Related papers: Abiotic molecular oxygen production -- ionic pathw…
We consider super-Earth sized planets which have a water mass fraction that is large enough to form an external mantle composed of high pressure water ice polymorphs and that lack a substantial H/He atmosphere. We consider such planets in…
The emergence of oxygenic photosynthesis created a new niche with dramatic potential to transform energy flow through Earth's biosphere. However, more primitive forms of photosynthesis that fix CO2 into biomass using electrons from reduced…
The biological molecules delivered to Earth on the board of meteorites and comets were called one of the possible causes of the origin of life. Therefore, our understanding of the routes of formation of biomolecules in space should shed the…
Radiative cooling by molecules is a crucial process for hydrodynamic escape, as it can efficiently remove the thermal energy driving the outflow, acquired through X-ray and extreme UV absorption. Carbon oxides, such as CO and CO2, and their…
The atmospheres of small exoplanets likely derive from a combination of geochemical outgassing and primordial gases left over from formation. Secondary atmospheres, such as those of Earth, Mars and Venus, are sourced by outgassing.…
New infrared absorption measurements of oxygen isotope ratios in CO gas from individual young stellar objects confirm that the solar system is anomalously high in its 18O/17O ratio compared with extra-solar oxygen in the Galaxy. We show…
Organic material in anoxic sediment represents a globally significant carbon reservoir that acts to stabilize Earth's atmospheric composition. The dynamics by which microbes organize to consume this material remain poorly understood. Here…
The driving force behind the origin and evolution of life has been the thermodynamic imperative of increasing the entropy production of the biosphere through increasing the global solar photon dissipation rate. In the upper atmosphere of…
Here we review how environmental context can be used to interpret whether O2 is a biosignature in extrasolar planetary observations. This paper builds on the overview of current biosignature research discussed in Schwieterman et al. (2017),…
Previous studies of haze formation in the atmosphere of the Early Earth have focused on N$_{2}$/CO$_{2}$/CH$_{4}$ atmospheres. Here, we experimentally investigate the effect of O$_{2}$ on the formation and composition of aerosols to improve…
O2 and O3 have been long considered the most robust individual biosignature gases in a planetary atmosphere, yet multiple mechanisms that may produce them in the absence of life have been described. However, these abiotic planetary…
Earth and Titan are two planetary bodies formed far from each other. Nevertheless the chemical composition of their atmospheres exhibits common indications of being produced by the accretion, plus ulterior in-situ processing of cometary…
Understanding the formation of molecules under conditions relevant to interstellar chemistry is fundamental to characterize the chemical evolution of the universe. Using reactive molecular dynamics simulations with model-based or…
The formation of organic compounds is generally assumed to result from abiotic processes in the Solar System, with the exception of biogenic organics on Earth. Nitrogen-bearing organics are of particular interest, notably for prebiotic…
Photochemistry induced by stellar UV flux should produce haze particles in exoplanet atmospheres. Recent observations indicate that haze and/or cloud layers exist in the atmospheres of exoplanets. However, photochemical processes in…
Sulfur is a redox active element that may have helped mediate an electron flow that kickstarted life and which presently is an essential element for all life on Earth. Despite current uncertainties in global sulfur fluxes, modeling sulfur's…
We propose that the photochemical smog mechanism produced substantial ozone (O3) in the troposphere during the Proterozoic, which contributed to ultraviolet (UV) radiation shielding hence favoured the establishment of life. The smog…
The history of molecular oxygen (O$_2$) in Earth's atmosphere is still debated; however, geological evidence supports at least two major episodes where O$_2$ increased by an order of magnitude or more: the Great Oxidation Event (GOE) and…
Photochemistry is a fundamental process of planetary atmospheres that regulates the atmospheric composition and stability. However, no unambiguous photochemical products have been detected in exoplanet atmospheres to date. Recent…
Deep elemental composition is a challenging measurement to achieve in the giant planets of the solar system. Yet, knowledge of the deep composition offers important insights in the internal structure of these planets, their evolutionary…