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We describe a molecular dynamics framework for the direct calculation of the short-ranged structural forces underlying grain-boundary premelting and grain-coalescence in solidification. The method is applied in a comparative study of (i) a…

Materials Science · Physics 2015-05-14 Saryu Fensin , David Olmsted , Dorel Buta , Mark Asta , Alain Karma , J. J. Hoyt

Grain boundaries affect properties of polycrystalline materials. The influence of a boundary is largely determined by its energy. Grain boundary energy is often portrayed as a function of macroscopic boundary parameters representing grain…

Materials Science · Physics 2025-01-07 Adam Morawiec

We study the motion of a grain boundary separating two otherwise stationary domains of hexagonal symmetry. Starting from an order parameter equation appropriate for hexagonal patterns, a multiple scale analysis leads to an analytical…

Soft Condensed Matter · Physics 2009-11-07 Denis Boyer , Jorge Vinals

We consider the influence of electric field gradients on the phase behavior of nonpolar binary mixtures. Small fields give rise to smooth composition profiles, whereas large enough fields lead to a phase-separation transition. The critical…

Statistical Mechanics · Physics 2015-05-13 Sela Samin , Yoav Tsori

We report on scanning tunneling microscopy and spectroscopy of grain boundaries in highly oriented pyrolytic graphite. Grain boundaries showed a periodic structure and an enhanced charge density compared to the bare graphite surface. Two…

Materials Science · Physics 2013-05-29 J. Cervenka , C. F. J. Flipse

With a reduction in the average grain size in nanostructured films of elemental Nb, we observe a systematic crossover from metallic to weakly-insulating behavior. An analysis of the temperature dependence of the resistivity in the…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Sangita Bose , Rajarshi Banerjee , Arda Genc , Pratap Raychaudhuri , Hamish L. Fraser , Pushan Ayyub

Grain boundary-based mechanisms are known to control the plastic deformation and failure of nanocrystalline metals, with manipulation of the boundary structure a promising path for tuning this response. In this study, the role of…

Materials Science · Physics 2021-05-26 Jenna L. Wardini , Charlette M. Grigorian , Timothy J. Rupert

The quantitative phase-field approach has been adapted to model solidification in the presence of Metal Matrix Nanocomposites (MMNCs) in a single-component liquid. Nanoparticles of fixed size and shape are represented by additional fields.…

Materials Science · Physics 2014-06-11 Tamás Pusztai , László Rátkai , Attila Szállás , László Gránásy

A systematic investigation is presented of grain boundaries and grain boundary networks in two dimensional flexible membranes with crystalline order. An isolated grain boundary undergoes a buckling transition at a critical value of the…

Condensed Matter · Physics 2009-10-22 Carlo Carraro , David R. Nelson

Atomistic computer simulations are applied to investigate the atomic structure, thermal stability, and diffusion processes in Al-Si interphase boundaries as a prototype of metal-ceramic interfaces in composite materials. Some of the most…

Materials Science · Physics 2023-08-24 Ian Chesser , Raj Koju , Akshay Vellore , Yuri Mishin

The formation of helium cavities in coarse-grained materials produces hardening proportional to the number density and size of the cavities and due to the interaction of dislocations with intragranular helium defects. In nanostructured…

Materials Science · Physics 2023-03-28 W. S. Cunningham , Y. Zhang , S. L. Thomas , O. El-Atwani , Y. Wang , J. R. Trelewicz

We discuss how simulations of mechanical properties of materials require descriptions at many different length scales --- from the nanoscale where an atomic description is appropriate, through a mesoscale where dislocation based…

Materials Science · Physics 2007-05-23 J. Schiøtz , T. Vegge , F. D. Di Tolla , K. W. Jacobsen

Stress enhanced self-diffusion of Copper on the $\Sigma$3 twin grain boundary was examined with molecular dynamics simulations. The presence of uniaxial tensile stress results in a significant reduction in activation energy for…

Materials Science · Physics 2007-05-23 Kevin M. Crosby

We use phase field simulations to study composites made of two different ferroelastics (e.g., two types of martensite). The deformation of one material due to a phase transformation can elastically affect the other constituent and induce it…

Materials Science · Physics 2009-03-25 Mathieu Bouville , Rajeev Ahluwalia

We study a Ginzburg-Landau model of structural phase transition in two dimensions, in which a single order parameter is coupled to the tetragonal and dilational strains. Such elastic coupling terms in the free energy much affect the phase…

Materials Science · Physics 2009-11-13 Akihiko Minami , Akira Onuki

Amorphous interfacial complexions have been shown to restrict grain growth and improve damage tolerance in nanocrystalline alloys, with increased chemical complexity stabilizing the complexions themselves. Here, we investigate local…

Materials Science · Physics 2026-03-05 Esther C. Hessong , Zhengyu Zhang , Tianjiao Lei , Mingjie Xu , Toshihiro Aoki , Timothy J. Rupert

Engineering structure of grain boundaries (GBs) by solute segregation is a promising strategy to tailor the properties of polycrystalline materials. Theoretically it has been suggested that solute segregation can trigger phase transitions…

Materials Science · Physics 2025-01-28 Vivek Devulapalli , Enze Chen , Tobias Brink , Timofey Frolov , Christian H. Liebscher

Thermal stability of nanocrystalline multilayer thin film is of paramount importance as the applications often involve high temperature. Here we report on the layer instability phenomenon in binary polycrystalline thin film initiating from…

Materials Science · Physics 2017-10-10 Tamoghna Chakrabarti , Nisha Verma , Sukriti Manna

Exchange coupling between magnetic grains is essential for maintaining the stability of stored information in magnetic recording media. Using an atomistic spin model, we have investigated the coupling between neighbouring magnetic grains…

We discuss the modelling of grain boundary dynamics within an amplitude equations description, which is derived from classical density functional theory or the phase field crystal model. The relation between the conditions for periodicity…

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