Related papers: Molecules with ALMA at Planet-forming Scales (MAPS…
Deuterium fractionation provides a window to the thermal history of volatiles in the solar system and protoplanetary disks. While evidence of active molecular deuteration has been observed towards a handful of disks, it remains unclear…
The distributions of deuterated molecules in protoplanetary disks are expected to depend on the molecular formation pathways. We use observations of spatially resolved DCN emission from the disk around TW Hya, acquired during ALMA Science…
Observations of deuterium fractionation in the solar system, and in interstellar and circumstellar material, are commonly used to constrain the formation environment of volatiles. Toward protoplanetary disks, this approach has been limited…
The deuterium enrichment of molecules is sensitive to their formation environment. Constraining patterns of deuterium chemistry in protoplanetary disks is therefore useful for probing how material is inherited or reprocessed throughout the…
We use spectra and maps of the $J=1-0$ and $J=2-1$ DCO$^{+}$, DCN, DNC, $\rm N_2D^+$ lines and $1_{11}-1_{01}$ ortho- and para-NH$_{2}$D lines, obtained with the IRAM-30m telescope, as well as observations of their hydrogenated…
The chemical evolution in high-mass star-forming regions is still poorly constrained. Studying the evolution of deuterated molecules allows to differentiate between subsequent stages of high-mass star formation regions due to the strong…
Molecular D/H ratios are frequently used to probe the chemical past of Solar System volatiles. Yet it is unclear which parts of the Solar Nebula hosted an active deuterium fractionation chemistry. To address this question, we present…
Deuterium was primarily created during the Big Bang Nucleosynthesis (BBN). This fact, alongside its fractionation reactions resulting in enhanced abundances of deuterated molecules, means that these abundances can be used to better…
Observations of deuterated species are useful in probing the temperature, ionization level, evolutionary stage, chemistry, and thermal history of astrophysical environments. The analysis of data from ALMA and other new telescopes requires…
We present the results of our studies of deuterated molecules (DCN, DNC, DCO$^+$, N$_2$D$^+$ and NH$_2$D) in regions of high-mass star formation, which include a survey of such regions with the 20-m Onsala radio telescope and mapping of…
We present new models of the deuterium chemistry in protoplanetary disks, including, for the first time, multiply deuterated species. We use these models to explore whether observations in combination with models can give us clues as to…
The formation pathways of deuterated species trace different regions of protoplanetary disks and may shed light into their physical structure. We aim to constrain the radial extent of main deuterated species; we are particularly interested…
Deuteration is a powerful tracer of the history of the cold prestellar phase in star forming regions. Apart from methanol, little is known about deuterium fractionation of complex organic molecules in the interstellar medium, especially in…
Deuteration is sensitive to environmental conditions in star-forming regions. To investigate NH$_2$D chemistry, we compared the spatial distribution of ortho-NH$_2$D $1_{11}^s-1_{01}^a$, NH$_3$(1,1) and NH$_3$(2,2) in 12 late-stage massive…
UV photochemistry in the surface layers of protoplanetary disks dramatically alters their composition relative to previous stages of star formation. The abundance ratio CN/HCN has long been proposed to trace the UV field in various…
We investigate deuterium chemistry coupled with the nuclear spin-state chemistry of H$_2$ and H$_3^+$ in protoplanetary disks. Multiple paths of deuterium fractionation are found; exchange reactions with D atoms, such as HCO$^+$ + D, are…
The Central Molecular Zone (CMZ) contains most of the mass of our Galaxy but its star formation rate is one order of magnitude lower than in the Galactic disc. This is likely related to the fact that the bulk of the gas in the CMZ is in a…
We have investigated the two-dimensional (R,Z) distribution of deuterated molecular species in circumstellar disks around young stellar objects. The abundance ratios between singly deuterated and normal molecules (``D/H ratios'') in disks…
We study deuterium fractionation in two massive starless/early-stage cores C1-N and C1-S in Infrared Dark Cloud (IRDC) G028.37+00.07, first identified by Tan et al. (2013) with ALMA. Line emission from multiple transitions of $\rm N_2H^+$…
The deuterium fractionation of water can serve as a tracer for the chemical and physical evolution of water during star formation and can constrain the origin of water in Solar System bodies. We determine the HDO/H$_2$O ratio in the inner…