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First-principles density functional theory (DFT) is employed to investigate the interactions of CO2 gas molecules with pristine and lithium-functionalized germanene. It is discovered that although a single CO2 molecule is weakly physisorbed…

Mesoscale and Nanoscale Physics · Physics 2017-05-17 S. M. Aghaei , M. M. Monshi , I. Torres , I. Calizo

Diamond and diamond-like carbon (DLC) are used as coating materials for numerous applications, ranging from biomedicine to tribology. Recently, it has been shown that the hydrophilicity of the carbon films can be enhanced by silicon doping,…

Mesoscale and Nanoscale Physics · Physics 2016-04-19 Seiji Kajita , M. C. Righi

Burning fossil fuels emits a significant amount of CO2, causing climate change concerns. CO2 Capture and Storage (CCS) aims to reduce emissions, with fullerenes showing promise as CO2 adsorbents. Recent research focuses on modifying…

Direct air capture of carbon dioxide (CO$_2$) is one of the most promising strategies to mitigate rising atmospheric CO$_2$ levels. Among various techniques, adsorption using porous materials is a viable method for extracting CO$_2$ from…

Materials Science · Physics 2025-10-09 N. van Dongen , A. J. F. van Hoof , S. Calero , J. M. Vicent-Luna

The B-doped monatomic carbon chain has fine molecular capture ability to H2O and especially to NO2, better than other doped monatomic carbon chains.At 300 K and 1 atm, the capture probability of the B-doped monatomic carbon chain is…

Mesoscale and Nanoscale Physics · Physics 2013-11-12 Zheng-Zhe Lin , Xi Chen

We show, with both experiment and theory, that adsorption of $CO_2$ is sensitive to charge on a capturing model carbonaceous surface. In the experiment we dope superfluid helium droplets with $C_{60}$ and $CO_2$ and expose them to ionising…

Atomic and Molecular Clusters · Physics 2016-09-06 Stefan Ralser , Alexander Kaiser , Michael Probst , Johannes Postler , Michael Renzler , Diethard K. Bohme , Paul Scheier

First-principles calculations based on density functional theory (DFT) have been employed to investigate the structural, electronic, and gas-sensing properties of pure, defected, and doped germanene nanosheets. Our calculations have…

Materials Science · Physics 2017-07-13 Md Monirojjaman Monshi , Sadegh Mehdi Aghaei , Irene Calizo

Hydrogen storage remains a key challenge for the development of a sustainable hydrogen energy system, where materials must satisfy requirements on storage capacity, thermodynamics, kinetics, and reversibility. Complex borohydrides are…

Materials Science · Physics 2026-04-13 Sikander Azam , Wilayat Khan

Using first-principle density functional theory, we investigated the hydrogen storage capacity of Li functionalized adamantane. We showed that if one of the acidic hydrogen atoms of adamantane is replaced by Li/Li+, the resulting complex is…

Mesoscale and Nanoscale Physics · Physics 2015-05-27 Ahmad Ranjbar , Mohammad Khazaei , Natarajan Sathiyamoorthy Venkataramanan , Hoonkyung Lee , Yoshiyuki Kawazoe

This study employs density functional theory (DFT) and density functional tight-binding theory (DFTB) to determine the adsorption properties of carbon dioxide (CO$_2$), methane (CH$_4$), and dihydrogen (H$_2$) in carbophenes functionalized…

The amorphous conducting carbon films have been prepared at three different preparation temperatures with different boron-doping levels. The structural and transport properties of the same have been studied. X-ray diffraction measurements…

Disordered Systems and Neural Networks · Physics 2007-05-23 P. N. Vishwakarma , S. V. Subramanyam

CO$_2$ capture using carbon-based materials, particularly graphene and graphene-like materials, is a promising strategy to deal with CO$_2$ emissions. However, significant gaps remain in our understanding of the molecular-level interaction…

Diborane (B$_2$H$_6$) is a promising molecular precursor for atomic precision p-type doping of silicon that has recently been experimentally demonstrated [T. {\v{S}}kere{\v{n}}, \textit{et al.,} Nature Electronics (2020)]. We use density…

A novel system containing nanoporous materials and carbonate ions is proposed, which is capable to capture CO2 from ambient air simply by controlling the amount of water (humidity) in the system. The system absorbs CO2 from the air when the…

Chemical Physics · Physics 2017-02-02 Xiaoyang Shi , Hang Xiao , Xi Chen , Klaus. S. Lackner

Two-dimensional (2D) materials have received considerable attention as possible electrodes in Li-ion batteries (LIBs), although a deeper understanding of the Li adsorption behavior as well as broad screening of the materials space is still…

Materials Science · Physics 2022-03-22 Sheng Gong , Shuo Wang , Taishan Zhu , Xi Chen , Jeffrey C. Grossman

We present molecular dynamics simulations of the adsorption of mixed CO2-water vapors on a graphene flakes substrate, a model inspired by the microporous structure of activated carbons. Adsorption strength is quantified through a reduced…

Materials Science · Physics 2025-12-17 Silvina Gatica

Adsorption of eight organic molecules (acetone, acetonitrile, ammonia, benzene, methane, methanol, ethanol, and toluene) onto silicene has been investigated using van der Waals density functional theory calculations (DFT-D). The calculated…

Mesoscale and Nanoscale Physics · Physics 2014-09-23 Thaneshwor P. Kaloni , Georg Schreckenbach , Michael S. Freund

Direct air capture (DAC) of carbon dioxide is a critical technology for mitigating climate change, but current materials face limitations in efficiency and scalability. We discover novel DAC materials using a combined machine learning (ML)…

Materials Science · Physics 2024-10-21 Megan C. Davis , Wilton J. M. Kort-Kamp , Ivana Matanovic , Piotr Zelenay , Edward F. Holby

The newly developed compound ExBox4+ is explored to check whether it is a proficient hydrogen storage material. Both exoherdal and endohedral hydrogen adsorption on ExBox4+ are studied. Endohedral hydrogen molecules interact strongly than…

Atomic and Molecular Clusters · Physics 2014-01-03 Ranjita Das , Pratim Kumar Chattaraj

The urgent need to mitigate rising atmospheric CO2 levels motivates the search for stable, efficient, and tunable adsorbent materials. In this study, we employ first-principles density functional theory to investigate the adsorption of CO2…

Materials Science · Physics 2026-02-16 Jakkapat Seeyangnok , Rungkiat Nganglumpoon , Joongjai Panpranot , Udomsilp Pinsook
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