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We demonstrate that collective vibrational strong coupling of molecules in thermal equilibrium can give rise to significant local electronic polarizations in the thermodynamic limit. We do so by first showing that the full non-relativistic…

Microcavity polaritons are light-matter quasiparticles that arise from the strong coupling between excitons and photons confined in a semiconductor microcavity. They typically operate at visible or near visible wavelengths. They combine the…

Mesoscale and Nanoscale Physics · Physics 2020-11-06 Dmitry D. Solnyshkov , Guillaume Malpuech , Philippe St-Jean , Sylvain Ravets , Jacqueline Bloch , Alberto Amo

Molecular polaritons, hybrid light-matter states formed from the strong coupling of molecular transitions and discrete photonic modes, are a compelling platform for optical control of chemical reactivity. Despite the origins of the field of…

Chemical Physics · Physics 2026-02-11 Jane C. Nelson , Trevor H. Wright , Neo Lin , Madeline Rohde , Marissa L. Weichman

In this work, we systematically investigate the spectral and transport properties of exciton-polaritons under the explicit influence of intermolecular vibrational coupling, which introduces dynamic disorder. In the context of a…

Chemical Physics · Physics 2025-12-03 Guangming Liu , Hsing-Ta Chen

Experimental evidence of strong coupling between excitons confined in a quantum well and the photonic modes of a two-dimensional dielectric lattice is reported. Both resonant scattering and photoluminescence spectra at low temperature show…

Polaritonic states, which arise from strong coupling between light and matter, show great promise in modifying chemical reactivity. However, reproducible enhancement of chemical reactions with polaritons is challenging due to a lack of…

Chemical Physics · Physics 2025-01-14 Shahzad Alam , Yicheng Liu , Russell J. Holmes , Renee R. Frontiera

Surface plasmon polaritons scattering from 2D subwavelength silicon wires is investigated using finite difference time domain method. It is shown that coupling an incident surface plasmon polariton to inter-cavity modes of the particle can…

The spectra of polaritons in bigyrotropic medium are received. The ion and electron polarizations of medium under influence of high-frequency electromagnetic and external magnetostatic field are considered. It is shown that by varying of…

Optics · Physics 2012-04-24 I. V. Dzedolik , O. S. Karakchieva

We demonstrate strong light-matter interaction at ambient conditions between a ladder-type conjugated polymer and the individual modes of a vertical microcavity with tunable resonance frequencies. Zero-dimensional wavelength-scale…

Mesoscale and Nanoscale Physics · Physics 2019-01-28 Darius Urbonas , Thilo Stöferle , Fabio Scafirimuto , Ullrich Scherf , Rainer F. Mahrt

Systems with strong light-matter interaction opens up new avenues for studying topological phases of matter. Examples include exciton-polaritons, mixed light-matter quasiparticles, where the topology of the polaritonic band structure arises…

Optics · Physics 2023-02-08 Li He , Jingda Wu , Jicheng Jin , Eugene J. Mele , Bo Zhen

In the last years, Infrared Reflection-Absorption Spectroscopy (IRRAS) became a standard technique to study vibrational excitations of molecules. These investigations are strongly motivated by perspective applications in monitoring chemical…

The way molecules absorb, transfer, and emit light can be modified by coupling them to optical cavities. The extent of the modification is often defined by the cavity-molecule coupling strength, which depends on the number of coupled…

Optics · Physics 2021-06-11 Adarsh B Vasista , Kishan S Menghrajani , William L Barnes

A series of experiments demonstrate that strong light-matter coupling between vibrational excitations in isotropic solutions of molecules and resonant infrared optical microcavity modes leads to modified thermally-activated kinetics.…

Chemical Physics · Physics 2020-06-23 Jorge A. Campos-Gonzalez-Angulo , Joel Yuen-Zhou

Polarization is well known for its ability to decompose diffuse and specular reflections. However, the existing decomposition methods only focus on direct reflection and overlook multiple reflections, especially specular inter-reflection.…

Computer Vision and Pattern Recognition · Computer Science 2026-03-24 Ryota Maeda , Shinsaku Hiura

Modeling the dielectric behavior of molecular materials made up of large pi-conjugated molecules is an interesting and complex task. Here we address linear polarizabilities, and the related dielectric constant, of molecular crystals and…

Chemical Physics · Physics 2007-05-23 Francesca Terenziani , Anna Painelli , Zoltan G. Soos

Polaritons, formed as a result of strong hybridization of matter with light, are promising for important applications including organic solar cells, optical logic gates, and qubits. Owing to large binding energies of Frenkel excitons…

We consider an ensemble of diatomic molecules resonantly coupled to an optical cavity under strong coupling conditions at normal incidence. Photodissociation dynamics is examined via direct numerical integration of the coupled…

Chemical Physics · Physics 2023-03-08 Maxim Sukharev , Joseph Subotnik , Abraham Nitzan

The scientific community has witnessed tremendous expansion of research on layered (i.e. two-dimensional, 2D) materials, with increasing recent focus on applications to photonics. Layered materials are particularly exciting for manipulating…

Materials Science · Physics 2020-11-17 Akshay Singh , Seong Soon Jo , Yifei Li , Changming Wu , Mo Li , R. Jaramillo

We present a detailed and self-contained theoretical study of polarons in two-dimensional (2D) polar materials, which extends the classical macroscopic theory of Fr\"ohlich polarons to the 2D case. The theory is fully determined by…

Mesoscale and Nanoscale Physics · Physics 2025-07-16 A. Kudlis , V. Shahnazaryan , I. V. Tokatly

Extreme confinement of electromagnetic energy by phonon polaritons holds the promise of strong and new forms of control over the dynamics of matter. To bring such control to the atomic-scale limit, it is important to consider phonon…

Mesoscale and Nanoscale Physics · Physics 2019-05-01 Nicholas Rivera , Thomas Christensen , Prineha Narang