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In this paper, we apply the first-principle theory to explore how the electronic structures of armchair graphene nanoribbons (AGNRs) are affected by chemical modifications. The edge addends include H, F, N, NH$_{2}$, and NO$_{2}$. Our…

Materials Science · Physics 2007-11-13 Hao Ren , Qunxiang Li , Haibin Su , Q. W. Shi , Jie Chen , Jinlong Yang

We present a theoretical study on narrow armchair graphene nanoribbons (AGNRs) with hydroxyl functionalized edges. Although this kind of passivation strongly affects the structure of the ribbon, a high degree of edge functionalization…

Mesoscale and Nanoscale Physics · Physics 2015-05-28 Nils Rosenkranz , Christian Till , Christian Thomsen , Janina Maultzsch

We report on nano-infrared (IR) imaging studies of confined plasmon modes inside patterned graphene nanoribbons (GNRs) fabricated with high-quality chemical-vapor-deposited (CVD) graphene on Al2O3 substrates. The confined geometry of these…

Mesoscale and Nanoscale Physics · Physics 2015-12-23 Z. Fei , M. D. Goldflam , J. -S. Wu , S. Dai , M. Wagner , A. S. McLeod , M. K. Liu , K. W. Post , S. Zhu , G. C. A. M. Janssen , M. M. Fogler , D. N. Basov

We report combined first-principle and tight-binding (TB) calculations to simulate the effects of chemical edge modifications on structural and electronic properties. The C-C bond lengths and bond angles near the GNR edge have considerable…

Materials Science · Physics 2007-05-23 Z. F. Wang , Qunxiang Li. Huaixiu Zheng , Hao Ren , Haibin Su , Q. W. Shi , Jie Chen

We conduct a theoretical examination of the electronic and magnetic characteristics of end-modified 7-atom wide armchair graphene nanoribbons (AGNRs). Our investigation is performed within the framework of a single-band Hubbard model,…

Mesoscale and Nanoscale Physics · Physics 2025-03-21 Antoine Honet , Luc Henrard , Vincent Meunier

Graphene-based nanostructures exhibit a vast range of exciting electronic properties that are absent in extended graphene. For example, quantum confinement in carbon nanotubes and armchair graphene nanoribbons (AGNRs) leads to the opening…

We analyze the collective mode spectrum of graphene nanoribbons within the random phase approximation. In the undoped case, only metallic armchair nanoribbons support a propagating plasmon mode. Landau damping of this mode is shown to be…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 L. Brey , H. A. Fertig

We investigate higher-order plasmons in graphene nanoribbons, and present how electronic edge states and wavefunction fine structure influence the graphene plasmons. Based on nearest-neighbor tight-binding calculations, we find that a…

Mesoscale and Nanoscale Physics · Physics 2019-01-09 Kåre Obel Wedel , N. Asger Mortensen , Kristian S. Thygesen , Martijn Wubs

Using density functional theory calculations, we have studied the edge-functionalization of armchair graphene nanoribbons (AGNRs) with pentagonal-hexagonal edge structures. While the AGNRs with pentagonal-hexagonal edge structures (labeled…

Mesoscale and Nanoscale Physics · Physics 2020-02-05 Junga Ryou , Jinwoo Park , Gunn Kim , Suklyun Hong

We present a first-principles calculation of the optical properties of armchair-edged graphene nanoribbons (AGNRs) with many-electron effects included. The reduced dimensionality of the AGNRs gives rise to an enhanced electron-hole binding…

Mesoscale and Nanoscale Physics · Physics 2007-10-10 Li Yang , Marvin L. Cohen , Steven G. Louie

In this Letter, we put forward a resolution to the prolonged ambiguity in energy band gaps between theory and experiments of fabricated graphene nanoribbons (GNRs). Band structure calculations using density functional theory are performed…

Mesoscale and Nanoscale Physics · Physics 2016-10-11 Deepika , T. J. Dhilip Kumar , Alok Shukla , Rakesh Kumar

We theoretically investigate the electron transport in armchair and zigzag graphene nanoribbons (GNRs) chemically functionalized with p-polyphenyl and polyacene groups of increasing length. Our nearest-neighbor tight-binding calculations…

Mesoscale and Nanoscale Physics · Physics 2020-10-01 Kristiāns Čerņevičs , Michele Pizzochero , Oleg V. Yazyev

The unusual electronic and optical properties of armchair and zigzag graphene nanoribbons (GNRs) subject to in-plane transverse electric and perpendicular magnetic fields have been systematically investigated. Our calculations were carried…

Mesoscale and Nanoscale Physics · Physics 2021-03-29 Thi-Nga Do , Po-Hsin Shih , Godfrey Gumbs , Danhong Huang

We present symmetry properties of the lattice vibrations of graphene nanoribbons with pure armchair (AGNR) and zigzag edges (ZGNR). In non-symmorphic nanoribbons the phonon modes at the edge of the Brillouin zone are twofold degenerate,…

Mesoscale and Nanoscale Physics · Physics 2015-05-18 Roland Gillen , Marcel Mohr , Janina Maultzsch

We present the analytical solution of the wavefunction and energy dispersion of armchair graphene nanoribbons (GNRs) based on the tight-binding approximation. By imposing hard-wall boundary condition, we find that the wavevector in the…

Mesoscale and Nanoscale Physics · Physics 2015-06-25 Huaixiu Zheng , Zhengfei Wang , Tao Luo , Qinwei Shi , Jie Chen

It is now possible to produce graphene nanoribbons (GNRs) with atomically defined widths. GNRs offer many opportunities for electronic devices and composites, if it is possible to establish the link between edge structure and…

Serving as a new two-dimensional plasmonic material, graphene has stimulated an intensive study of its optical properties which benefit from the unique electronic band structure of the underlying honeycomb lattice of carbon atoms. In…

Mesoscale and Nanoscale Physics · Physics 2015-03-18 Weihua Wang , Thomas Christensen , Antti-Pekka Jauho , Kristian S. Thygesen , Martijn Wubs , N. Asger Mortensen

We performed an investigation concerning bipolaron dynamics in armchair graphene nanoribbons (AGNRs) under the influence of different electric field and electron-phonon coupling regimes. By studying the response to the electric excitation,…

Based on atomistic simulations, the nonlinear elastic properties of monolayer graphene nanoribbons under quasistatic uniaxial tension are predicted, emphasizing the effect of edge structures (armchair and zigzag, without and with hydrogen…

Mesoscale and Nanoscale Physics · Physics 2010-07-21 Qiang Lu , Rui Huang

A simple model which combines tight-binding (TB) approximation with parameters derived from first principle calculations is developed for studying the influence of edge passivation and uniaxial strain on electron effective mass of armchair…

Mesoscale and Nanoscale Physics · Physics 2014-06-06 Benjamin O. Tayo
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