Related papers: The First Detection of CH$_2$CN in a Protoplanetar…
Cometary studies suggest that the organic composition of the early Solar Nebula was rich in complex nitrile species such a CH$_3$CN. Recent ALMA detections in protoplanetary disks suggest that these species may be common during planet and…
Bright ring-like structure emission of the CN molecule has been observed in protoplanetary disks. We investigate whether such structures are due to the morphology of the disk itself or if they are instead an intrinsic feature of CN…
Recent measurements of carbon isotope ratios in both protoplanetary disks and exoplanet atmospheres have suggested a possible transfer of significant carbon isotope fractionation from disks to planets. For a clearer understanding of the…
Molecular lines observed towards protoplanetary disks carry information about physical and chemical processes associated with planet formation. We present ALMA Band 6 observations of C2H, HCN, and C18O in a sample of 14 disks spanning a…
We report the first detection in the interstellar medium of $N$-cyanomethanimine (H$_2$CNCN), the stable dimer of HCN of highest energy, and the most complex organic molecule identified in space containing the prebiotically relevant NCN…
Searches for the prebiotically-relevant cyanamide (NH$_2$CN) towards solar-type protostars have not been reported in the literature. We here present the first detection of this species in the warm gas surrounding two solar-type protostars,…
We present the first spatially resolved map of methanimine CH2NH in the prestellar core L1544 using the IRAM 30m telescope. The 2$_{0,2}$-1$_{0,1}$ line at 127 GHz was mapped with 20" resolution ($\sim$2800 au), revealing extended CH2NH…
We report the first detection in interstellar space of the 3-cyano propargyl radical (CH2C3N). This species was observed in the cold dark cloud TMC-1 using the Yebes 40m telescope. A total of seven rotational transitions for both ortho- and…
We have investigated molecular distributions in protoplanetary disks, adopting a disk model with a temperature gradient in the vertical direction. The model produces sufficiently high abundances of gaseous CO and HCO+ to account for line…
Studying molecular species in protoplanetary disks is very useful to characterize the properties of these objects, which are the site of planet formation. We attempt to constrain the chemistry of S-bearing molecules in the cold parts of…
The distributions and abundances of molecules in protoplanetary disks are powerful tracers of the physical and chemical disk structures. The abundance ratios of HCN and its isomer HNC are known to be sensitive to gas temperature. Their line…
The chemistry of proto-planetary disks is thought to be dominated by two major processes: photodissociation near the disk surface, and depletion on dust grains in the disk mid-plane, resulting in a layered structure with molecules located…
The organic content of protoplanetary disks sets the initial compositions of planets and comets, thereby influencing subsequent chemistry that is possible in nascent planetary systems. We present observations of the complex nitrile-bearing…
We report the first detection in space of the single deuterated isotopologue of methylcyanoacetylene, CH$_2$DC$_3$N. A total of fifteen rotational transitions, with $J$ = 8-12 and $K_a$ = 0 and 1, were identified for this species in TMC-1…
While the nitrile group is by far the most prevalent one among interstellar molecules, the existence of interstellar dinitriles (molecules containing two -CN groups) has recently been proven. Here we report the discovery of two new…
We report the first detection in interstellar medium of the 1-cyano propargyl radical, HC$_3$HCN. This species is an isomer of the 3-cyano propargyl radical (CH$_2$C$_3$N), which was recently discovered in TMC-1. The 1-cyano propargyl…
Using the QUIJOTE line survey in the 32.0-50.4 GHz range, we report the discovery of the molecule CH2CCHC4H towards the prestellar cold core TMC-1 in the Taurus region. We also present a rigorous detection of CH2CCHC3N, along with its…
We seek to establish the presence and properties of gas in the circumstellar disk orbiting T Cha, a nearby (d~110 pc), relatively evolved (age ~5-7 Myr) yet actively accreting 1.5 Msun T Tauri star. We used the APEX 12 m radiotelescope to…
The recent detection of gas-phase methanol (CH$_3$OH) lines in the disc of TW Hya by Walsh et al. provided the first observational constraints on the complex O-bearing organic content in protoplanetary discs. The emission has a ring-like…
We present the first detection of 13CCH in a protoplanetary disk (TW Hya). Using observations of C2H we measure CCH/13CCH = 65 +/- 20 in gas with a CO isotopic ratio of 12CO/13CO = 21 +/- 5 (Yoshida et al. 2022a). The TW Hya disk exhibits a…