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After initial proof-of-principle demonstrations, optically pumped nitrogen-vacancy (NV) centres in diamond have been proposed as a non-invasive platform to achieve hyperpolarisation of nuclear spins in molecular samples over macroscopic…

Mesoscale and Nanoscale Physics · Physics 2021-01-27 J. -P. Tetienne , L. T. Hall , A. J. Healey , G. A. L. White , M. -A. Sani , F. Separovic , L. C. L. Hollenberg

Symmetry considerations are used in presenting a model of the electronic structure and the associated dynamics of the nitrogen-vacancy center in diamond. The model accounts for the occurrence of optically induced spin polarization, for the…

Materials Science · Physics 2013-05-29 N. B. Manson , J. P. Harrison , M. J. Sellars

The photoluminescence of nitrogen-vacancy (NV) centers in diamond nanoparticles exhibits specific properties as compared to NV centers in bulk diamond. For instance large fluctuations of lifetime and brightness from particle to particle…

Optics · Physics 2011-07-05 J. -J. Greffet , J. -P. Hugonin , M. Besbes , N. D. Lai , F. Treussart , J. -F. Roch

Single charge detection with nanoscale spatial resolution in ambient conditions is a current frontier in metrology that has diverse interdisciplinary applications. Here, such single charge detection is demonstrated using two…

We report electrical tuning by the Stark effect of the excited-state structure of single nitrogen-vacancy (NV) centers located less than ~100 nm from the diamond surface. The zero-phonon line (ZPL) emission frequency is controllably varied…

Although chemical vapor deposition (CVD) is one of the preferred routes to synthetic diamond crystals, a full knowledge of the point defects produced during growth is still incomplete. Here we exploit the charge and spin properties of…

Materials Science · Physics 2020-05-20 A. Lozovoi , D. Daw , H. Jayakumar , C. A. Meriles

We investigate nuclear spin hyperpolarization from nitrogen vacancy centers in isotopically enriched diamonds with $^{13}$C concentrations up to 100%. $^{13}$C enrichment leads to hyperfine structure of the nitrogen vacancy electron spin…

We determine and analyze the charge and spin density distributions of nitrogen-vacancy (N-V) center in diamond for both the ground and excited states by \emph{ab initio} supercell calculations. We show that the hyperfine tensor of $^{15}$N…

Materials Science · Physics 2009-05-11 Adam Gali

Ensembles of nitrogen-vacancy (NV) centers in diamond are a leading platform for practical quantum sensors. Reproducible and scalable fabrication of NV-ensembles with desired properties is crucial. This work addresses these challenges by…

We report the formation of perfectly aligned, high-density, shallow nitrogen vacancy (NV) centers on the ($111$) surface of a diamond. The study involved step-flow growth with a high flux of nitrogen during chemical vapor deposition (CVD)…

Mesoscale and Nanoscale Physics · Physics 2017-09-13 Hitoshi Ishiwata , Makoto Nakajima , Kosuke Tahara , Hayato Ozawa , Takayuki Iwasaki , Mutsuko Hatano

A key limitation of electron paramagnetic resonance (EPR), an established and powerful tool for studying atomic-scale biomolecular structure and dynamics is its poor sensitivity, samples containing in excess of 10^12 labeled biomolecules…

We study spectroscopy of negatively charged nitrogen-vacancy center in diamond at high temperatures under high vacuum conditions. Spin resonances are studied using optical detection of magnetic resonance (ODMR), and optical spectroscopy is…

Quantum Physics · Physics 2023-03-15 Mohammed Attrash , Oleg Shtempluck , Eyal Buks

In this paper, we study the photoinduced switching of the nitrogen-vacancy (NV) center between two different charge states - negative (NV-) and neutral (NV0) at liquid helium temperature. The conversion of NV- to NV0 on a single defect is…

Quantum Physics · Physics 2013-04-17 P. Siyushev , H. Pinto , A. Gali , F. Jelezko , J. Wrachtrup

Over the years, an enormous effort has been made to establish nitrogen vacancy (NV) centers in diamond as easily accessible and precise magnetic field sensors. However, most of their sensing protocols rely on the application of bias…

Nitrogen-vacancy (NV) center in diamond is a promising quantum sensor with remarkably versatile sensing capabilities. While scanning NV magnetometry is well-established, NV electrometry has been so far limited to bulk diamonds. Here we…

Quantum Physics · Physics 2022-10-12 Ziwei Qiu , Assaf Hamo , Uri Vool , Tony X. Zhou , Amir Yacoby

We present a density functional theory analysis of the negatively charged nitrogen-vacancy (NV$^-$) defect complex in diamond located in the vicinity of (111)- or (100)-oriented surfaces with mixed (N,H)-terminations. We assess the…

Materials Science · Physics 2022-02-21 Wolfgang Körner , Reyhaneh Ghassemizadeh , Daniel F. Urban , Christian Elsässer

Deep defects in wide band gap semiconductors have emerged as leading qubit candidates for realizing quantum sensing and information applications. Due to the spatial localization of the defect states, these deep defects can be considered as…

The nitrogen-vacancy (NV) colour centre in diamond is an important physical system for emergent quantum technologies, including quantum metrology, information processing and communications, as well as for various nanotechnologies, such as…

The ability to perform nanoscale electric field imaging of elementary charges at ambient temperatures will have diverse interdisciplinary applications. While the nitrogen-vacancy (NV) center in diamond is capable of high-sensitivity…

Mesoscale and Nanoscale Physics · Physics 2021-04-28 M. S. J Barson , L. M. Oberg , L. P. McGuinness , A. Denisenko , N. B. Manson , J. Wrachtrup , M. W. Doherty

The charge degree of freedom in solid-state defects fundamentally underpins the electronic spin degree of freedom, a workhorse of quantum technologies. Here we study charge state properties of individual near-surface nitrogen-vacancy (NV)…

Mesoscale and Nanoscale Physics · Physics 2019-02-26 Dolev Bluvstein , Zhiran Zhang , Ania C. Bleszynski Jayich