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The procedure for simulating the nuclear magnetic resonance spectrum linked to the spin system of a molecule for a certain nucleus entails diagonalizing the associated Hamiltonian matrix. As the dimensions of said matrix grow exponentially…

Quantum Physics · Physics 2024-10-29 Joaquín Ossorio-Castillo , Alexandre Rodríguez-Coello

Recent technological advances may lead to the development of small scale quantum computers capable of solving problems that cannot be tackled with classical computers. A limited number of algorithms has been proposed and their relevance to…

Quantum Physics · Physics 2020-07-07 Dries Sels , Hesam Dashti , Samia Mora , Olga Demler , Eugene Demler

Nanoscale engineered spin systems, ranging from spins on surfaces to nanographenes, provide flexible platforms to realize entangled quantum magnets from a bottom up approach. However, assessing the quantum many-body Hamiltonian realized in…

Mesoscale and Nanoscale Physics · Physics 2025-10-22 Netta Karjalainen , Greta Lupi , Rouven Koch , Adolfo O. Fumega , Jose L. Lado

Efficiently characterising quantum systems, verifying operations of quantum devices and validating underpinning physical models, are central challenges for the development of quantum technologies and for our continued understanding of…

The complex-scaling method can be used to calculate molecular resonances within the Born-Oppenheimer approximation, assuming the electronic coordinates are dilated independently of the nuclear coordinates. With this method, one will…

Quantum Physics · Physics 2021-06-16 Teng Bian , Sabre Kais

Nuclear magnetic resonance spectroscopy is one of the few remaining areas of physical chemistry for which polynomially scaling simulation methods have not so far been available. Here, we report such a method and illustrate its performance…

Chemical Physics · Physics 2014-07-16 Luke J. Edwards , D. V. Savostyanov , Z. T. Welderufael , Donghan Lee , Ilya Kuprov

Quantum chemistry has been viewed as one of the potential early applications of quantum computing. Two techniques have been proposed for electronic structure calculations: (i) the variational quantum eigensolver and (ii) the…

Quantum Physics · Physics 2021-04-19 Christina Daniel , Diksha Dhawan , Dominika Zgid , James K. Freericks

Hamiltonian learning is a cornerstone for advancing accurate many-body simulations, improving quantum device performance, and enabling quantum-enhanced sensing. Existing readily deployable quantum metrology techniques primarily focus on…

Quantum Physics · Physics 2025-10-10 Suying Liu , Xiaodi Wu , Murphy Yuezhen Niu

We derive the Hamiltonian in the rotating frame for NMR quantum computing with homonucleus molecules as its computational resource. The Hamiltonian thus obtained is different from conventional Hamiltonians that appear in literature. It is…

Quantum Physics · Physics 2007-05-23 Yasushi Kondo , Mikio Nakahara , Kazuya Hata , Shogo Tanimura

Extracting the Hamiltonian parameters of nanoscale quantum magnets from experimental measurements is a significant challenge in quantum matter. Here we establish a machine learning strategy to extract the parameters of a spin Hamiltonian…

Mesoscale and Nanoscale Physics · Physics 2025-09-11 Rouven Koch , Robert Drost , Peter Liljeroth , Jose L. Lado

We employ so-called quantum kernel estimation to exploit complex quantum dynamics of solid-state nuclear magnetic resonance for machine learning. We propose to map an input to a feature space by input-dependent Hamiltonian evolution, and…

Quantum Physics · Physics 2022-03-14 Takeru Kusumoto , Kosuke Mitarai , Keisuke Fujii , Masahiro Kitagawa , Makoto Negoro

Variational quantum algorithms are promising applications of noisy intermediate-scale quantum (NISQ) computers. These algorithms consist of a number of separate prepare-and-measure experiments that estimate terms in a Hamiltonian. The…

Quantum Physics · Physics 2020-06-25 Andrew Zhao , Andrew Tranter , William M. Kirby , Shu Fay Ung , Akimasa Miyake , Peter Love

Molecular quantum magnets adsorbed on surfaces exhibit rich spin and orbital excitations that can be probed by scanning tunneling microscopy with inelastic electron tunneling spectroscopy (STM-IETS). However, the quantitative extraction of…

Mesoscale and Nanoscale Physics · Physics 2026-01-28 Greta Lupi , Adolfo O. Fumega , Mohammad Amini , Robert Drost , Peter Liljeroth , Jose L. Lado

Impurities in quantum materials have provided successful strategies for learning properties of complex states, ranging from unconventional superconductors to topological insulators. In quantum magnetism, inferring the Hamiltonian of an…

Mesoscale and Nanoscale Physics · Physics 2025-06-23 Greta Lupi , Jose L. Lado

We present a quantum algorithm to obtain the response of the atomic nucleus to a small external electromagnetic perturbation. The Hamiltonian of the system is presented by a harmonic oscillator, and the linear combination of unitaries (LCU)…

Quantum Physics · Physics 2022-10-18 Abhishek , Nifeeya Singh , Pooja Siwach , P. Arumugam

Determining the vibrational structure of a molecule is central to fundamental applications in several areas, from atmospheric science to catalysis, fuel combustion modeling, biochemical imaging, and astrochemistry. However, when significant…

Quantum Physics · Physics 2021-12-22 Nicolas P. D. Sawaya , Francesco Paesani , Daniel P. Tabor

We report the realization of a nuclear magnetic resonance computer with three quantum bits that simulates an adiabatic quantum optimization algorithm. Adiabatic quantum algorithms offer new insight into how quantum resources can be used to…

Quantum Physics · Physics 2007-05-23 Matthias Steffen , Wim van Dam , Tad Hogg , Greg Breyta , Isaac Chuang

Nuclear magnetic resonance (NMR) is a powerful tool for applications ranging from chemical analysis to quantum information processing. Achieving optical initialization and detection of molecular nuclear spins promises new opportunities -…

Simulations of nuclear magnetic resonance (NMR) experiments can be an important tool for extracting information about molecular structure and optimizing experimental protocols but are often intractable on classical computers for large…

Identifying an accurate model for the dynamics of a quantum system is a vexing problem that underlies a range of problems in experimental physics and quantum information theory. Recently, a method called quantum Hamiltonian learning has…

Quantum Physics · Physics 2014-04-23 Nathan Wiebe , Christopher Granade , Christopher Ferrie , David G. Cory
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