Related papers: A thermodynamical description of third grade fluid…
We consider viscous, heat conducting mixtures of molecularly miscible chemical species forming a fluid in which the constituents can undergo chemical reactions. Assuming a common temperature for all components, we derive a closed system of…
Internal energy, enthalpy and entropy are the key quantities to study thermodynamic properties of the moist atmosphere, because they correspond to the First (internal energy and enthalpy) and Second (entropy) Laws of thermodynamics. The aim…
The Cahn-Hilliard and Ginzburg-Landau (Allen-Cahn) equations are derived from the second law. The intuitive approach by separation of full divergences is supported by a more rigorous method, based on Liu procedure and a constitutive entropy…
The continuum equations of fluid mechanics are rederived with the intention of keeping certain mechanical and thermodynamic concepts separate. A new "mechanical" mass density is created to be used in computing inertial quantities, whereas…
Single component nonrelativistic dissipative fluids are treated independently of reference frames and flow-frames. First the basic fields and their balances, then the related thermodynamic relations and the entropy production are calculated…
The paper studies constitutive modelling of Korteweg fluids. Thermodynamic consistency, i.e. compatibility with entropy balance law, is achieved using Liu's method of multipliers. Appropriate constitutive assumptions facilitated inclusion…
Surface-active agents (surfactants) release potential energy as they migrate from one of two adjacent fluids onto their fluid-fluid interface, a process that profoundly impacts the system's energy and entropy householding. The continuum…
The nonisothermal single-component theory of droplet nucleation (Alekseechkin, 2014) is extended to binary case; the droplet volume V, composition x, and temperature T are the variables of the theory. An approach based on macroscopic…
In the first part of the paper we provide a new classification of incompressible fluids characterized by a continuous monotone relation between the velocity gradient and the Cauchy stress. The considered class includes Euler fluids,…
The purpose of this work is to analyze the mathematical model governing motion of $n$-component, heat conducting reactive mixture of compressible gases. We prove sequential stability of weak variational entropy solutions when the state…
The aim of this paper is to develop a general constitutive scheme within continuum thermodynamics to describe the behavior of heat flow in deformable media. Starting from a classical thermodynamic approach, the rate-type constitutive…
We present a classical approach of a mixture of compressible fluids when each constituent has its own temperature. The introduction of an average temperature together with the entropy principle dictates the classical Fick law for diffusion…
The approach to a substantiation of thermodynamics is offered. A conservative system of interacting elements, which is not in equilibrium, is used as a model. This system is then split into small subsystems that are accepted as being in…
The role of gradient dependent constitutive spaces is investigated on the example of Extended Thermodynamics of rigid heat conductors. Different levels of nonlocality are developed and the different versions of extended thermodynamics are…
Thermodynamic relations are derived from first principles of mechanics for non-equilibrium processes. Since the key role herein is played by the law of increase of entropy, the latter is analyzed at first. It is shown that its derivation…
We determine the energy-momentum tensor of non-perfect fluids in thermodynamic equilibrium. To this end, we derive the constitutive equations for energy density, isotropic and anisotropic pressure as well as for heat-flux from the…
We analyze some aspects of the third law of thermodynamics. We first review both the entropic version (N) and the unattainability version (U) and the relation occurring between them. Then, we heuristically interpret (N) as a continuity…
We introduce a simple model of the time evolution of a binary mixture of compressible fluids including the thermal effects. Despite its apparent simplicity, the model is thermodynamically consistent admitting an entropy balance equation. We…
A microscopic definition of the thermodynamic entropy in an isolated quantum system must satisfy (i) additivity, (ii) extensivity and (iii) the second law of thermodynamics. We show that the diagonal entropy, which is the Shannon entropy in…
The motion of water is governed by the Navier-Stokes equations, which are complemented by the continuity equation to ensure local mass conservation. In this work, we construct the relativistic generalization of these equations through a…