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The ability to design quantum systems that decouple from environmental noise sources is highly desirable for development of quantum technologies with optimal coherence. The chemical tunability of electronic states in magnetic molecules…

A major challenge in using spins in the solid state for quantum technologies is protecting them from sources of decoherence. This can be addressed, to varying degrees, by improving material purity or isotopic composition for example, or…

Clock transitions (CTs) in spin systems, which occur at avoided level crossings, enhance quantum coherence lifetimes T$_2$ because the transition becomes immune to the decohering effects of magnetic field fluctuations to first order. We…

Materials Science · Physics 2025-02-06 Brendan C. Sheehan , Guanchu Chen , Jonathan R. Friedman

Molecular magnets are attractive as spin qubits due to their chemical tunability, addressability through electron-spin resonance techniques, and long coherence times. Clock transitions (CTs), for which the system is immune to the effect of…

The clock transitions (CTs) of central spins have long coherence times because their frequency fluctuations vanish in the linear order of external field noise (such as Overhauser fields from nuclear spin baths). Therefore, CTs are useful…

Quantum Physics · Physics 2021-01-04 Geng-Li Zhang , Wen-Long Ma , Ren-Bao Liu

Clock transitions are well known in atomic and solid-state systems, but are largely unexplored in molecular liquids. Here we demonstrate a clock-like, nuclear-spin avoided crossing in [1--$^{13}$C]-fumarate that supports long-lived and…

Manipulation of spin states at the single-atom scale underlies spin-based quantum information processing and spintronic devices. Such applications require protection of the spin states against quantum decoherence due to interactions with…

Mesoscale and Nanoscale Physics · Physics 2018-11-13 Yujeong Bae , Kai Yang , Philip Willke , Taeyoung Choi , Andreas J. Heinrich , Christopher P. Lutz

Decoherence of quantum systems due to uncontrolled fluctuations of the environment presents fundamental obstacles in quantum science. `Clock' transitions which are insensitive to such fluctuations are used to improve coherence, however,…

Quantum Gases · Physics 2018-01-24 D. Trypogeorgos , A. Valdés-Curiel , N. Lundblad , I. B. Spielman

Despite the importance of isotopically purified samples in current experiments, there have been few corresponding studies of spin qubit decoherence using full quantum bath calculations. Isotopic purification eliminates the well-studied…

Quantum Physics · Physics 2016-01-06 J. E. Lang , R. Guichard , S. J. Balian , T. S. Monteiro

A viable qubit must have a long coherence time $T_2$. In molecular nanomagnets $T_2$ is often limited at low temperatures by the presence of dipole and hyperfine interactions, which are often mitigated through sample dilution, chemical…

We theoretically study Floquet engineering of magnetic molecules via a time-periodic magnetic field that couples to the emergent total electronic spin of the metal center. By focusing on the low-lying energy levels using an $S = 1$ spin…

Quantum Physics · Physics 2025-10-20 Andrew Cupo , Shuanglong Liu , Silas Hoffman , X. -G. Zhang , Hai-Ping Cheng

The protection of superconducting qubits from certain noise sources often comes at the cost of increased sensitivity to other decoherence channels. Here, we explore a route to avoid this tradeoff by encoding quantum information in quantum…

Recently it was shown that by means of an STM it is experimentally possible to stimulate clock transitions between the singlet and the non-magnetic triplet state of a Heisenberg-coupled spin dimer (Bae et al., Science Advances 4, eaau4159).…

Strongly Correlated Electrons · Physics 2020-02-05 P. Vorndamme , J. Schnack

Trapped-ion qubits are among the most promising candidates for quantum computing, quantum information processing, and quantum simulation. In general, trapped ions are considered to have sufficiently long coherence times, which are mainly…

Quantum Physics · Physics 2025-10-28 Hengchao Tu , Chun-Yang Luan , Menglin Zou , Zihan Yin , Kamran Rehan , Kihwan Kim

Molecules are a powerful platform to probe fundamental symmetry violations beyond the Standard Model, as they offer both large amplification factors and robustness against systematic errors. As experimental sensitivities improve, it is…

Atomic Physics · Physics 2023-11-07 Yuiki Takahashi , Chi Zhang , Arian Jadbabaie , Nicholas R. Hutzler

Recent advances in quantum technologies have enabled the precise control of single trapped molecules on the quantum level. Exploring the scope of these new technologies, we studied theoretically the implementation of qubits and clock…

Atomic Physics · Physics 2020-12-02 Kaveh Najafian , Ziv Meir , Stefan Willitsch

Enhanced coherence in HoW$_{10}$ molecular spin qubits has been demonstrated by use of Clock Transitions (CTs). More recently it was shown that, while operating at the CTs, it was possible to use an electrical field to selectively address…

Quantum Physics · Physics 2022-12-08 Aman Ullah , Ziqi Hu , Jesus Cerdá , Juan Aragó , Alejandro Gaita-Ariño

Spin decoherence poses a significant challenge in molecular magnets, with the nuclear spin bath serving as a prominent source. Intriguingly, spin qubits at the clock transition exhibit remarkable insensitivity to the surrounding nuclear…

Quantum Physics · Physics 2025-10-14 Xiao Chen , Haechan Park , Silas Hoffman , Shuanglong Liu , Hai-Ping Cheng

Optically addressable paramagnetic defects in wide-band-gap semiconductors are promising platforms for quantum communications and sensing. The presence of avoided crossings between the electronic levels of these defects can substantially…

Molecular spins offer promise in emerging quantum technologies such as quantum sensing and computing. At low temperatures, nuclear spin-spin interactions affect electron spin coherence lifetimes through pure dephasing. Nuclear-spin noise…

Quantum Physics · Physics 2026-05-06 Timothy J. Krogmeier , James Bradley , Anthony W. Schlimgen , Kade Head-Marsden
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