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We investigated transition strengths from ultracold weakly bound 41K87Rb molecules produced via the photoassociation of laser-cooled atoms. An accurate potential energy curve of the excited state (3)1Sigma+ was constructed by carrying out…

Atomic Physics · Physics 2015-05-20 K. Aikawa , D. Akamatsu , M. Hayashi , J. Kobayashi , M. Ueda , S. Inouye

We demonstrate coherent control of both the rotational and hyperfine state of ultracold, chemically stable $^{87}$Rb$^{133}$Cs molecules with external microwave fields. We create a sample of ~2000 molecules in the lowest hyperfine level of…

Quantum Gases · Physics 2016-11-02 Philip D. Gregory , Jesus Aldegunde , Jeremy M. Hutson , Simon L. Cornish

We demonstrate the long-term ($<$ 1 minute) trapping of Stark-decelerated OH radicals in their $X~^{2}\Pi _{3/2}~(\nu = 0,~J = 3/2,~M_{J} = 3/2,~f)$ state in a permanent magnetic trap. The trap environment was cryogenically cooled to a…

Chemical Physics · Physics 2019-08-05 Dominik Haas , Claudio von Planta , Thomas Kierspel , Dongdong Zhang , Stefan Willitsch

Ultracold collisions of cold atoms or molecules make the bound states of the collision complex formed from the two colliding species accessible for control and manipulation of the cold species or the complex. Such resonances are best…

Atomic Physics · Physics 2015-05-13 Paul S. Julienne

We present a theoretical investigation of reactive and non-reactive collisions of Li and Rb atoms with C$_{2}^{-}$ molecular anions at low temperatures in the context of sympathetic cooling in hybrid trap experiments. Based on recently…

Chemical Physics · Physics 2020-08-26 M. Kas , J. Liévin , N. Vaeck , J. Loreau

The collision of molecules at ultracold temperatures is of great importance for understanding the chemical interactions at the quantum regime. While much theoretical work has been devoted to this, experimental data are only available…

Quantum Gases · Physics 2018-01-30 Xin Ye , Mingyang Guo , Maykel L. González-Martínez , Goulven Quéméner , Dajun Wang

Molecular dynamics calculations of inelastic collisions of atomic oxygen with molecular nitrogen are known to show orders of magnitude discrepancies with experimental results in the range from room temperature to many thousands of degrees…

We analyze collisional decoherence of atoms or molecules prepared in a coherent superposition of nondegenerate internal states at ultralow temperatures and placed in an ultracold buffer gas. Our analysis is applicable for an arbitrary bath…

Quantum Physics · Physics 2015-05-14 C. J. Hemming , R. V. Krems

A major motivation for cold atom experiments is the search for quantum ground states such as antiferromagnets and d-wave superfluids. The primary obstacle to this task is the difficulty of cooling to sufficiently low temperatures. We…

Quantum Gases · Physics 2012-10-23 Yen Lee Loh

We use the McLerran-Venugopalan model of the glasma energy-momentum tensor to compute the rapidity loss and excitation energy of the colliding nuclei in the fragmentation regions followed by a space-time picture to obtain their energy and…

Nuclear Theory · Physics 2017-03-08 Joseph Kapusta , Ming Li

We trap neutral Cs atoms in a two-dimensional optical lattice and cool them close to the zero-point of motion by resolved-sideband Raman cooling. Sideband cooling occurs via transitions between the vibrational manifolds associated with a…

Quantum Physics · Physics 2009-10-31 S. E. Hamann , D. L. Haycock , G. Klose , P. H. Pax , I. H. Deutsch , P. S. Jessen

We report rotational quenching cross sections and rate coefficients of HCl due to collisions with He. The close-coupling method and the coupled-states approximation are applied in quantum-mechanical scattering calculations of state-to-state…

Solar and Stellar Astrophysics · Physics 2015-06-18 Benhui Yang , Phillip C. Stancil

Recent experimental developments in the loading of ultracold KRb molecules into quasi-two-dimensional traps, combined with the ability to tune the ratio between elastic and loss (inelastic/reactive) collisions through application of an…

Quantum Physics · Physics 2013-12-18 Bihui Zhu , Goulven Quéméner , Ana M. Rey , Murray J. Holland

The carbon monoxide rovibrational emission from discs around Herbig Ae stars and T Tauri stars with strong ultraviolet emissions suggests that fluorescence pumping from the ground X1 Sigma+ to the electronic A1 Pi state of CO should be…

Astrophysics of Galaxies · Physics 2015-06-11 Wing-Fai Thi , Inga Kamp , Peter Woitke , Gerrit van des Plas , Rosina Bertelsen , Laurent Wiesenfeld

(Abridged) Gas-phase complex organic molecules are commonly detected in the warm inner regions of protostellar envelopes. Recent models show that photochemistry in ices followed by desorption may explain the observed abundances. This study…

Astrophysics of Galaxies · Physics 2015-05-13 K. I. Oberg , R. T. Garrod , E. F. van Dishoeck , H. Linnartz

We present high-resolution rovibronic spectroscopy of calcium monohydride molecular ions (CaH$^+$) co-trapped in a Coulomb crystal with calcium ions ($^{40}$Ca$^+$), focusing on rotational transitions in the $|X^1\Sigma^+, \nu" = 0>…

Atomic Physics · Physics 2026-02-10 Swapnil Patel , Kenneth R. Brown

We propose a general technique to produce cold spin-polarized molecules, in which rotationally excited states are first populated by coherent microwave excitation, and then allowed to spin-flip and relax via collisional quenching, which…

Chemical Physics · Physics 2024-11-13 Rebekah Hermsmeier , Timur V. Tscherbul

We present a method to design a finite decay rate for excited rotational states in polar molecules. The setup is based on a hybrid system of polar molecules with atoms driven into a Rydberg state. The atoms and molecules are coupled via the…

Quantum Gases · Physics 2012-05-15 Sebastian D. Huber , Hans Peter Büchler

Experimental measurements and theoretical calculations of state-to-state rate coefficients for rotational energy transfer of CO in collision with H$_2$ are reported at the very low temperatures prevailing in dense interstellar clouds (5 -…

Rate coefficients for rotational transitions in H_2 induced by H_2 impact are presented. Extensive quantum mechanical coupled-channel calculations based on a recently published (H_2)_2 potential energy surface were performed. The potential…

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