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Density functional theory (DFT) has greatly expanded our ability to affordably compute and understand electronic ground states, by replacing intractable {\em ab initio} calculations by models based on paradigmatic physics from high- and…

Chemical Physics · Physics 2023-03-29 Tim Gould , Derk P. Kooi , Paola Gori-Giorgi , Stefano Pittalis

Based on the contractor renormalization group (CORE) method and the density matrix renormalization group (DMRG) method, a new computational scheme, which is called the block density matrix renormalization group with effective interactions…

Strongly Correlated Electrons · Physics 2009-11-18 Haibo Ma , Chungen Liu , Yuansheng Jiang

The Density Matrix Renormalisation Group (DMRG) is an electronic structure method that has recently been applied to ab-initio quantum chemistry. Even at this early stage, it has enabled the solution of many problems that would previously…

We present a novel formulation of the vibrational density matrix renormalization group (vDMRG) algorithm tailored to strongly anharmonic molecules described by general high-dimensional model representations of potential energy surfaces. For…

Chemical Physics · Physics 2023-12-29 Nina Glaser , Alberto Baiardi , Markus Reiher

We employ the density matrix renormalization group (DMRG) and the wave function factorization method for the numerical solution of large scale nuclear structure problems. The DMRG exhibits an improved convergence for problems with realistic…

Nuclear Theory · Physics 2007-05-23 T. Papenbrock , D. J. Dean

We present an extension of the time-dependent Density Matrix Renormalization Group (t-DMRG), also known as Time Evolving Block Decimation algorithm (TEBD), allowing for the computation of dynamically important excited states of…

Quantum Gases · Physics 2013-05-30 Mateusz Lacki , Dominique Delande , Jakub Zakrzewski

We improve the methodology to construct a complete active space-configuration interaction (CAS-CI) expansion for density-matrix renormalization group (DMRG) wave function using matrix-product state representation, inspired by the…

Strongly Correlated Electrons · Physics 2017-10-12 Zhen Luo , Yingjin Ma , Chungen Liu , Haibo Ma

Earlier this decade, the so-called FEAST algorithm was released for computing the eigenvalues of a matrix in a given interval. Previously, rational filter functions have been examined as a parameter of FEAST. In this thesis, we expand on…

Numerical Analysis · Computer Science 2017-10-24 Konrad Kollnig

We present a method for finding individual excited states' energy stationary points in complete active space self-consistent field theory that is compatible with standard optimization methods and highly effective at overcoming difficulties…

Strongly Correlated Electrons · Physics 2019-04-12 Lan Nguyen Tran , Jacqueline A. R. Shea , Eric Neuscamman

We introduce a class of variational states to describe quantum many-body systems. This class generalizes matrix product states which underly the density-matrix renormalization group approach by combining them with weighted graph states.…

Quantum Physics · Physics 2009-11-13 R. Hübener , C. Kruszynska , L. Hartmann , W. Dür , F. Verstraete , J. Eisert , M. B. Plenio

Density Matrix Renormalization Group (DMRG) or Matrix Product States (MPS) are widely acknowledged as highly effective and accurate methods for solving one-dimensional quantum many-body systems. However, the direct application of DMRG to…

Strongly Correlated Electrons · Physics 2024-11-25 Xiangjian Qian , Jiale Huang , Mingpu Qin

We have proposed a density-matrix renormalization group (DMRG) scheme to optimize the one-electron basis states of molecules. It improves significantly the accuracy and efficiency of the DMRG in the study of quantum chemistry or other…

Strongly Correlated Electrons · Physics 2010-10-20 H. -G. Luo , M. -P. Qin , T. Xiang

We introduce the Nuclear Electronic All-Particle Density Matrix Renormalization Group (NEAP-DMRG) method for solving the time-independent Schr\"odinger equation simultaneously for electrons and other quantum species. In contrast to already…

Chemical Physics · Physics 2020-05-29 Andrea Muolo , Alberto Baiardi , Robin Feldmann , Markus Reiher

We describe a low cost alternative to the standard variational DMRG (density matrix renormalization group) algorithm that is analogous to the combination of selected configuration interaction plus perturbation theory (SCI+PT). We denote the…

Chemical Physics · Physics 2018-03-28 Sheng Guo , Zhendong Li , Garnet Kin-Lic Chan

We present a general approach to converge excited state solutions to any quantum chemistry orbital optimization process, without the risk of variational collapse. The resulting Square Gradient Minimization (SGM) approach only requires…

Chemical Physics · Physics 2020-03-11 Diptarka Hait , Martin Head-Gordon

Expanding and improving the repertoire of numerical methods for studying quantum lattice models is an ongoing focus in many-body physics. While the density matrix renormalization group (DMRG) has been established as a practically useful…

Strongly Correlated Electrons · Physics 2021-09-28 Maxwell Block , Johannes Motruk , Snir Gazit , Michael P. Zaletel , Zeph Landau , Umesh Vazirani , Norman Y. Yao

A momentum-space approach of the density-matrix renormalization-group (DMRG) method is developed. Ground state energies of the Hubbard model are evaluated using this method and compared with exact diagonalization as well as quantum…

Condensed Matter · Physics 2009-10-28 T. Xiang

In this paper we give an introduction to the numerical density matrix renormalization group (DMRG) algorithm, from the perspective of the more general matrix product state (MPS) formulation. We cover in detail the differences between the…

Strongly Correlated Electrons · Physics 2009-11-13 Ian P. McCulloch

We propose a density matrix renormalization group (DMRG) technique at finite temperatures. As is the case of the ground state DMRG, we use a single-target state that is calculated by making use of a regulated polynomial expansion. Both…

Strongly Correlated Electrons · Physics 2009-03-09 Shigetoshi Sota , Takami Tohyama

A numerical approach to ground-state dynamical correlation functions from Density Matrix Renormalization Group (DMRG) is developed. Using sum rules, moments of a dynamic correlation function can be calculated with DMRG, and with the moments…

Condensed Matter · Physics 2016-08-31 Hanbin Pang , H. Akhlaghpour , M. Jarrell