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Related papers: Low-Depth Unitary Coupled Cluster Theory for Quant…

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We establish a general framework for developing approximation algorithms for a class of counting problems. Our framework is based on the cluster expansion of abstract polymer models formalism of Koteck\'y and Preiss. We apply our framework…

Quantum Physics · Physics 2024-01-18 Ryan L. Mann , Romy M. Minko

Simulating quantum circuits (QC) on high-performance computing (HPC) systems has become an essential method to benchmark algorithms and probe the potential of large-scale quantum computation despite the limitations of current quantum…

The chemistry community has long sought the exact relationship between the conventional and the unitary coupled cluster ansatz for a single-reference system, especially given the interest in performing quantum chemistry on quantum…

Quantum Physics · Physics 2022-01-31 James K. Freericks

The numerical unitarity approach has been important for obtaining reliable QCD predictions for the LHC. Here I discuss the extension of the approach beyond the leading quantum corrections for computing multi-loop amplitudes. The numerical…

High Energy Physics - Phenomenology · Physics 2017-03-27 Harald Ita

Electronic structure methods built around double-electron excitations have a rich history in quantum chemistry. However, it seems to be the case that such methods are only suitable in particular situations and are not naturally equipped to…

Chemical Physics · Physics 2024-07-12 Zachary W. Windom , Ajith Perera , Rodney J. Bartlett

We introduce a range-separation approximation to coupled cluster doubles (CCD) theory that successfully overcomes limitations of regular CCD when applied to the uniform electron gas. We combine the short-range ladder channel with the…

Chemical Physics · Physics 2014-05-07 James J. Shepherd , Thomas M. Henderson , Gustavo E. Scuseria

Accurate modeling of noise in realistic quantum processors is critical for constructing fault-tolerant quantum computers. While a full simulation of actual noisy quantum circuits provides information about correlated noise among all qubits…

Quantum Physics · Physics 2025-04-10 F. Setiawan , Alexander V. Gramolin , Elisha S. Matekole , Hari Krovi , Jacob M. Taylor

Unitary and non-unitary diagonal operators are fundamental building blocks in quantum algorithms with applications in the resolution of partial differential equations, Hamiltonian simulations, the loading of classical data on quantum…

Quantum Physics · Physics 2025-01-22 Julien Zylberman , Ugo Nzongani , Andrea Simonetto , Fabrice Debbasch

We propose to use wavefunction overlaps obtained from a quantum computer as inputs for the classical split-amplitude techniques, tailored and externally corrected coupled cluster, to achieve balanced treatment of static and dynamic…

Efficient and high-performance quantum error correction is essential for achieving fault-tolerant quantum computing. Low-depth random circuits offer a promising approach to identifying effective and practical encoding strategies. In this…

Quantum Physics · Physics 2026-03-02 Guoding Liu , Zhenyu Du , Zi-Wen Liu , Xiongfeng Ma

In this paper we discuss the utilization of Variational Quantum Solver (VQE) and recently introduced Generalized Unitary Coupled Cluster (GUCC) formalism for the diagonalization of downfolded/effective Hamiltonians in active spaces. In…

Quantum Physics · Physics 2020-11-05 Nicholas P. Bauman , Jaroslav Chládek , Libor Veis , Jiří Pittner , Karol Kowalski

We introduce a multicomponent unitary coupled cluster framework for quantum simulations of molecular systems that incorporate both electronic and nuclear quantum effects beyond the Born-Oppenheimer approximation. Using the…

The emerging field of quantum simulation of many-body systems is widely recognized as a very important application of quantum computing. A crucial step towards its realization in the context of many-electron systems requires a rigorous…

Atomic Physics · Physics 2021-08-23 Sumeet , V. S. Prasannaa , B. P. Das , B. K. Sahoo

One of the fundamental conditions for one-way quantum computation (1WQC) is the ability to make sequential measurements on isolated qubits that comprise the highly entangled resource for 1WQC, the cluster state. This has been a significant…

Quantum Physics · Physics 2009-11-13 Timothy P. Friesen , David L. Feder

In this work we present a coupled-cluster theory for the propagation of multireference electronic systems initiating at general quantum mechanical states. Our formalism is based on the infinitesimal analysis of modified cluster operators,…

Chemical Physics · Physics 2025-05-09 Martín A. Mosquera

Circuit depth reduction is of critical importance for quantum chemistry simulations on current and near term quantum computers. This issue is tackled by introducing a chemically aware strategy for the Unitary Coupled Cluster ansatz. The…

In order to explore the effects of high levels of electron correlation on the real-time coupled cluster formalism and algorithmic behavior, we introduce a time-dependent implementation of the CC3 singles, doubles and approximate triples…

Chemical Physics · Physics 2025-01-23 Zhe Wang , Håkon Emil Kristiansen , Thomas Bondo Pedersen , T. Daniel Crawford

An implementation of coupled-cluster (CC) theory to treat atoms and molecules in finite magnetic fields is presented. The main challenges stem from the magnetic-field dependence in the Hamiltonian, or, more precisely, the appearance of the…

Chemical Physics · Physics 2015-09-02 Stella Stopkowicz , Jürgen Gauss , Kai K. Lange , Erik I. Tellgren , Trygve Helgaker

Quantum computers promise to revolutionise electronic simulations by overcoming the exponential scaling of many-electron problems. While electronic wave functions can be represented using a product of fermionic unitary operators, shallow…

Quantum Physics · Physics 2022-07-04 Hugh G. A. Burton , Daniel Marti-Dafcik , David P. Tew , David J. Wales

Current quantum computing hardware is restricted by the availability of only few, noisy qubits which limits the investigation of larger, more complex molecules in quantum chemistry calculations on quantum computers in the near-term. In this…

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