Related papers: The First Detection of CH$_2$CN in a Protoplanetar…
Atacama Large Millimeter/submillimeter Array observations suggest that the disc of HD 163296 is being actively shaped by embedded, yet unseen protoplanets, as indicated by numerous gas and dust substructures consistent with planet-disc…
Vinyl cyanide (C$_2$H$_3$CN) is theorized to form in Titan's atmosphere via high-altitude photochemistry and is of interest regarding the astrobiology of cold planetary surfaces due to its predicted ability to form cell membrane-like…
Methanol (CH$_{3}$OH) ice is abundant in space and is a key feedstock for seeding chemical complexity in interstellar and circumstellar environments. Despite its ubiquity, gas-phase methanol has only been detected in one disk around a…
Using the recently-commissioned Submillimeter Array (SMA), we have detected several complex organic molecules, including (CH3)2O, C2H5OH, C2H5CN, and tentatively CH2CDCN, toward the protostellar hot cores of IRAS 16293-2422 at…
Nitrogen chemistry in protoplanetary disks and the freeze-out on dust particles is key to understand the formation of nitrogen bearing species in early solar system analogs. So far, ammonia has not been detected beyond the snowline in…
We present the discovery in TMC-1 of allenyl acetylene, H2CCCHCCH, through the observation of nineteen lines with a signal-to-noise ratio ~4-15. For this species, we derived a rotational temperature of 7 +/- 1 K and a column density of (1.2…
While the number of detected molecules, particularly complex organic molecules, in the solid-state in astrophysical environments is still rather limited, laboratory experiments and astrochemical models predict many potential candidates.…
Observations are presented of emission lines from organic molecules at frequencies 32 - 50 GHz in the vicinity of Chamaeleon MMS1. This chemically-rich dense cloud core habours an extremely young, very low-luminosity protostellar object and…
We present new spectral line observations of the CH3CN molecule in the accretion disk around the massive protostar IRAS 20126+4104 with the Submillimeter Array that for the first time measure the disk density, temperature, and rotational…
We report the first detection of DCO+ in a circumstellar disk. The DCO+ J=5-4 line at 360.169 GHz is observed with the 15m James Clerk Maxwell Telescope in the disk around the pre-main sequence star TW Hya. Together with measurements of the…
The results of single-dish observations of low- and high-J transitions of selected molecules from protoplanetary disks around two TTauri stars (LkCa15 and TWHya) and two HerbigAe stars (HD163296 and MWC480) are reported. Simple molecules…
Mid-infrared spectroscopy of protoplanetary disks provides a chemical inventory of gas within a few au, where planets are readily detected around older stars. With the JWST Disk Infrared Spectral Chemistry Survey (JDISCS), we explore…
The relative abundances of singly-deuterated methanol isotopologues, [CH$_{2}$DOH]/[CH$_{3}$OD], in star-forming regions deviate from the statistically expected ratio of 3. In Orion KL, the nearest high-mass star-forming region to Earth,…
Context. Characterizing the evolution of protoplanetary disks is necessary to improve our understanding of planet formation. Constraints on both dust and gas are needed to determine the dominant disk dissipation mechanisms. Aims. We aim to…
Recent observations show that the CO gas abundance, relative to H$_2$, in many 1-10 Myr old protoplanetary disks may be heavily depleted, by a factor of 10-100 compared to the canonical interstellar medium value of 10$^{-4}$. When and how…
Star formation often occurs within or nearby stellar clusters. Irradiation by nearby massive stars can photoevaporate protoplanetary disks around young stars (so-called proplyds) which raises questions regarding the ability of planet…
The dominant form of oxygen in cold molecular clouds is gas-phase carbon monoxide (CO) and ice-phase water (H$_2$O). Yet, in planet-forming disks around young stars, gas-phase CO and H$_2$O are less abundant relative to their ISM values,…
Among all closed-shell species observed in molecular clouds, molecules with C$_{3v}$ symmetry play a crucial role, as their rotational spectroscopy allows them to behave as a gas thermometer. In the interstellar medium, methyl cyanide…
We report observations of resolved C2H emission rings within the gas-rich protoplanetary disks of TW Hya and DM Tau using the Atacama Large Millimeter Array (ALMA). In each case the emission ring is found to arise at the edge of the…
High-dispersion (l/dl ~ 25,000) infrared spectra of Comet C/2004 Q2 (Machholz) were acquired on Nov. 28-29, 2004, and Jan. 19, 2005 (UT dates) with NIRSPEC at the Keck-2 telescope on Mauna Kea. We detected H2O, CH4, C2H2, C2H6, CO, H2CO,…