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A coupling-limited approach for the Ullmann reaction-like on-surface synthesis of a two-dimensional covalent organic network starting from a halogenated metallo-porphyrin is demonstrated. Copper-octabromo-tetraphenylporphyrin molecules can…

Chemical Physics · Physics 2015-02-23 Lars Smykalla , Pavel Shukrynau , Marcus Korb , Heinrich Lang , Michael Hietschold

Carbonyl sulfide (OCS) is widely observed in the gas phase towards star-forming regions and was the first of the only two sulfur-bearing species detected in interstellar ices so far. However, the chemical network governing its formation is…

Astrophysics of Galaxies · Physics 2024-10-02 Julia C. Santos , Harold Linnartz , Ko-Ju Chuang

We address a molecular dissociation mechanism that is known to occur when a H 2 molecule approaches a catalyst with its molecular axis parallel to the surface. It is found that molecular dissociation is a form of quantum dynamical phase…

Chemical Physics · Physics 2016-05-31 Andres Ruderman , Axel Dente , Elizabeth Santos , Horacio Miguel Pastawski

Rigid particles in a Stokesian fluid can physically not overlap, as a thin layer of fluid always separates a particle pair, exerting increasingly strong repulsive forces on the bodies for decreasing separations. Numerically, resolving these…

Fluid Dynamics · Physics 2024-06-11 Anna Broms , Anna-Karin Tornberg

The last decade has witnessed a swiftly increasing interest in the design and production of novel multivalent molecules as powerful alternatives for conventional antibodies in the fight against cancer and infectious diseases. However, while…

Soft Condensed Matter · Physics 2019-08-23 Suman Saurabh , Francesco Piazza

A major challenge faced in the design of large-scale cyber-physical systems, such as power systems, the Internet of Things or intelligent transportation systems, is that traditional distributed optimal control methods do not scale…

Optimization and Control · Mathematics 2017-01-23 Yuh-Shyang Wang , Nikolai Matni , John C. Doyle

Off-lattice agent-based models (or cell-based models) of multicellular systems are increasingly used to create in-silico models of in-vitro and in-vivo experimental setups of cells and tissues, such as cancer spheroids, neural crest cell…

Numerical Analysis · Mathematics 2026-02-23 Justin Steinman , Andreas Buttenschön

The adsorption and dissociation of O$_{2}$ molecules at the Be(0001) surface is studied by using density-functional theory within the generalized gradient approximation and a supercell approach. The physi- and chemisorbed molecular…

Materials Science · Physics 2013-05-29 Ping Zhang , Bo Sun , Yu Yang

Solid-On-Solid (SOS) computer simulations are employed to investigate the sublimation of surfaces. We distinguish three sublimation regimes: layer-by-layer sublimation, free step flow and hindered step flow. The sublimation regime is…

Condensed Matter · Physics 2009-10-30 Stefan Schinzer , Wolfgang Kinzel

Supported Lipid Bilayers (SLBs) are model membranes formed at solid substrate surfaces. This architecture renders the membrane experimentally accessible to surface sensitive techniques used to study their properties, including Atomic Force…

Biological Physics · Physics 2019-11-19 James A. Goodchild , Danielle L. Walsh , Simon D. Connell

We study an SOS model whose dynamics is inspired by recent studies of the synchronization transition in coupled map lattices (CML). The synchronization of CML is thus related with a depinning of interface from a binding wall. Critical…

Statistical Mechanics · Physics 2009-11-07 Adam Lipowski , Michel Droz

Programmable metasurfaces have recently attracted considerable interest for their versatile applications in areas such as beam steering, holography, and wireless communications, utilizing either phase or amplitude modulation. Despite this,…

Optics · Physics 2024-10-24 Parsa Farzin , Kasra Rouhi , Seyed Ehsan Hosseininejad

Many tasks in geometry processing are modeled as variational problems solved numerically using the finite element method. For solid shapes, this requires a volumetric discretization, such as a boundary conforming tetrahedral mesh.…

Graphics · Computer Science 2018-07-04 Silvia Sellán , Herng Yi Cheng , Yuming Ma , Mitchell Dembowski , Alec Jacobson

Aliphatic hydrocarbons, such as normal alkanes, constitute a naturally abundant source of carbon atoms. Of special interest is the formation of cyclic and aromatic products from aliphatic reactants. Combining scanning tunneling microscopy…

Inspired by the recent developments in computer vision, low-rank and structured sparse matrix decomposition can be potentially be used for extract moving objects in satellite videos. This set of approaches seeks for rank minimization on the…

Computer Vision and Pattern Recognition · Computer Science 2023-07-19 Junpeng Zhang , Xiuping Jia , Jiankun Hu , Jocelyn Chanussot

Solid-state Spatial Light Modulators (SLMs) are fundamentally limited in their ability to achieve high spatial complexity and high temporal bandwidth simultaneously. High-speed, low-energy modulation requires sub-wavelength active mode…

Optics · Physics 2026-05-15 Virat Tara , Anna Wirth-Singh , Johannes E. Fröch , Arka Majumdar

Advances in understanding chemical and physical driving forces in self-assembly allow the fabrication of unique nanoarchitectures with subwavelength building blocks as the basis for plasmonic and metamaterial devices. Chemical crosslinking…

On-surface metal-organic coordination provides a promising way for synthesizing different two-dimensional lattice structures that have been predicted to possess exotic electronic properties. Using scanning tunneling microscopy (STM) and…

Materials Science · Physics 2019-10-04 Linghao Yan , Ilona Pohjavirta , Benjamin Alldritt , Peter Liljeroth

The barriers standing against the formation of superheavy elements and their consecutive $\alpha$ decay have been determined in the quasimolecular shape path within a Generalized Liquid Drop Model including the proximity effects between…

Nuclear Theory · Physics 2015-06-26 G. Royer , K. Zbiri , C. Bonilla

Atomic layer deposition (ALD) is a key technique for the continued scaling of semiconductor devices, which increasingly relies on reproducible and scalable processes for interface manipulation of 3D structured surfaces on the atomic scale.…