical systems is linked to the structure of their causal representation in terms of Bayesian networks. We consider stochastic maps resulting from a time discretization with interval \tau…

Data Analysis, Statistics and Probability · Physics 2018-03-15 Andrea Auconi , Andrea Giansanti , Edda Klipp

Thermodynamic uncertainty relations reveal a fundamental trade-off between the precision of a trajectory observable and entropy production, where the uncertainty of the observable is quantified by its variance. In information theory,…

Statistical Mechanics · Physics 2025-11-25 Yoshihiko Hasegawa , Tomohiro Nishiyama

Without violating causality, we allow performing measurements in time reverse process of a feedback manipulated stochastic system. As a result we come across an entropy production due to the measurement process. This entropy production, in…

Statistical Mechanics · Physics 2015-06-17 A. Kundu

Fluctuation theorems specify the non-zero probability to observe negative entropy production, contrary to a naive expectation from the second law of thermodynamics. For closed particle trajectories in a fluid, Stokes theorem can be used to…

Statistical Mechanics · Physics 2022-07-06 Benoît Mahault , Evelyn Tang , Ramin Golestanian

We suggest a certain statistical interpretation for the entropy produced in driven thermodynamic processes. The exponential function of half irreversible entropy re-weights the probability of the standard Ornstein-Uhlenbeck-type…

Chemical Physics · Physics 2007-05-23 Lajos Diosi

Fluctuation theorems allow one to make generalised statements about the behaviour of thermodynamic quantities in systems that are driven far from thermal equilibrium. In this article we use Crooks' fluctuation theorem to understand the…

Quantum Physics · Physics 2022-08-24 M. J. Kewming , S. Shrapnel

Fluctuation theorems are fundamental results in non-equilibrium thermodynamics. Considering the fluctuation theorem with respect to the entropy production and an observable, we derive a new thermodynamic uncertainty relation which also…

Statistical Mechanics · Physics 2022-02-02 Gianluca Francica

In stochastic thermodynamics, the entropy production of a thermodynamic system is defined by the irreversibility measured by the logarithm of the ratio of the path probabilities in the forward and reverse processes. We derive the relation…

Statistical Mechanics · Physics 2018-03-14 Hyun-Myung Chun , Jae Dong Noh

Small systems in contact with a heat bath evolve by stochastic dynamics. Here we show that, when one such small system is weakly coupled to another one, it is possible to infer the presence of such weak coupling by observing the violation…

Statistical Mechanics · Physics 2016-11-07 Deepak Gupta , Sanjib Sabhapandit

The probability distribution of the total entropy production in the non-equilibrium steady state follows a symmetry relation called the fluctuation theorem. When a certain part of the system is masked or hidden, it is difficult to infer the…

Statistical Mechanics · Physics 2020-04-29 Deepak Gupta , Sanjib Sabhapandit

Stochastic thermodynamics provides the framework to analyze thermodynamic laws and quantities along individual trajectories of small but fully observable systems. If the observable level fails to capture all relevant degrees of freedom,…

Statistical Mechanics · Physics 2024-07-01 Julius Degünther , Jann van der Meer , Udo Seifert

We derive the main equations of irreversible thermodynamic including the expression for the Glansdorff-Prigogine extremal principle from stochastic thermodynamics. To this end, we analyze a system that is subject to gradients of temperature…

Statistical Mechanics · Physics 2025-01-28 Tânia Tomé , Mário J. de Oliveira

Fluctuation theorems make use of time reversal to make predictions about entropy production in many-body systems far from thermal equilibrium. Here we review the wide variety of distinct, but interconnected, relations that have been derived…

Statistical Mechanics · Physics 2007-08-02 R. J. Harris , G. M. Schütz
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