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A strong coupling between electric polarization and elastic deformation in solids is an important factor in creating useful electromechanical nanodevices. Such coupling is typically allowed in insulating materials with inversion symmetry…

Materials Science · Physics 2024-10-30 Hidefumi Takahashi , Yusuke Kurosaka , Kenta Kimura , Akitoshi Nakano , Shintaro Ishiwata

We study from first-principles calculations the ferroelectric structural phase transition of Pb$_5$Ge$_3$O$_{11}$ crystal. The calculations of phonons and Born effective charges of the paraelectric phase allow us to identify a polar…

Materials Science · Physics 2024-01-18 Mauro Fava , William Lafargue-Dit-Hauret , Aldo H. Romero , Eric Bousquet

The compounds exhibit piezoelectricity, which demands to break inversion symmetry, and then to be a semiconductor. For $\mathrm{Ga_2O_3}$, the orthorhombic case ($\epsilon$-$\mathrm{Ga_2O_3}$) of common five phases breaks inversion…

Materials Science · Physics 2020-01-29 San-Dong Guo , Hui-Min Du

In this study, we succeeded in synthesizing new antiperovskite phosphides $M$Pd$_3$P ($M$ = Ca, Sr, Ba) and discovered the appearance of a superconducting phase (0.17 $\leq$ $x$ $\leq$ 0.55) in a solid solution (Ca$_{1-x}$Sr$_x$)Pd$_3$P.…

Piezoresistivity is the most commonly used sensing principle in cement-based smart composites for strain-monitoring applications. Nonetheless, the need for external electric power to conduct electrical resistivity measurements restricts the…

Introducing symmetry breaking in materials enables the emergence of functionalities. This can be microscopically and macroscopically driven by applying external stimuli such as mechanical stress, electric field, temperature, and chemical…

Lead-free ceramics (K0.44+xNa0.52Li0.04)(Nb0.86Ta0.10Sb0.04)O3+x/2 (x=-0,06) were prepared by conventional solid state sintering. The results indicate a correlation between crystalline symmetry and electrical properties. Higher…

Materials Science · Physics 2008-08-04 F. Rubio-Marcos , P. Marchet , T. Merle-Mejean , J. F. Fernandez

In this work, we address the issue of peaking of piezoelectric response at a particular composition in the morphotropic phase boundary (MPB) region of (Pb0.940Sr0.06)(ZrxTi1-x)O3 (PSZT) piezoelectric ceramics. We present results of…

In recent years, the investigation of low-dimensional ferroelectrics has attracted great attention for their promising applications in nano devices. Piezoelectricity is one of the most core properties of ferroelectric materials, which plays…

Materials Science · Physics 2024-12-06 Ning Ding , Shuai Dong

Piezoresistance, the change of a material's electrical resistance ($R$) in response to an applied mechanical stress ($\sigma$), is the driving principle of electromechanical devices such as strain gauges, accelerometers, and cantilever…

Strongly Correlated Electrons · Physics 2022-07-20 S. Ghosh , C. Lane , F. Ronning , E. D. Bauer , J. D. Thompson , J. -X. Zhu , P. F. S. Rosa , S. M. Thomas

A technique for obtaining efficient bulk second order susceptibility in non centro-symmetric Photonic Crystals (PC) made from centro-symmetric materials is discussed. The effect is based on the electric quadrupole effect, strong…

Optics · Physics 2009-11-07 A. Feigel , Z. Kotler , B. Sfez

Charge density waves (CDWs) with multi-component order parameters can break unexpected symmetries through the interplay of nearly degenerate instabilities. In the widely investigated material 1T-TiSe$_2$, a central question is whether the…

The stability of a high-symmetry $P4mm$ polar phase in seventeen short-period ferroelectric perovskite superlattices with polar discontinuity is studied from first principles within the density-functional theory. It is shown that in most…

Materials Science · Physics 2021-02-16 Alexander I. Lebedev

At first sight piezoresponse force microscopy (PFM) seems an ideal technique for the determination of piezoelectric coefficients (PCs), thus making use of its ultra-high vertical resolution (<0.1 pm/V). Christman et al. \cite{Chr98} first…

Materials Science · Physics 2009-11-13 T. Jungk , A. Hoffmann. , E. Soergel

In this review we address some of the experimental challenges found in the x-ray diffraction characterization of the low-symmetry phases recently discovered in the PZT, PZN-PT and PMN-PT piezoelectric systems around their morphotropic phase…

Materials Science · Physics 2007-05-23 B. Noheda , D. E. Cox , G. Shirane

The septuple-atomic-layer $\mathrm{VSi_2P_4}$ with the same structure of experimentally synthesized $\mathrm{MoSi_2N_4}$ is predicted to be a spin-gapless semiconductor (SGS). In this work, the biaxial strain is applied to tune electronic…

Materials Science · Physics 2021-02-03 San-Dong Guo , Wen-Qi Mu , Yu-Tong Zhu , Xing-Qiu Chen

We performed factor-group analysis of all phonons in possible monoclinic C2/c and C2 structures of BiMnO3 and compared it with our experimental infrared and Raman spectra. We conclude that the crystal structure is centrosymmetric C2/c in…

Materials Science · Physics 2012-10-10 V. Goian , S. Kamba , M. Savinov , D. Nuzhnyy , F. Borodavka , P. Vanek , A. A. Belik

This paper presents multiple-modes Scanning Probe Microscopy (SPM) studies on characterize resistance switching (RS), polarization rotation (PO) and surface potential changes in copper doped ZnO (ZnO:Cu) thin films. The bipolar RS behavior…

Materials Science · Physics 2018-02-14 Juanxiu Xiao , Tun Seng Herng , Jun Ding , Kaiyang Zeng

The structure of a single antiparallel ferroelectric domain wall in LiNbO3 is quantitatively mapped by piezoelectric force microscopy (PFM) with calibrated probe geometry. The PFM measurements are performed for 49 probes with the radius…

Strong coupling between electrical and mechanical phenomena and the presence of switchable polarization have enabled applications of ferroelectric materials for nonvolatile memories (FeRAM), data storage, and ferroelectric lithography.…