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It is speculated that there might be some linkage between interstellar aldehydes and their corresponding alcohols. Here, an observational study and astrochemical modeling are coupled together to illustrate the connection between them. The…

An extensive series of neutron diffraction experiments and molecular dynamics simulations has shown that mixtures of methanol and water exhibit extended structures in solution despite the components being fully miscible in all proportions.…

Soft Condensed Matter · Physics 2009-11-10 L. Dougan , S. P. Bates , R. Hargreaves , J. P. Fox , J. Crain , J. L. Finney , V. Reat , A. K. Soper

Functionalized polcyclic aromatic hydrocarbons (PAHs) are an interesting class of molecules in which the electronic state of the graphene-like hydrocarbon part is tuned by the functional group. Searching for new types of donor and acceptor…

The delicate balance between H-bonding and van der Waals interactions determine the stability,structure and chirality of many molecular and supramolecular aggregates weakly adsorbed on solid surfaces.Yet the inherent complexity of these…

The classes of Monge-Amp\`ere systems, decomposable and bi-decomposable Monge-Amp\`ere systems, including equations for improper affine spheres and hypersurfaces of constant Gauss-Kronecker curvature are introduced. They are studied by the…

Differential Geometry · Mathematics 2015-10-13 Goo Ishikawa , Yoshinori Machida

The correlations of primary and secondary structures were analyzed using proteins with known structure from Protein Data Bank. The correlation values of amino acid type and the eight secondary structure types at distant position were…

Biomolecules · Quantitative Biology 2007-05-23 Sasa Malkov , Miodrag V. Zivkovic , Milos V. Beljanski , Snezana D. Zaric

Due to the simultaneous presence of two polar functional groups and flexible spatial structure, Aminoethanol (AE) is a model system for investigating the relationship between intramolecular hydrogen bonding and conformational equlibrium. In…

Chemical Physics · Physics 2024-03-22 Honghui Zhao , Hongyuan Shen , Ao You , Yuanqin Yu

We study the interaction of lipid bilayers with short chain alcohols using molecular dynamics on different length scales. We use detailed atomistic modeling and modeling on the length scale where an alcohol is just an amphiphilic dimer. Our…

Biological Physics · Physics 2015-06-26 Allison N. Dickey , Roland Faller

Assessments of machine-learned (ML) potentials are an important aspect of the rapid development of this field. We recently reported an assessment of the linear-regression permutationally invariant polynomial (PIP) method for ethanol, using…

Chemical Physics · Physics 2024-07-30 Paul L. Houston , Chen Qu , Qi Yu , Priyanka Pandey , Riccardo Conte , Apurba Nandi , Joel M. Bowman

Due to the increasing number of industrial applications of electro-active polymers (EAPs), there is a growing need for electromechanical models which accurately capture their behavior. To this end, we compare the predicted behavior of EAPs…

Soft Condensed Matter · Physics 2016-04-27 Noy Cohen , Andreas Menzel , Gal deBotton

Fabrication of diamond structures by self-assembly is a fundamental challenge in making three-dimensional photonic crystals. We simulate a system of model hard particles with attractive patches and show that they can self-assemble into a…

Statistical Mechanics · Physics 2012-01-18 Zhenli Zhang , Aaron S. Keys , Ting Chen , Sharon C. Glotzer

The solvent quality determines the collapsed or the expanded state of a polymer. For example, a polymer dissolved in a poor solvent collapses, whereas in a good solvent it opens up. While this standard understanding is generally valid,…

Soft Condensed Matter · Physics 2020-07-01 Yani Zhao , Manjesh K. Singh , Kurt Kremer , Robinson Cortes-Huerto , Debashish Mukherji

A representation without explicit use of the isospin formalism is developed for the precise study of few-nucleon systems, and the advantages of the proposed approach are demonstrated. Using the example of three-nucleon systems with central…

Nuclear Theory · Physics 2007-05-23 I. V. Simenog , I. S. Dotsenko , B. E. Grinyuk

If particles interact according to isotropic pair potentials that favor multiple length scales, in principle a large variety of different complex structures can be achieved by self-assembly. We present, motivate, and discuss a conjecture…

Soft Condensed Matter · Physics 2018-11-07 Erdal C. Oğuz , Aleksandar Mijailović , Michael Schmiedeberg

Bone structure is generally hierarchically organized into organic (collagen, proteins,...), inorganic (hydroxyapatite (HAP)) components. However, many fundamental mechanisms of the biomineralization processes such as HAP formation, the…

The associative interaction, such as hydrogen bonding, can bring about versatile functionalities to polymer systems, which has been investigated by tremendous researches, but the fundamental understanding on association process is still…

Soft Condensed Matter · Physics 2025-01-20 Xiangyu Zhang , Dong Meng

For some values of the constituent masses m_i, the hydrogen-like molecule (m_1^+,m_2^+,m_3^-,m_4^-) is stable with respect to spontaneous dissociation into two neutral atoms, while none of its three-body subsystems such as…

Atomic Physics · Physics 2007-05-23 Jean-Marc Richard

We explore the structural signatures of excitations in amorphous materials with the atomic cluster expansion (ACE), a universal and complete linear basis of descriptors of the atomic environment. Body-orderd linear classifiers are…

Disordered Systems and Neural Networks · Physics 2024-10-07 Joerg Rottler , Christoph Ortner

The use of polymer nanocomposites as gas barrier materials has seen increasing interest, including applications involving hydrogen transport and storage. Better understanding of gas transport through those polymeric systems requires 3D…

Solvent interactions, particularly hydration, are vital in chemical and biochemical systems. Model systems unveil microscopic details of such interactions. We uncover a specific hydrogen-bonding motif of the biomolecular building block…

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