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Understanding hydrogen-grain boundary (GB) interactions is critical to the analysis of hydrogen embrittlement in metals. This work presents a mesoscale fully kinetic model to investigate the effect of GB misorientation on hydrogen diffusion…

Materials Science · Physics 2024-12-31 Abdelrahman Hussein , Byungki Kim , Kim Verbeken , Tom Depover

We investigate how the existence of hydrogen molecules on grain surfaces may affect H$_2$ formation efficiency in diffuse and translucent clouds. Hydrogen molecules are able to reduce the desorption energy of H atoms on grain surfaces in…

Astrophysics of Galaxies · Physics 2022-03-30 Gang Zhao , Qiang Chang , Xia Zhang , Donghui Quan , Yong Zhang , Xiao-Hu Li

Hydrogen embrittlement (HE) poses a significant challenge in the mechanical integrity of iron and its alloys. This study explores the influence of hydrogen atoms on two distinct grain boundaries (GBs), $\Sigma37$ and $\Sigma3$, in…

Materials Science · Physics 2024-07-04 Aynour Khosravi , Jun Song , Normand Mousseau

Molecular hydrogen is a fascinating candidate for quantum fluid showing bosonic and fermionic superfluidity. We have studied diffusion dynamics of thin films of H$_2$, HD and D$_2$ adsorbed on a glass substrate by measurements of…

Strongly Correlated Electrons · Physics 2019-12-18 Takahiko Makiuchi , Katsuyuki Yamashita , Michihiro Tagai , Yusuke Nago , Keiya Shirahama

The electrochemical permeation test is one of the most used methods for characterising hydrogen diffusion in metals. The flux of hydrogen atoms registered in the oxidation cell might be fitted to obtain apparent diffusivities. The magnitude…

Materials Science · Physics 2019-12-06 A. Díaz , I. I. Cuesta , E. Martínez-Pañeda , J. M. Alegre

We report a first-principles density functional theory study on the role of grain boundary and dislocation loop in H blistering in W. At low temperature, the {\Sugma}3(111) tilt grain boundary, when combined with a vacancy of vanishing…

Materials Science · Physics 2015-05-27 W. Xiao , W. T. Geng

Grain boundary (GB) diffusion in polycrystalline materials is a physical phenomenon of great fundamental interest and practical significance. Although the accelerated ("short circuit") atomic transport along GBs has been known for decades,…

Materials Science · Physics 2022-08-02 Ian Chesser , Yuri Mishin

This paper presents an overview of recent computer simulations of grain boundary (GB) diffusion focusing on atomistic understanding of diffusion mechanisms. At low temperatures when GB structure is ordered, diffusion is mediated by point…

Materials Science · Physics 2019-04-25 Y. Mishin

Hydrogen grain boundary (GB) trapping is widely accepted as the main cause for hydrogen induced intergranular failure. Several studies were conducted to unveil the role of GBs on hydrogen transport; however, a clear understanding is yet to…

Materials Science · Physics 2024-12-30 Abdelrahman Hussein , Byungki Kim , Tom Depover , Kim Verbeken

Rutile-type RuO2 likely supports a simple antiferromagnetic structure which can be verified by x-ray Bragg diffraction. Three magnetic motifs that do not break translation symmetry are explored in calculations of amplitudes suitable for…

Strongly Correlated Electrons · Physics 2022-01-12 S. W. Lovesey , D. D. Khalyavin , G. van der Laan

This manuscript embarks on an inquiry into the influence of helium implantation on nanocrystalline tungsten, a contender for plasma-facing components (PFCs) in nuclear fusion reactors. The study underscores the inevitability of helium…

Materials Science · Physics 2024-03-20 Yang Zhang , Jason Trelewicz

Hydrogen embrittlement remains a critical challenge in structural and electronic applications of copper (Cu) but its mechanism is still not fully understood. In this study, we combine density functional theory (DFT) and bond-order potential…

Materials Science · Physics 2026-03-17 Vasileios Fotopoulos , Alexander L. Shluger

To investigate the barrier effect of grain boundaries on the propagation of avalanche-like plasticity at the atomic-scale, we perform three-dimensional molecular dynamics simulations by using simplified polycrystal models including…

Materials Science · Physics 2017-01-19 Tomoaki Niiyama , Tomotsugu Shimokawa

We describe an optical scattering study of grain boundary premelting in water ice. Ubiquitous long ranged attractive polarization forces act to suppress grain boundary melting whereas repulsive forces originating in screened Coulomb…

Materials Science · Physics 2013-05-23 E. S. Thomson , Hendrik Hansen-Goos , L. A. Wilen , J. S. Wettlaufer

Grain boundary roughness can affect electronic and mechanical properties of two-dimensional materials. This roughness depends crucially on the growth process by which the two-dimensional material is formed. To investigate the key mechanisms…

Materials Science · Physics 2022-04-06 Fabio D. A. Aarão Reis , Bastien Marguet , Olivier Pierre-Louis

A realistic tight-binding model is developed and employed to elucidate the resistivity size effect due to steps on Ru thin films. The resistivity of two different film orientations, $(0001)$ and $(1 \bar{1}00)$, is computed for transport…

Mesoscale and Nanoscale Physics · Physics 2021-11-23 W. E. Richardson , E. R. Mucciolo , P. K. Schelling

The accumulation of helium bubbles at grain boundaries (GBs) critically degrades the mechanical integrity of structural materials in nuclear reactors. While GBs act as sinks for radiation-induced defects, their inherent structural…

Materials Science · Physics 2025-09-10 Yang Zhang , Peter Hatton , Blas P. Uberuaga , Jason R. Trelewicz

Researchers are currently exploring nanoporous two-dimensional materials, such as hexagonal boron nitride (hBN), as potential desalination membranes. Here, we study the effect of grain boundaries (GBs) and interfacial electrostatic…

Materials Science · Physics 2022-02-22 Ananth Govind Rajan , Bharat Bhushan Sharma

Polycrystalline materials can be viewed as composites of crystalline particles or grains separated from one another by thin amorphous grain boundary (GB) regions. While GB have been exhaustively investigated at low temperatures, where these…

Materials Science · Physics 2015-05-13 Hao Zhang , David J. Srolovitz , Jack F. Douglas* , James A. Warren

Ruthenium (Ru) is a promising candidate for the next-generation of electronic interconnects due to its low resistivity, small mean free path, and superior electromigration reliability at nanometer scales. Additionally, Ru exhibits…

Superconductivity · Physics 2025-12-03 Bernardo Langa , Brooke Henry , Ivan Lainez , Richard Haight , Kasra Sardashti
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