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Reduced graphene oxide (rGO) is a bulk-processable quasi-amorphous 2D material with broad spectral coverage and fast electronic response. rGO sheets are suspended in a polymer matrix and sequentially photoreduced while measuring the…

Materials Science · Physics 2023-06-19 Alden N. Bradley , Spencer G. Thorp , Gina Mayonado , Edward Elliott , Matt W. Graham

Reducible oxides are widely used catalyst supports that can increase oxidation reaction rates by transferring their lattice oxygen at the metal-support interface. The interfacial oxidation process is typically described in terms of a…

Materials Science · Physics 2021-04-05 Joshua L. Vincent , Peter A. Crozier

Octa-penta graphene (OPG), a novel carbon allotrope characterized by its distinctive arrangement of pentagonal and octagonal rings, has garnered considerable attention due to its exceptional structure and functional properties. This study…

Materials Science · Physics 2025-03-07 Chenyi Zhou , Rubin Huo , Boyi Situ , Zihan Yan , Zhe Zhang , Yusong Tu

Graphene Oxide (GO) remains a perennial chemical enigma despite its utility in preparing graphene and its functionalization. Epoxides and tertiary alcohols are construed as primary functional groups, but the structural motifs, spectra, and…

Materials Science · Physics 2025-01-27 Musiri M Balakrishnarajan , Gaurav Jhaa , Pattath D Pancharatna

While graphene oxide (GO) is representative of a disordered phase of oxocarbons with lackluster electronic properties, the coexistence of ordered, stoichiometric solid-state carbon oxides with graphene brings renewed momentum to the…

Materials Science · Physics 2024-01-23 N. Hassani , A. Movafegh-Ghadirli , Z. Mahdavifar , F. M. Peeters , M. Neek-Amal

The formation of highly reactive oxygen species (ROS) on metal oxide surfaces have attracted considerable interest due to their diverse applications. In this work, we have performed densi-ty-functional theory calculations to investigate the…

Chemical Physics · Physics 2016-08-18 Zhenjun Song , Hu Xu

In this work, we demonstrate that edge-oxidation of graphene can enable larger enhancement in thermal conductivity (k) of graphene-nanoplatelet (GnP)/polyetherimide (PEI) composites relative to oxidation of the basal plane of graphene. Edge…

Nuclear magnetic resonance (NMR) has been widely used in the graphene oxide (GO) structure study. However, the detailed relationship between its spectroscopic features and the GO structural configuration has remained elusive. Based on first…

Materials Science · Physics 2015-03-13 Ning Lu , Ying Huang , Haibei Li , Zhenyu Li , Jinlong Yang

Since the discovery of graphene oxide (GO), the most accessible of the precursors of graphene, this material has been widely studied for applications in science and technology. In this work, we describe a procedure to obtain GO dispersions…

Hydration or interfacial water present in biomolecules and inorganic solids have been shown to exhibit a dynamical transition upon supercooling. However, an understanding of the extent of the underlying surface hydrophilicity as well as the…

Soft Condensed Matter · Physics 2020-08-26 Rajasekaran M , K. Ganapathy Ayappa

Graphene/AlGaN/GaN heterostructures are proposed to investigate the drag and two-stream instability effects. In this study, graphene grown by chemical vapor deposition was transferred from copper onto the top of the standard AlGaN/GaN…

Mesoscale and Nanoscale Physics · Physics 2026-01-27 A. Rehman , D. B. But , P. Sai , M. Dub , P. Prystawko , A. Krajewska , G. Cywinski , W. Knap , S. Rumyantsev

Quantum dot - graphene hybrid materials have raised significant interest due to the unique synergy of the optical properties of colloidal quantum dots (QDs) and the transport properties of graphene. This stimulated the development of…

Mesoscale and Nanoscale Physics · Physics 2026-01-21 Beatriz Martín-García , Anatolii Polovitsyn , Mirko Prato , Iwan Moreels

Transition-metal perovskite oxides constitute a series of functional material systems for electronics, catalysis and energy-conversion processes, in which oxygen migration and evolution play a key role. However, the stable metal-oxygen…

Materials Science · Physics 2021-11-02 Qian Wang , Youdi Gu , Wenxuan Zhu , Lei Han , Feng Pan , Cheng Song

Adsorption of molecular oxygen on B-, N-, Al-, Si-, P-, Cr- and Mn-doped graphene is theoretically studied using density functional theory in order to clarify if O2 can change the possibility of using doped graphene for gas sensors,…

Mesoscale and Nanoscale Physics · Physics 2015-03-14 Jiayu Dai , Jianmin Yuan

Fast slip flow was reported for water inside the interlayer gallery between graphene layers or carbon nanotubes. We report here that this flow rate enhancement (over two orders) breaks down with the presence of chemical functionalization…

Mesoscale and Nanoscale Physics · Physics 2014-06-05 Ning Wei , Zhiping Xu

Heterostructures of 2D materials offer a fertile ground to study ion transport and charge storage. Here we employ ab initio molecular dynamics to examine the proton-transfer/diffusion and redox behavior in a water layer confined in the…

Chemical Physics · Physics 2022-01-12 Lihua Xu , De-en Jiang

We utilized the momentum transfer(Q)-dependence of Quasi-Elastic Neutron Scattering (QENS) to reveal the dynamics of water and ethanol confined in Graphene Oxide (GO) powder or membranes at different temperatures and in different…

Soft Condensed Matter · Physics 2021-12-20 Gobin R. Acharya , Madhusudan Tyagi , Eugene Mamontov , Peter M. Hoffmann

The layers of graphene oxide (GO) are found to be good for permeation of water but not for helium (Science 2012 335 (6067): 442-444) suggesting that the GO layers are dynamic in the formation of permeation route depending on the environment…

Mesoscale and Nanoscale Physics · Physics 2015-10-01 Nallani Raghav , Sudip Chakraborty , Prabal K. Maiti

On-chip integration of two-dimensional (2D) materials with unique structures and distinctive properties endow integrated devices with new functionalities and improved performance. With a high flexibility in modifying its properties and a…

Optics · Physics 2024-06-06 David J. Moss

Electronic properties of graphene oxides enriched by the strong chemical bondings are investigated using first-principle calculations. They are very sensitive to the changes in the number of graphene layer, stacking configuration, and…

Materials Science · Physics 2015-07-28 Ngoc Thanh Thuy Tran , Shih-Yang Lin , Yu-Tsung Lin , Ming-Fa Lin