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Related papers: Excited-state DMRG made simple with FEAST

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We propose a new block localized excitation (BLE) method to directly construct diabatic excited states without the need to first compute the adiabatic states. The new method is capable to keep any electrons, spins, and excitations localized…

Chemical Physics · Physics 2020-01-22 Peng Bao , Qiang Shi , Jiali Gao

In these lecture notes, we present a pedagogical review of a number of related {\it numerically exact} approaches to quantum many-body problems. In particular, we focus on methods based on the exact diagonalization of the Hamiltonian matrix…

Strongly Correlated Electrons · Physics 2007-05-23 Reinhard M. Noack , Salvatore R. Manmana

Dukelsky, Mart\'in-Delgado, Nishino and Sierra (Europhys. Lett., 43, 457 (1998) - hereafter referred to as DMNS) investigated the matrix product method (MPM), comparing it with the infinite-size density matrix renormalization group (DMRG).…

Strongly Correlated Electrons · Physics 2009-11-07 I. P. McCulloch , M. Gulacsi

In this contribution we review in a rigorous, yet comprehensive fashion the assessment of the one-body reduced density matrices derived from the most used single-reference excited-state calculation methods in the framework of the…

Chemical Physics · Physics 2021-04-19 Thibaud Etienne

We reformulate the density matrix renormalization group method (DMRG) in terms of a single block, instead of the standard left and right blocks used in the construction of the superblock. This version of the DMRG, which we call the puncture…

Condensed Matter · Physics 2009-10-31 M. A. Martin-Delgado , J. Rodriguez-Laguna , G. Sierra

The computation of excited electronic states with commonly employed (approximate) methods is challenging, typically yielding states of lower quality than the corresponding ground state for a higher computational cost. In this work, we…

Materials Science · Physics 2020-04-01 Nell Karpinski , Pablo Ramos , Michele Pavanello

We present the first successful functional renormalization group(FRG)-aided density-functional (DFT) calculation of the equation of state (EOS) of an infinite nuclear matter (NM) in (1+1)-dimensions composed of spinless nucleons. We give a…

Nuclear Theory · Physics 2019-02-06 Takeru Yokota , Kenichi Yoshida , Teiji Kunihiro

We propose and work out a reduced density matrix functional theory (RDMFT) for calculating energies of eigenstates of interacting many-electron systems beyond the ground state. Various obstacles which historically have doomed such an…

Quantum Physics · Physics 2021-07-08 Christian Schilling , Stefano Pittalis

The authors propose a fast numerical renormalization group method --- the product wave function renormalization group (PWFRG) method --- for 1D quantum lattice models and 2D classical ones. A variational wave function, which is expressed by…

Condensed Matter · Physics 2016-08-31 T. Nishino , K. Okunishi

Intermolecular charge-transfer is a highly important process in biology and energy-conversion applications where generated charges need to be transported over several moieties. However, its theoretical description is challenging since the…

Chemical Physics · Physics 2024-05-03 Nicola Bogo , Christopher J. Stein

We theoretically derive and validate with large scale simulations a remarkably accurate power law scaling of errors for the restricted active space density matrix renormalization group (DMRG-RAS) method [arXiv:2111.06665] in electronic…

Chemical Physics · Physics 2023-04-04 Gero Friesecke , Gergely Barcza , Örs Legeza

A biorthonormal-block density-matrix renormalization group algorithm is proposed to accurately compute properties of large-scale non-Hermitian many-body systems, in which a renormalized-space partition of the non-Hermitian reduced density…

Strongly Correlated Electrons · Physics 2025-07-08 Peigeng Zhong , Wei Pan , Haiqing Lin , Xiaoqun Wang , Shijie Hu

We present two efficient and intruder-free methods for treating dynamic correlation on top of general multi-configuration reference wave functions---including such as obtained by the density matrix renormalization group (DMRG) with large…

Chemical Physics · Physics 2016-09-13 Sandeep Sharma , Gerald Knizia , Sheng Guo , Ali Alavi

Following a recent work [E. Fromager, J. Phys. Chem. A 2025, 129, 4, 1143-1155] on the ensemble density functional theory (DFT) of excited electronic energy levels, we derive in this paper the ensuing static linear response theory, thus…

Chemical Physics · Physics 2025-09-26 Lucien Dupuy , Emmanuel Fromager

We present a first principles strategy for developing state-specific density functional approximations for excited states. We first clarify why approaches based on conventional ground state approximations miss density-driven correlations,…

Chemical Physics · Physics 2025-06-09 Tim Gould , Stephen G Dale , Leeor Kronik , Stefano Pittalis

We propose an excited-state molecular dynamics simulation method based on variational quantum algorithms at a computational cost comparable to that of ground-state simulations. We utilize the feature that excited states can be obtained as…

Chemical Physics · Physics 2023-03-02 Hirotoshi Hirai

We propose a simple modification of the density matrix renormalization group (DMRG) method in order to tackle strongly disordered quantum spin chains. Our proposal, akin to the idea of the adaptive time-dependent DMRG, enables us to reach…

Strongly Correlated Electrons · Physics 2018-11-14 J. C. Xavier , J. A. Hoyos , E. Miranda

The density-matrix renormalization group (DMRG) algorithm can be adapted to the calculation of dynamical correlation functions in various ways which all represent compromises between computational efficiency and physical accuracy. In this…

Strongly Correlated Electrons · Physics 2012-11-19 P. E. Dargel , A. Wöllert , A. Honecker , I. P. McCulloch , U. Schollwöck , T. Pruschke

In previous work we have shown that the Density Matrix Renormalization Group (DMRG) enables near-exact calculations in active spaces much larger than are possible with traditional Complete Active Space algorithms. Here, we implement orbital…

Strongly Correlated Electrons · Physics 2009-11-13 Debashree Ghosh , Johannes Hachmann , Takeshi Yanai , Garnet K. -L. Chan

We introduce the transcorrelated Density Matrix Renormalization Group (tcDMRG) theory for the efficient approximation of the energy for strongly correlated systems. tcDMRG encodes the wave function as a product of a fixed Jastrow or…

Strongly Correlated Electrons · Physics 2020-11-13 Alberto Baiardi , Markus Reiher